• Journal of the Korean Ceramic Society
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• v.43 no.2 s.285
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• pp.98-105
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• 2006

YBCO film was synthesized by using a new approach to the TFA-MOD method. In the fabrication process, $Y_2Ba_1Cu_1O_x\;and\;Ba_3Cu_5O_8$ powders were used as precursors (the so called '211 process'), instead of Y-, Ba-, and Cu-based acetates, and dissolved in trifluoroacetic acid followed by calcining and firing heat treatment. Consequently, we successfully fabricated YBCO film and evaluated the phase formation, texture evolution, and critical properties as a function of the calcining and firing temperature and humidity, in order to explore its possible application in coated conductor fabrication. The films were calcined at $430-460^{\circ}C$ and then fired at $750-800^{\circ}C\;in\;a\;0-20\%$ humidified $Ar-O_2$ atmosphere. We observed that $BaF_2$ phase was effectively reduced and that a sharp and strong biaxial texture formed under humidified atmosphere leading to increased critical properties. In addition, we found that the microstructure varied significantly with the firing temperature: the grain grew further, the film became denser, and the degree of texture and phase purity varied as the firing temperature increased. For the film fired at $775^{\circ}C$ after calcining at $460^{\circ}C$, the critical current was obtained to be 39 A/cm-width (corresponding critical current density is $2.0\;MA/cm^2$ which was probably attributed to such factors as the enhanced phase purity and out-of-plane texture, the moderate film density and grain size, and crack-free surface.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.47 no.6
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• pp.1026-1036
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• 2014

Real-time monitoring for environmental factors (temperature, salinity, chlorophyll-a, etc.) and fugacity of carbon dioxide ($fCO_2$) was conducted at an oyster Crassostrea gigas farm in Goseong Bay, south coast of Korea during 2-4th of November, 2011. Surface temperature and salinity were ranged from $17.9-18.7^{\circ}C$ and 32.7-33.8, respectively, with daily and inter-daily variations due to tidal currents. Surface $fCO_2$ showed a range of $390-510{\mu}atm$ and was higher than air $CO_2$ during the study period. Surface temperature, salinity and $fCO_2$ are showed significant correlations with chl.-a and nutrients, respectively. It means when chl.-a value is high in surface water of the oyster farm, active biological production consume $CO_2$ and nutrients from environments and produce oxygen, suggesting a tight feedback between biological processes and environmental reaction. Thus, factors affecting the surface $fCO_2$ were evaluated using a simple mass balance. Temperature and biological productions by phytoplankton are the main factors for $CO_2$ drawdown from afternoon to early night, while biological respiration increases seawater $CO_2$ at night. Air-sea exchange fraction acts as a $CO_2$ decreasing gear during the study period and is much effective when the wind speed is higher than $2-3m\;s^{-1}$. Future studies about organic carbon and biological production/respiration are required for evaluating the roles of oyster farms on carbon sink and coastal carbon cycle.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.15 no.1
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• pp.67-74
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• 2002

A phosphor for Plasma Display Panel, BaMgAl$_{10}$ O$_{17}$ :Eu$^{2+}$, showing a blue emission band at about 450nm was prepared by a solid-state reaction using BaCO$_3$, $Al_2$O$_3$, MgO, Eu$_2$O$_3$ as starting materials wish flux AlF$_3$. The study of the behaviour of Eu in BAM phosphor was carried out by the photoluminescence spectra and the Rietveld method with X-ray and neutron powder diffraction data to refine the structural parameters such as lattice constants, the valence state of Eu, the preferential site of Mg atom and the site fraction of each atom. The phenomenon of the concentration quenching was abound 2.25~2.3wt% of Eu due to a decrease in the critical distance for energy transfer of inter-atomic Eu. Through the combined Rietveld refinement, R-factor, R$_{wp}$, was 8.11%, and the occupancy of Eu and Mg was 0.0882 and 0.526 at critical concentration. The critical distance of Eu$^{2+}$ in BAM was 18.8$\AA$ at 2.25% Eu of the concentration quenching. Furthermore, c/a ratio was decreased to 3.0wt% and no more change was observed over that concentration. The maximum entropy electron density was found that the modeling of $\beta$-alumina structure in BaMgAl$_{10}$ O$_{17}$ :Eu$^{2+}$correct coincided showing Ba, Eu, O atoms of z= 1/4 mirror plane.e.ane.e.

• Bulletin of the Korean Chemical Society
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• v.35 no.8
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• pp.2438-2442
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• 2014

A kinetic study is reported for $S_NAr$ reaction of 1-fluoro-2,4-dinitrobenzene (5a) and 1-chloro-2,4-dinitrobenzene (5b) with alkali-metal ethoxides (EtOM, M = Li, Na, K and 18-crown-6-ether complexed K) in anhydrous ethanol. The second-order rate constant increases in the order $k_{EtOLi}$ < $k_{EtO^-}$ < $k_{EtONa}$ < $k_{EtOK}$ < $k_{EtOK/18C6}$ for the reaction of 5a and $k_{EtOLi}$ < $k_{EtONa}$ < $k_{EtO^-$ < $k_{EtOK}$ < $k_{EtOK/18C6}$ for that of 5b. This indicates that $M^+$ ion behaves as a catalyst or an inhibitor depending on the size of $M^+$ ion and the nature of the leaving group ($F^-$ vs. $Cl^-$). Substrate 5a is more reactive than 5b, although the $F^-$ in 5a is ca. $10pK_a$ units more basic than the $Cl^-$ in 5b, indicating that the reaction proceeds through a Meisenheimer complex in which expulsion of the leaving group occurs after the rate-determining step (RDS). $M^+$ ion would catalyze the reaction by increasing either the nucleofugality of the leaving group through a four-membered cyclic transition state or the electrophilicity of the reaction center through a ${\pi}$-complex. However, the enhanced nucleofugality would be ineffective for the current reaction, since expulsion of the leaving group occurs after the RDS. Thus, it has been concluded that $M^+$ ion catalyzes the reaction by increasing the electrophilicity of the reaction center through a ${\pi}$-complex between $M^+$ ion and the ${\pi}$-electrons in the benzene ring.

• Journal of Ginseng Research
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• v.48 no.2
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• pp.211-219
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• 2024

Background: Recently, plant-derived exosome-like nanoparticles (PDENs) have been isolated, and active research was focusing on understanding their properties and functions. In this study, the characteristics and molecular properties of ginseng root-derived exosome-like nanoparticles (GrDENs) were examined in terms of skin protection. Methods: HPLC-MS protocols were used to analyze the ginsenoside contents in GrDENs. To investigate the beneficial effect of GrDENs on skin, HaCaT cells were pre-treated with GrDENs (0-2 × 10⁹ particles/mL), and followed by UVB irradiation or H₂O₂ exposure. In addition, the antioxidant activity of GrDENs was measured using a fluorescence microscope or flow cytometry. Finally, molecular mechanisms were examined with immunoblotting analysis. Results: GrDENs contained detectable levels of ginsenosides (Re, Rg1, Rb1, Rf, Rg2 (S), Gyp17, Rd, C-Mc1, C-O, and F2). In UVB-irradiated HaCaT cells, GrDENs protected cells from death and reduced ROS production. GrDENs downregulated the mRNA expression of proapoptotic genes, including BAX, caspase-1, -3, -6, -7, and -8 and the ratio of cleaved caspase-8, -9, and -3 in a dose-dependent manner. In addition, GrDENs reduced the mRNA levels of aging-related genes (MMP2 and 3), proinflammatory genes (COX-2 and IL-6), and cellular senescence biomarker p21, possibly by suppressing activator protein-1 signaling. Conclusions: This study demonstrates the protective effects of GrDENs against skin damage caused by UV and oxidative stress, providing new insights into beneficial uses of ginseng. In particular, our results suggest GrDENs as a potential active ingredient in cosmeceuticals to promote skin health.

• Membrane and Water Treatment
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• v.15 no.1
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• pp.21-29
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• 2024

1H,1H,2H,2H-perfluorodecytriethoxysilane (C₁₆H₁₉F₁₇O₃Si) be successfully applied to the hydrophobic modification of Al₂O₃ tubular ceramic membrane. Taking the concentration of modification solution, modification time, and modification temperature as factors, orthogonal experiments were designed to study the hydrophobicity of the composite membranes. The experiments showed that the modification time had the greatest impact on the experimental results, followed by the modification temperature, and the modification solution concentration had the smallest impact. Concentration of the modified solution 0.012 mol·L^-1, modification temperature 30 ℃ and modification time 24 h were considered optimal hydrophobic modification conditions. And the pure water flux reached 274.80 kg·m^-2·h^-1 at 0.1MPa before hydrophobic modification, whereas the modified membrane completely blocked liquid water permeation at pressures less than 0.1MPa. Air gap membrane distillation experiments were conducted for NaCl (2wt%) solution, and the maximum flux reached 4.20 kg·m^-2·h^-1, while the retention rate remained above 99.8%. Given the scarcity of freshwater resources in coastal areas, the article proposed a system for seawater desalination using air conditioning waste heat, and conducted preliminary research on its freshwater production performance using Aspen Plus. Finally, the proposed system achieved a freshwater production capacity of 0.61 kg·m^-2·h^-1.

• Journal of the Korean Institute of Telematics and Electronics C
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• v.36C no.11
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• pp.29-34
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• 1999

In this paper, a current comparative frequency automatic tuning circuit for the CMOS gm-C bandpass filters are designed with the new architecture. And also, when the designed circuit is compared to the typical tuning circuit, the designed circuit has very simple architecture that is composed of the current comparator and charge pump and operating in 3V power supply. The proposed tuning circuit automatically compensates the difference between the operating current of the transconductor and the specified reference Current. Using CMOS 0.8um parameter a biquad gm-C bandpass filter with center frequency($f_\circ$=60MHz) is designed, and according to the transistor size the variation of the center frequency is simulated. As the HSPICE simulation results, the tuning operation of the proposed current comparative frequency automatic tuning circuit is verified.

• Phonetics and Speech Sciences
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• v.9 no.3
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• pp.57-65
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• 2017

The current study explored how Korean-speaking children processed the multiple acoustic cues (VOT and f0) for the stop laryngeal contrast (/t'/, /t/, and /$t^h$/) and examined whether individual perceptual strategies could be related to a general cognitive ability performing executive functions (EF). 15 children (aged from 7 to 8) participated in the speech perception task identifying the three Korean laryngeal stops (3AFC) on listening to the auditory stimuli of C-/a/ with synthetically varying VOT and f0. They completed a series of EF tasks to measure working memory, inhibition, and cognitive shifting ability. The findings showed that children used the two cues in a highly correlated manner. While children utilized VOT consistently for the three laryngeal categories, their use of f0 was either reduced or enhanced depending on the phonetic categories. Importantly, the children's processing strategies of a f0 suppression for a tense-aspirated contrast were meaningfully associated with children's better cognitive abilities such as working memory, inhibition, and attentional shifting. As a preliminary experimental investigation, the current research demonstrated that listeners with inefficient processing strategies were poor at the EF skills, suggesting that cognitive skills might be responsible for developmental variations of processing sub-phonemic information for the linguistic contrast.

• Journal of the Korean Mathematical Society
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• v.37 no.6
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• pp.915-927
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• 2000

This paper is concerned with degenerate Volterra equations Mu(t) + ∫(sub)0(sup)t k(t-s) Lu(s)ds = f(t) in Banach spaces both in the hyperbolic case, and the parabolic one. The key assumption is played by the representation of the underlying space X as a direct sum X = N(T) + R(T), where T is the bounded linear operator T = ML(sup)-1. Hyperbolicity means that the part T of T in R(T) is an abstract potential operator, i.e., -T(sup)-1 generates a C(sub)0-semigroup, and parabolicity means that -T(sup)-1 generates an analytic semigroup. A maximal regularity result is obtained for parabolic equations. We will also investigate the cases where the kernel k($.$) is degenerated or singular at t=0 using the results of Pruss[8] on analytic resolvents. Finally, we consider the case where $\lambda$ is a pole for ($\lambda$L + M)(sup)-1.

• Proceedings of the Korea Water Resources Association Conference
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• 2021.06a
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• pp.388-388
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• 2021

하천에서 호안이나 교량의 교각 등은 홍수 시 주변 하상의 세굴에 의한 피해가 많이 발생한다. 하상보호를 위해서 하천 수공구조물 주변 하상에 자갈, 호박돌, 전석 등을 깔기도 한다. 이 재료들은 다공성 집단을 이루며 유수에 의한 소류력과 항력이 작용한다. 다공성 집단체 공극의 흐름에 의한 항력은 외부 흐름이 가하는 소류력에 비해 작으나 집단의 안정성에 큰 영향을 미칠 수 있다. 집단체에 작용하는 항력은 공극 내의 흐름의 유속과 항력계수를 이용하여 구할 수 있다. 본 연구에서는 다공성 매질 내 흐름에 대한 항력계수를 조사하기 위하여 수리실험을 이용하여 자갈 매질의 공극을 흐르는 물이 일으킨 항력과 동수경사를 측정하였다. 수리실험을 위한 대공극 매질은 상업용 연마 자갈을 사용하여 크기에 따라 작은 자갈(5~10mm), 중간자갈(15~25mm), 큰 자갈(25~50mm)로 구분하였다. 대표입경 D₅₀은 작은 자갈 8.0 mm, 중간 자갈 17.6 mm, 큰 자갈 32.2 mm이고, 형상계수는 각각 0.28~0.74, 0.29~0.58, 0.38~0.68의 범위였다. 자갈 매질의 공극율은 각각 0.405~0.422이었다. 매질 내의 흐름 길이는 24.2cm로 하였다. 실험결과 자갈 매질 내 흐름의 입자 레이놀즈수 Re_p에 따른 내부항력 F_D와 항력계수 C_D는 Fig. 1 및 Fig. 2와 같다. 실험에서 Re_p는 31.5~3,175.4였다. 자갈 매질의 내부항력은 Re_p가 증가하면 비선형적으로 증가하였으며 입자가 클수록 작았다. 항력계수는 작은 자갈과 중간 자갈 매질에 차이가 거의 없었으나 큰 자갈의 경우 작은 것으로 나타났다.