• Title/Summary/Keyword: C:N ratio

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Study on the Industrial Process of Rubber Anti-oxidant RD

  • Liu, Yu;Gao, Qinyu;Liu, Lianxin;Shi, Guangxia
    • Journal of the Korean Chemical Society
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    • v.55 no.5
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    • pp.830-834
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    • 2011
  • This paper is on the industrial synthesis process of anti-oxidant RD ((2,2,4-trimethyl-1,2-dihydroquinoline polymer $(C_{12}H_{15}N)_n$. n=2-4)).The content of dimer, trimer and tetramer of RD as the inspection targets, using the orthogonal design method - take the ratios of keto-amine, the reaction time, the reaction temperatures and the ratios of catalyst acid-amine as inspect factors - to optimized the reaction condition. The results indicate that the best ratio of keto-amine is 2:1, the time of salification and condensation is 3 hours and 7.5 hours. The range of temperature of salification and condensation is $135^{\circ}C$ and $120-125^{\circ}C$, and that the best ratio of acid-amine is 0.2: 1 (the proportion is the concentration ratio for mole). Under the optimization conditions, the yield of RD was stabilized and content of RD more than 45%.

A Study on the Characteristics of Continuous Scouring and Shrinking Equipment -Rota-drum and conveyor type- (연속 정련축소 장치의 특성 연구 -로터드럼형과 컨베이어형-)

  • 허만우;서말용
    • Textile Coloration and Finishing
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    • v.12 no.1
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    • pp.68-75
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    • 2000
  • In this study, polyester DTY faille(yoryu) and N/NP microfiber fabrics were pretreated (desizing, scouring and shrinking) by Continuous Scouring and Shringking Equipment with rota-drum and conveyor type in which types were different with retaining method. The results were as follows. The shrinkage ratio of wp/wf direction of DTY fabrics scoured by conveyor type was 1.5/23% higher than those by rota-drum type at $97^\circ{C}$ with 10min. treatment. In this case, The shrinkage ratio of wp/wf direction by those types was about 15/27%, respectively. The shrinkage ratio of wp/wf direction of N/NP microfiber fabrics scoured by conveyor type was 1.5/23% higher than that by rota-drum type at $97^\circ{C}$ with 10min. treatment. The size add-on of DTY fabrics scoured at $97^\circ{C}$ with 10min. treatment by conveyor type and by rota-drum type were 0.15% and 0.42%, respectively. The size add-on of DTY fabric treated by rota-drum type decreased until 9min. of treated time, but increased after 9min. The size add-on of N/NP microfiber fabrics treated by conveyor type was decreased by increasing temperature and treated time, while the size add-on of that treated by rota-drum type was decreased until 6min. treated time and increased after 6min. The size add-on of N/NP microfiber fabrics treated by conveyor type at $97^\circ{C}$ for 10min. was 0.3% lower than that by rota-drum type.

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Spatial and Temporal Variations of δ13C and C/N in Suspended Particulate Organic Matter in the Gangneung Namdae Stream, Korea (강릉 남대천 부유입자유기물의 탄소안정동위원소 비와 C/N 비의 시·공간 변동)

  • Kwak, Jung Hyun;Park, Hyun Je
    • Journal of Environmental Science International
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    • v.29 no.5
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    • pp.531-539
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    • 2020
  • To understand the composition, quantity, and quality of Suspended Particulate Organic Matter (SPOM) in the Gangneung Namdae Stream, Korea, we examined spatiotemporal variations in water temperature, salinity, chlorophlly a (Chl a), Particulate Organic Carbon (POC) and nitrogen (PON), and carbon stable isotope (δ13C) of SPOM at six stations in June (pre-monsoon), July (monsoon), and September (post-monsoon) 2017. With increasing precipitation, the average POC and C/N values increased significantly in July than in June. In September, the values decreased with decreasing precipitation. The δ13C values showed irregular spatiotemporal fluctuations among the stations and periods, thereby suggesting a greater contribution of autochthonous organic matter to the pool of SPOM than that of allochthonous organic matter derived from upstream. In addition, the large and irregular changes in POC, C/N ratio, C:Chl a, and δ13C compared to that of PON were observed for all periods among the stations, indicating a serial discontinuity of the stream. Our results suggest that the Gangneung Namdae Stream is significantly influenced by the increase in freshwater discharge caused by heavy rainfalls during the summer monsoon and post-monsoon periods.

Stabilization of Industrial Wastes Landfill using Lab-lysimeter (모형매립조를 이용한 산업폐기물 매립지의 안정화 조사 기초 연구)

  • 박동일;최석규;홍종순;장인용
    • Journal of environmental and Sanitary engineering
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    • v.13 no.3
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    • pp.9-18
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    • 1998
  • An experimental research was conducted to establish primary data for the stabilization assessment of industrial wastes landfill with analysis of waste components and investigation of leachate and gas generation, using three sets of lysimeter as experimental apparatus. Comparing results of lysimeter from data of landfill, it is suggested that lysimeter of this study can be used to accomplish the stabilization assessment of the real landfill site. Moisture content was lower as landfill period was older and combustible component was the highest in lysimeter C. The C/N ratio of waste was 7.4~14.4 and, with the elemental analysis, the theoretical gas generation rate based on the modified Buswell equation was 0.47~0.49 $m^3/kg-dry$ waste in lysimeter C. Considering the C/N ratio of leachate, it is concluded that the addition of carbon source is needed to biodegrade leachate hereafter. Gas generation rate($m^3/kg-dry$ waste) from lysimeter A, B and C was 0.0009, 0.014 and 0.0067, respectively, and different from each other according to the landfill period of wastes. The results in this study show that the biodegradation of microorganism for stabilization of landfill was inhibited and more activated in acidogenic step than in methanogenic of anaerobic degradation.

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A Statistical Study of SNR, SDNR on Water Temperature, C/N Ratio, and BOD Loads in Wastewater Treatment process (하수처리공정에서 수온, C/N비, BOD부하량에 따른 SNR, SDNR의 통계적 연구)

  • An, Sang-Woo;Min, Jee-Eun;Park, Jae-Woo
    • 한국방재학회:학술대회논문집
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    • 2008.02a
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    • pp.823-826
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    • 2008
  • Statistical methods were used in the analysis of data, which are the SNR and SDNR in describing the various natures, and the methodology relating the results with the operation was developed. Multiple regression analysis based on the results of statistics of data were SNR = 0.0219 + 0.000044BOD lording - 0.00600C/N ratio and SDNR = 0.0226 + 0.000044BOD lording - 0.00602C/N ratio. It were concluded that the variability of the process performance should be reflected to the operation condition procedure through the analysis based on the statistics methods.

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Influence of Rain Tree Pod Meal Supplementation on Rice Straw Based Diets Using In vitro Gas Fermentation Technique

  • Anantasook, N.;Wanapat, M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.3
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    • pp.325-334
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    • 2012
  • The objective of this study was to determine the roughage to concentrate (R:C) ratio with rain tree pod meal (RPM) supplementation on in vitro fermentation using gas production technique. The experiment design was a 6${\times}$4 factorial arrangement in a CRD. Factor A was 6 levels of R:C ratio (100:0, 80:20, 60:40, 40:60, 20:80 and 0:100) and factor B was 4 levels of RPM (0, 4, 8 and 12 mg). It was found that gas kinetic, extent rate (c) was linearly increased (p<0.01) with an increasing level of concentrate while cumulative gas production (96 h) was higher in R:C of 40:60. In addition, interaction of R:C ratio and RPM level affected $NH_3-N$ and IVDMD and were highest in R:C of 0:100 with 0, 4 mg of RPM and 40:60 with 8 mg of RPM, respectively. Moreover, interaction of R:C ratio and RPM level significantly increased total volatile fatty acids and propionate concentration whereas lower acetate, acetate to propionate ratios and $CH_4$ production in R:C of 20:80 with 8 mg of RPM. Moreover, the two factors, R:C ratio and RPM level influenced the protozoal population and the percentage of methanogens in the total bacteria population. In addition, the use of real-time PCR found that a high level of concentrate in the diet remarkably decreased three cellulolytic bacteria numbers (F. succinogenes, R. flavefaciens and R. albus). Based on this study, it is suggested that the ratio of R:C at 40:60 and RPM level at 12 mg could improve ruminal fluid fermentation in terms of reducing fermentation losses, thus improving VFA profiles and ruminal ecology.

Effect of V/III Ratio Variation on the Properties of AlN Epilayers in HVPE (HVPE법에 의해 성장된 AlN 에피층의 V/III비에 따른 특성변화)

  • Son, Hoki;Lim, Tae-Young;Lee, Mijai;Kim, Jin-Ho;Kim, Younghee;Hwang, Jonghee;Oh, Hae-Kon;Choi, YoungJun;Lee, Hae-Yong;Kim, Hyung Sun
    • Korean Journal of Materials Research
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    • v.23 no.12
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    • pp.732-736
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    • 2013
  • AlN epilayers were grown on a c-plane sapphire substrate using hydride vapor phase epitaxy (HVPE). A series of AlN epilayers were grown at $1120^{\circ}C$ with V/III ratios 1.5, 2.5 and 3.5, and the influence of V/III ratio on their properties was investigated. As the V/III ratio was increased, the surface roughness (RMS roughness), Raman shift of $E_2$ high peaks and full-width at half-maximum (FWHM) of symmetrical (002) & asymmetrical (102) of the AlN epilayers increased. However, the intensities of the Raman $E_2$ high peaks were reduced. This indicates that the crystal quality of the grown AlN epilayers was degraded by activation of the parasitic reaction as the V/III ratio was increased. Smooth surface, stress free and high crystal quality AlN epilayers were obtained at the V/III ratio of 1.5. The crystal quality of AlNepilayers is worsened by the promotion of three-dimensional (3D) growth mode when the flow of $NH_3$ is high.

Phase and Microstructure of SiC-AlN Ceramics Prepared by Pressureless Sintering (상압소결에 의하여 제조된 SiC-AlN 세라믹스의 상 및 미세구조)

  • Choi, Woong;Lee, Jong-Kook;Cho, Duk-Ho;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.32 no.11
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    • pp.1308-1314
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    • 1995
  • Changes in phase and microstructure were investigated in the SiC-AlN ceramics prepared by pressureless sintering using yttrium aluminum garnet (YAG) as a sintering aid at 200$0^{\circ}C$ and 210$0^{\circ}C$. The SiC/AlN ratio made a remarkable difference in densification, phase relations and the morphology of grains. In the AlN-rich composition, major phase was 2H and microstructure was composed of the densified equiaxed grains irrespective of the sintering temperatures. While those sintered at 200$0^{\circ}C$ were porous with major phase being 3C, the rod-like and the equiaxed grains were coexisted when sintered at 210$0^{\circ}C$ in the SiC-rich composition.

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Optimum Conditions for the Removal of External Organic Carbon Sources in a Submerged Denitrification Biofilter (탈질 여과조에서 외부 탄소원 제거를 위한 적정 체류 시간과 외부 탄소원 종류 및 질산염 농도에 대한 외부 탄소원의 적정 비율)

  • 오승용;조재윤;윤길하
    • Journal of Aquaculture
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    • v.12 no.1
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    • pp.47-56
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    • 1999
  • Denitrification by anaerobic bacteria is one of the most common processes of removing nitrate from recirculating aquaculture systems. This process is affected by many factors such as external carbon sources, hydraulic retention time (HRT), and $COD/NO_3-N$ ratio. Although external organic carbon sources are essential for the denitrification process, these also contribute to increase dissolved organic carbon concentration in recirculating aquaculture systems. So these external organic carbons must be removed from the systems. This study was conducted to find out the optimum operating conditions for the removal of external organic carbons in a submerged denitrification biofilter. Combinations of two external carbon sources (glucose and methanol), two HRT (4- and 8-hour), and four different C:N ratios (3, 4, 5, and 6) were used in this experiment. The removal efficiencies of organic carbon sources at 8-hour HRT were always better than those at 4-hour's (P<0.05). Maximum removal efficiencies were achieved when C:N ratio was 5 in both glucose and methanol. The removal efficiencies of methanol were always better than those of glucose. The maximum removal efficiencies of glucose and methanol were 76.5% and 84.0%, respectively and the removal rates were 223.5 $g/m^2/day$ and 247.1$g/m^2/day$. The maximum removal rates of glucose (290.9 $g/m^2/day$) and methanol (355.6 $g/m^2/day$) were achieved at 4-hour HRT and 5 C:N ratio. But the concentrations of SCOD in the effluent of both glucose ($52.5 mg/\ell$) and methanol ($40.9 mg/\ell$) were too high for rearing fish. Therefore, the optimum operating conditions for the removal of external carbon in a submerged denitrification biofilter were 8-hour HRT and 5 C:N ratio. And methanol showed better efficiency as an external carbon sources.

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Decay Rate and Nutrient Dynamics during Litter Decomposition of Quercus acutissima in Gongju and Jinju (공주와 진주지역에서 상수리나무 낙엽의 분해율 및 분해과정에 따른 영양염류 함량 변화)

  • Won, Ho-Yeon;Oh, Kyung-Hwan;Mun, Hyeong-Tae
    • Journal of Wetlands Research
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    • v.14 no.4
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    • pp.537-545
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    • 2012
  • Decay rate and nutrient dynamics during leaf litter decomposition of deciduous Quercus acutissima were compared between Gongju and Jinju for 33 months from December 2008 through March 2011. Percent remaining weight of Q. acutissima leaf litter after 33 months elapsed in Gongju and in Jinju was $41.2{\pm}0.4%$ and $28.3{\pm}0.6%$, and decay constant (k) was 0.39 and 0.61, respectively. Decomposition in Jinju was significantly faster than that in Gongju. This seemed to be related to higher temperature and precipitation in Jinju than those in Gongju during the experimental period. Initial C/N and C/P ratio of Q. acutissima leaf litter was 46.8 and 270.9, respectively. After 33 months elapsed, C/N and C/P ratios in Gongju decreased to 22.0 and 106.8, and those in Jinju decreased to 19.2 and 170.2, respectively. Initial concentration of N, P, K, Ca and Mg in Q. acutissima leaf litter was 8.31, 0.44, 4.18, 9.38, 1.37 mg/g, respectively. After 33 month elapsed, remaining N, P, K, Ca and Mg were 91.0, 85.4, 30.2, 47.9, 11.7% in Gongju, and 67.0, 54.2, 19.9, 30.0, 40.8% in Jinju, respectively. Except for Mg, remaining nutrients of decomposing leaf litter in Jinju were lower than those in Gongju. In case of N and P, initial immobilization was observed, however, only mineralization was observed in K, Ca and Mg during the whole experimental period.