• Title/Summary/Keyword: C/R ratio

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Mechanistic Aspects in the Grignard Coupling Reaction of Bis(chloromethyl)dimethylsilane with Trimethylchlorosilane

  • 조연석;유복렬;안삼영;정일남
    • Bulletin of the Korean Chemical Society
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    • v.20 no.4
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    • pp.422-426
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    • 1999
  • The Grignard reactions of bis(chloromethyl)dimethylsilane (1) with trimethylchlorosilane (2) in THF give both the intermolecular C-Si coupling and intramolecular C-C coupling products. At beginning stage, 1 reacts with Mg to give the mono-Grignard reagent ClCH2Me2SiCH2MgCl (1) which undergoes the C-Si coupling reaction to give MC2Si(CH2SiMe3)2 3, or C-C coupling to a mixture of formula Me3SiCH2(SiMe2CH2CH2)nR1 (n = 1, 2, 3, ..; 4a, R1I = H: 4b, R1 = SiMe3). In the reaction, two reaction pathways are involved: a) Ⅰ reacts with 2 to give Me3SiCH2SiMe2CH2Cl 6 which further reacts with Mg to afford a Me2SiCH2Mel-SiCH2MgCl (Ⅱ) or b) I cyclizes intramolecularly to a silacyclopropane intermediate A, which undergoes a ring-opening polymerization by the nucleophilic attack of the intermediates I or Ⅱ, followed by the termination reaction with H2O and 2, to give 4a and 4b, respectively. As the mole ratio of 2/1 increased from 2 to 16 folds, the formation of product 3 increased from 16% to 47% while the formation of polymeric products 4 was reduced from 60% to 40%. The intermolecular C-Si coupling reaction of the pathway a becomes more favorable than the intramolecular C-C coupling reaction of the pathways b at the higher mole ratio of 2/1.

Part-Load Performance Test of a Screw Chiller with Economizer using R22 and R407C (이코노마이저를 채용한 스크류 냉동기에서 R22와 R407C의 부분부하 성능실험)

  • 장영수;이용철;김영일
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.11
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    • pp.902-909
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    • 2003
  • Screw compressor type chillers are widely used in refrigeration for capacity over 30 RT. In general, chillers operate under part-load conditions. Therefore, information on characteristics at part-load is very important in view of chiller performance and energy economy. In this study, performance tests of part-load and economizer system using R22 and R407C have been performed for various secondary fluid temperatures. Adoption of an economizer system increased the cooling capacity and improved COP except for lower part-load condition when injection volume ratio is 1.01. For the same cooling capacity condition at part-load, COP of both non-economizer and economizer system showed similar values.

Changes of Texture and Plastic Strain Ratio of Asymmetrically Rolled and Annealed Cu Sheet (I) (비대칭 압연과 열처리한 Cu 판의 집합조직과 소성변형비 변화 (I))

  • Lee, C.W.;Lee, D.N.;Kim, I.
    • Transactions of Materials Processing
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    • v.28 no.6
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    • pp.354-360
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    • 2019
  • The plastic strain ratio is one of the factors that affect the deep drawability of metal sheets. The plastic strain ratio of fully annealed Cu sheet is low because its texture has {001}<100>. In order to improve the deep drawability of Cu sheet, it is necessary to increase the plastic strain ratio of Cu sheet. This study investigate the increase of plastic strain ratio of a Cu sheet after the first asymmetry rolling and annealing, and the second asymmetry rolling and annealing in air and Ar gas conditions. The average plastic strain ratio (Rm) was 0.951 and |ΔR| value was 1.27 in the initial Cu sheet. After the second 30.1% asymmetric rolling and annealing of Cu sheet at 1000℃ in air condition, the average plastic strain ratio (Rm) was 1.03 times higher. However, |ΔR| was 0.12 times lower than that of the initial specimen. After the second 18.8% asymmetric rolling and annealing of Cu sheet at 630℃ in Ar gas condition, the average plastic strain ratio (Rm) was 1.68 times higher and |ΔR| was 0.82 times lower than that of the initial specimen. These results are attributed to the change of the texture of Cu sheet due to the different annealing conditions.

Experimental study on the strength behavior of cement-stabilized sand with recovered carbon black

  • Chhun, Kean Thai;Choo, Hyunwook;Kaothon, Panyabot;Yune, Chan-Young
    • Geomechanics and Engineering
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    • v.23 no.1
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    • pp.31-38
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    • 2020
  • Soil-cement stabilization is a type of ground improvement method which has been used to improve the engineering properties of soil. The unconfined compression test is the commonly used method to evaluate the quality of the stabilized soil due to its simplicity, reliability, rapidity and cost-effectiveness. The main objective of this study was to evaluate the effect of recovered carbon black (rCB) on the strength characteristic of cement-stabilized sand. Various rCB contents and water to cement ratios (w/c) were examined. The unconfined compression test on stabilized sand with different curing times was also conducted for a reconstituted specimen. From the test result, it was found that the compressive strength of cement-stabilized sand increased with the increase of the rCB content up to 3% and the curing time and with the decrease of the w/c ratio, showing that the optimum rCB concentration of the tested stabilized sand was around 3%. In addition, a prediction equation was suggested in this study for cement-stabilized sand with rCB as a function of the w/c ratio and rCB concentration at 14 and 28 days of curing.

Performance of a room air conditioner using R410A according to the variation of outdoor temperature (실외온도 변화에 따른 R410A 적용 에어콘 시스템의 성능)

  • 김병순;이승홍
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.4
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    • pp.537-541
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    • 1999
  • The system performance of a room air conditioner using R410A was experimentally evaluated and compared with that of R22 system. The results indicated that the cooling EER(energy efficiency ratio) of R410A was 1% higher than that of R22 at the outdoor temperature of $35^{\circ}C$. As outdoor temperature increases above $35^{\circ}C$ ambient, EER of the R410A system decreased more substantially compared with R22 system. R410A showed higher compressor discharge temperature than that of R22 system at the outdoor temperature of higher than $50^{\circ}C$.

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Test Results of Refrigerant R152a in a Mobile Air-Conditioning System

  • Shin, Jeong-Sub;Park, Won-Gu;Kim, Man-Hoe
    • International Journal of Air-Conditioning and Refrigeration
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    • v.16 no.2
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    • pp.44-50
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    • 2008
  • This study presents test results of a mobile air-conditioning system using a potential alternative refrigerant, R152a. A series of performance tests have been carried out and cycle characteristics such as cooling capacity, energy efficiency ratio, suction and discharge pressures, and temperatures are presented, compared to those for the baseline R134a system. Tests were conducted with evaporation temperature of $5^{\circ}C$, condensation temperature of $45^{\circ}C$, subcooling temperature of $5^{\circ}C$, superheating temperature of $5^{\circ}C$, and compressor speed of 500-1500 rpm. The performance of R152a system with readjustment of an expansion valve showed better than those of R134a. The effect of oil on the pressure drop in the evaporator was also addressed.

Static loading test of R/C deep beams with CFRP-Grids (탄소격자섬유를 이용한 RC 깊이보의 정적파괴실험)

  • 조병완;김영진;태기호
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.04b
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    • pp.567-572
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    • 1998
  • Structural behavior of R/C deep beams was investigated and compared to those of specimens with CFRP Grids. Test results show that the crushing of compression strut for the unstrengthened R/C deep beams is changed to the group of several diagonal cracks at mid-depth within the sheat span. Strengthened specimens grow to be more ductile after the redistribution of internal force on the CFRP Grids. The failure mode and variations of strains in the specimens are dependent on the shear span-to-depth ratio. The lower the shear span-to-depth ratio, the bigger failure load and the less variations in strain are observed. Additional anchorage of CFRP Grids does not only cause the improvement in the internal resistance, but also control the brittle shear failure of specimen after reaching the maximum loads.

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Synthesis of AlN-SiO2-Al2O3 System (AlN-SiO2-Al2O3계로부터 AlN-Polytypes의 제조)

  • 박용갑;장병국
    • Journal of the Korean Ceramic Society
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    • v.26 no.1
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    • pp.31-36
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    • 1989
  • In order to synthesize AlN-polytypes from AlN-SiO2-Al2O3 system, composition A (AlN/SiO2/Al2O3=1/0.3/0.05, mole ratio) and composition B(AlN-SiO2-Al2O3=1/0.2/0.05, mole ratio) were used. AlN-polytypes were produced by nitriding the mixture at 175$0^{\circ}C$~190$0^{\circ}C$ under N2 atmosphere. For lower reaction temperature, 15R phase was produced and in the case of higher reaction temperature, AlN phase was only produced. As each composition was heated at 185$0^{\circ}C$ in N2 atmosphere, produced main phases were 15R phase for composition A and 21R phase for composition B respectively. The fracture surfaces of produced reactants showed porous skeleton structure.

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Some Relationships between Measurement Capability Indices of Type 1 Study, Gage R&R Study, and ISO 22514-7 (Type 1 Study, Gage R&R Study와 ISO 22514-7의 측정능력지수 간 연관성 분석)

  • Lee, Seung-Hoon;Lim, Keun
    • Journal of Korean Society for Quality Management
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    • v.44 no.1
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    • pp.77-94
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    • 2016
  • Purpose: This paper reviews Type 1 Gage study, Gage R&R study, and procedure of ISO 22514-7 for assessing a measurement system, and discusses some relationships between the measurement capability indices. Methods: The gage capability index $C_g$ of Type 1 Gage study, precision-to-tolerance ratio PTR of Gage R&R study, and measurement performance ratio $Q_{MS}$ and $Q_{MP}$ of ISO 22514-7 are considered in this paper. Results: This paper derives the relationships between $C_g$ and $Q_{MS}$, PTR and $Q_{MP}$, and $Q_{MS}$ and $Q_{MP}$, respectively, and discusses the acceptance conditions for each procedures. Conclusion: The measurement capability analysis is the first step for the quality improvement of the manufacturing processes. Therefore the result of this study provides a helpful guidelines for assessing the measurement system, enabling proper evaluation of manufacturing processes.