• 제목/요약/키워드: C/N RATIO

검색결과 2,893건 처리시간 0.037초

Electroluminescence characteristics of organic light-emitting diodes with TPD doped PVK as the hole transport layer

  • Shin, Y.C.;Song, J.H.;Lee, C.H.
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.II
    • /
    • pp.1404-1407
    • /
    • 2005
  • We have fabricated organic light-emitting diodes using poly(N-vinylcarbazole)(PVK) doped with N,N'- diphenyl-N,N'-bis(3-methylphenyl)-[l,l'-biphenyl]- 4,4/-diamine (TPD) as the hole transport layer. TPD molecules act as the trapping sites in PVK and reduce the hole mobility, which can enhance the electronhole balance in the emitting layer, resulting in the enhanced device performance. We have found the optimum ratio of TPD to PVK for the EL efficiency.

  • PDF

구리배선용 베리어메탈로 쓰이는 Ta-N/Ta/Si(001)박막에 관한 X-선 산란연구 (X-ray Scattering Study of Reactive Sputtered Ta-N/Ta/Si(001)Film as a Barrier Metal for Cu Interconnection)

  • 김상수;강현철;노도영
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2001년도 춘계학술대회 논문집 반도체재료
    • /
    • pp.79-83
    • /
    • 2001
  • In order to compare the barrier properties of Ta-N/Si(001) with those of Ta-N/Ta/Si(001), we studied structural properties of films grown by RF magnetron sputtering with various $Ar/N_2$ ratios. To evaluate the barrier properties, the samples were annealed in a vacuum chamber. Ex-situ x-ray scattering measurements were done using an in-house x-ray system. With increasing nitrogen ratio in Ta-N/Si(001), the barrier property of Ta-N/Si(001) was enhanced, finally failed at $750^{\circ}C$ due to the crystallization and silicide formation. Compared with Ta-N/Si(001), Ta-N/Ta/Si(001) forms silicides at $650^{\circ}C$. However it does not crystallize even at $750^{\circ}C$. With increasing nitrogen composition in Ta-N/Ta/Si(001), the formation of tantalum silicide was reduced and the surface roughness was improved. To observe the surface morphology of Ta-N/Ta/Si(001) during annealing, we performed an in-situ x-ray scattering experiment using synchrotron radiation of the 5C2 at Pohang Light Source(PLS). Addition of Ta layer between Ta-N and Si(001) improved the surface morphology and reduced the surface degradation at high temperatures. In addition, increasing $N_2/Ar$ flow ratio reduced the formation of tantalum silicide and enhanced the barrier properties.

  • PDF

폐기물의 퇴비화 과정중 물질 변화;3. C/N 율 변화 (Changes of Chemical Compounds in Compost of Municipal Refuse;3. Changes of C/N Ratios in Compost)

  • 서정윤
    • 한국환경농학회지
    • /
    • 제8권1호
    • /
    • pp.55-59
    • /
    • 1989
  • 퇴비중의 정확한 C/N율은 미생물이 이용할 수 있는 탄소와 비로서 결정하여야 하기 때문에 본 시험에서는 일반적으로 C/N율을 결정하기 위하여 사용하는 Kjeldahl방법과 아질산과 질산도 동시에 분석되는 질소 분석방법인 Forster 방법으로 병행하여 질소 함량을 분석하고 이들 함량으로 부터 얻어진 퇴비 중의 C/N율 변화를 조사하였으며 그 결과는 다음과 같다. 1. 퇴비화 기간에 따라 두 질소 분석 방법에서 얻어진 C/N율이 모두 점차 감소하였으며 퇴비화 초기 2주까지 급격히 감소한 후 2주와 6주사이에 약간 증가 내지 일정하게 유지하다가 이후부터 완만하게 감소하는 경향이었다. 2. 퇴비화 기간에 따라 두 질소 분석 방법에서 분석된 퇴비 종류의 질소와 탄소로부터 얻어진 모든 C/N율을 비교할 때 Kjeldahl 방법에 의한 C/N율이 $F{\"{o}}rster$ 방법에 의한 C/N율 보다 높았다. 3. 통상 퇴비 중 C/N율 계산을 위하여 질소 분석 방법으로 사용하는 Kjeldahl 방법에서 얻은 총 질소와 총 탄소로 부터 얻어진 C/N율이 $F{\"{o}}rster$방법에 의한 미생물이 이용할 수 있는 질소와 미생물이 이용할 수 있는 탄소로 부터 얻어진 C/N율보다 C/N율로서 5백분율로 36% 높았다. 4. 총 찬소와 Kjeldahl 방법에 의한 총 질소 간의 C/N율, 미생물이 이용할 수 있는 탄소와 Kjeldahl 방법에 의한 미생물이 이용할 수 있는 질소간의 C/N율, 총 탄소와 $F{\"{o}}rster$ 방법에 의한 총 질소간의 C/N율 및 미생물이 이용할 수 있는 탄소와 $F{\"{o}}rster$ 방법에 의한 미생물이 이용할 수 있는 질소간의 C/N율간에 서로 서로 고도의 유의적인 정(+)의 상관이 있었다.

  • PDF

Cucumber Growth and Nitrogen Uptake as Affected by Solution Temperature and NO3-:NH4+ Ratios during the Seedling

  • Yan, Qiu-Yan;Duan, Zeng-Qiang;Li, Jun-Hui;Li, Xun;Dong, Jin-Long
    • 원예과학기술지
    • /
    • 제31권4호
    • /
    • pp.393-399
    • /
    • 2013
  • The effect of solution temperature and nitrogen form on cucumber (Cucumis sativus L.) growth, photosynthesis and nitrogen metabolism was investigated in hydroponic culture. Cucumber plants were grown for 35 days in a greenhouse at three constant solution temperatures ($15^{\circ}C$, $20^{\circ}C$, and $25^{\circ}C$) within a natural aerial temperature ($15-30^{\circ}C$). Four nitrate:ammonium ($NO{_3}^-:NH{_4}^+$) ratios (10:0, 8:2, 5:5, and 2:8 $mmol{\cdot}L^{-1}$) at constant nitrogen (N) concentration of $10mmol{\cdot}L^{-1}$ were applied within each solution temperature treatment. Results showed an increasing solution temperature enhanced plant growth (height, dry weight, and leaf area) in most N treatments. Dry weight accumulation was greatest at the 10:0 $NO{_3}^-:NH{_4}^+$ ratio in the $15^{\circ}C$ solution, the 5:5 ratio in the $20^{\circ}C$ solution and the 8:2 ratio in the $25^{\circ}C$ solution. Photosynthetic rate (Pn) response to solution temperature and $NO{_3}^-:NH{_4}^+$ ratio was similar to that of plant growth. Probably, the photosynthate shortage played a role in the reduced biomass formation. Increasing solution temperature enhanced the nitrate reductase (NR) activity, and further reduced shoots nitrate content. Our results indicate that the optimal ratio of nitrate to ammonium that promotes growth in hydroponic cucumber varies with solution temperature.

Hybrid Plasma Processing에 의한 Si3N4-SiC계 미립자의 합성과정 제어 (Process Control for the Synthesis of Ultrafine Si3N4-SiC Powders by the Hybrid Plasma Processing)

  • 이형직
    • 한국세라믹학회지
    • /
    • 제29권9호
    • /
    • pp.681-688
    • /
    • 1992
  • Ultrafine Si3N4 and Si3N4+SiC mixed powders were synthesized through thermal plasma chemical vapor deposition(CVD) using a hybrid plasma, which was characterized by the supersposition of a radio-frequency plasma and arc jet. The reactant SiCl4 was injected into an arc jet and completely decomposed in a hybrid plasma, and the second reactant CH4 and/or NH3 mixed with H2 were injected into the tail flame through double stage ring slits. In the case of ultrafine Si3N4 powder synthesis, reaction efficiency increased significantly by double stage injection compared to single stage one, although crystallizing behaviors depended upon injection speed of reactive quenching gas (NH3+N2) and injection method. For the preparation of Si2N4+SiC mixed powders, N/C composition ratio could be controlled by regulating the injection speed of NH3 and/or CH4 reactant and H2 quenching gas mixtures as well as by adjusting the reaction space.

  • PDF

n-6/n-3 지방산 비율이 비만 랫드의 지질대사에 미치는 영향 (Effect of n-6/n-3 fatty acid ratio on lipid metabolism in obesity model rats)

  • 신종서;엄경환;박병성
    • 한국응용과학기술학회지
    • /
    • 제35권3호
    • /
    • pp.654-666
    • /
    • 2018
  • 본 연구는 비만 모델동물 랫드에서 식이 내 오메가 6와 3 지방산 비율(n-6/n-3 0, 4:1, 15:1, 30:1)이 지질대사의 생화학적 메카니즘을 구명하였다. 혈액 중성지방은 대조군과 비교할 때 n-6/n-3 비율 4:1, 15;1, 30:1 처리군에서 22.21%, 총콜레스테롤 20.60%, LDL-C 52.96%, 혈당 15.71%, ALT 11.97%, AST 9.13%, 인슐린 37.57%, 렙틴 45.98% 낮아졌으나, HDL-C 28.38%, 인지질 80.39% 증가하였고, 특히 4:1 처리군에서 가장 큰 효과가 나타났다. 간 조직에서 SREPB-$1{\alpha}$, SREPB-2 mRNA는 대조군과 비교할 때 n-6/n-3 비율 처리군에서 하향조절 하였으나 PPARs 그리고 지방조직의 LPL-mRNA는 상향조절 하였다. 간 조직에서 지방세포의 크기는 n-6/n-3 비율 30:1, 대조군, 15:1, 4:1 순서로 낮아졌고, 지방조직에서 지방세포의 크기는 대조군, 30:1, 15:1, 4:1 순서로 낮았다. 결과는 비만 모델동물 랫드에서 오메가 6와 오메가 3 지방산 비율, 특히 4:1을 함유하는 식이를 급여하면 혈액 유해 지질, 간 기능 효소, 렙틴, 인슐린, 간과 지방조직의 유전자 발현 조절을 통하여 건강을 유지할 수 있다는 새로운 사실을 발견하였다.

PSN-PMN-PZT 세라믹스의 유전 및 압전 특성과 공진 주파수의 온도안정성 (Dielectric, Piezoelectric Properties and Temperature Stability of Resonant Frequency in PSN-PMN-PZT Ceramics)

  • 윤광희;류주현;민석규;이명수;서성재
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
    • /
    • pp.391-395
    • /
    • 2000
  • In this study, the temperature coefficient of resonant frequency(TC $F_{r}$), dielectric and piezoelectric properties of Pb[(S $b_{1}$2/N $b_{1}$2/)$_{0.0035}$-(M $n_{1}$3/N $b_{2}$3/)$_{0.0065}$-(Z $r_{x}$ $Ti_{1-x}$ )$_{0.90}$] $O_3$ceramics is investigated with Zr/Ti ratio. The dielectric constant and electromechanical coupling factor( $k_{p}$) showed the highest values of 1257, 0.562 respectively when the Zr/Ti ratio is 49.5/50.5. The mechanical quality factor( $Q_{m}$) is the lowest value of 713 when the Zr/Ti ratio is 49.5/50.5, and increased with the decrease of the Zr/Ti ratio. The temperature coefficient of resonant frequency(TC $F_{r}$) change abruptly at the morphotropic phase boundary(MPB), which is between the rhombohedral phase with highly negative TC $F_{r}$ of -106ppm/$^{\circ}C$ and the tetragonal phase with highly positive TC $F_{r}$ of +64pp $m^{\circ}C$ as Zr/Ti ratio changes from 50/50 to 49.5/50.5.50.5..5.50.5.5.

  • PDF

실내실험을 통한 김해점토의 투수특성 평가 (Evaluation of Permeability Characteristics of Kimhae Clay by Laboratory Tests.)

  • 김동휘;임형덕;김진원;이우진
    • 한국지반공학회:학술대회논문집
    • /
    • 한국지반공학회 2000년도 봄 학술발표회 논문집
    • /
    • pp.647-654
    • /
    • 2000
  • During consolidation, the permeability of clay decreases with void ratio because of the reduction in total void space. After Kozeny(1927) and Carman(1956), many researchers have proposed the relations between void ratio and permeability. Most of the relations are expressed in the following forms as : (1) log e - log k(1+e), (2) e - log k, or (3) log e - log k. These relations have been found valid for a large number of normally consolidated clays. From laboratory test(CRS and I $L_{CON}$) results, the relation between void ratio and permeability of Kimhae clay was well defined in all of the three forms. Permeability change index, $C_{k}$, of Kimhae clay was in the range of 0.64~1,03 and average value of $C_{k}$ was 0.821. And the test results satisfied the experimental correlation between $C_{k}$ and e, $C_{k}$=0.5e. In log e - log k(1+e) relation, constant C was in the range of 1.91~4.74$\times$10$^{-8}$ cm/sec and n was in the range of 3.74~4.60.c and n was in the range of 3.74~4.60.74~4.60.0.

  • PDF

무기질소원의 종류에 따른 염조류 Anabaena flos-aquae 광합성의 특성 (Photosynthetic Characteristics of Anabaena flos-aquae Growing on Various Inorganic Nitrogen Sources)

  • 맹주선
    • Journal of Plant Biology
    • /
    • 제25권4호
    • /
    • pp.153-160
    • /
    • 1982
  • The kinetics of $^{14}C$ fixation have been investigated in Anabaena flos-aquae growing on ${NH}_4+$,$NO_3-$ and $NO_2-N$ in batch cultures. Growth rate was highest with ${NH}_4+$, followed by $NO_2-$ and finally $NO_2$. The compensation intensity($I_0$) and the half-saturation irradiance($K_1$) with $K_1$ were higher than with other N sources, but the maximum C fixation rate($P_{max}$) was lower. The ($P_{max}$)/$K_1$ ratio, which is analogous to quantum efficiency at low irradiance ranges, was also lower with $N_2$. All these parameters except $K_1$ decrease with culture age, or decreasing growth rate. Since $^{14}C$ uptake measures net photosynthesis, the higher values of $I_0$ and $K_1$, and the low values of $P_{max}$/$K_1$ ratio with $N_2$ appear to be related to the high energy demand of $N_2$fixation. They may also be related to the lox maximum growth rate with $NO_2-N$.

  • PDF

축분의 퇴비화를 위한 최적 환경조건 (Optimum Environmental Conditions for Composting of Livestock Manure)

  • 임재명;한동준;강현재
    • 산업기술연구
    • /
    • 제13권
    • /
    • pp.3-17
    • /
    • 1993
  • The composting process is a suitable to dispose the livestock manure in terms of resources recovery. However the performence of composting process is greatly affected by the environmental conditions such as characteristics of manure, type of the bulking agent, initial moisture contents, temperature, recycle and so on. The purpose of this study is to evaluate the optimum environmental conditions of composting process for livestock manures. The analytical results indicated that no bulking agent was necessary for the cow manure because of the proper C/N ratio. However the pig manure required a bulking agent since the pig manure had not only low in C/N ration but poor ventilation characteristics. In addtion, the initial miosture content for optimum composting appeared to be about 60%. The temperature control was also an essential factor to enhance the activity of thermophilic microorganisms in the laboratory composting unit. It was further found that the recycle of composts may contributed the completion of composting precess as well as C/N ratio reduction and moisture control.

  • PDF