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Effect of Si/α-Si3N4 Ratio on the Shape of Silicon Nitride Particles Produced by SHS Method

  • Kim, Min-Sung;Park, Dong-Soo;Han, Byung-Dong;Kim, Hai-Doo;Park, Chan
    • Journal of the Korean Ceramic Society
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    • v.39 no.3
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    • pp.217-221
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    • 2002
  • Si and ${\alpha}-Si_3N_4$ powder mixtures added with 3 wt% $Y_2O_3$ were reacted under 5 MPa nitrogen pressure. The reaction products contained ${\alpha}-Si_3N_4$ particles with elongated shapes. Length and width of the elongated grains were the maximum when the starting powder mixture of 50 wt% Si - 47 wt% ${\alpha}-Si_3N_4$ and 3 wt% $Y_2O_3$ was used. Aspect ratio of the elongated grains were between 4.4 and 5. When the starting powder mixture contained 70 wt% Si, large particles with irregular shapes appeared. Meanwhile, the reaction did not proceed when the starting powder mixture contained 30 wt% Si and less. The SHS product was easy to crush and the elongated particles obtained from the starting powder mixtures of 40 wt% Si - 57 wt% ${\alpha}-Si_3N_4$ - 3 wt% $Y_2O_3$ and 50 wt% Si - 47 wt% ${\alpha}-Si_3N_4$ - 3 wt% $Y_2O_3$ were good candidates for the seeds.

VOCs Emission Characteristics of Coating Materials for Wood Finishing (목재용 마감도료의 휘발성유기화합물 방출특성)

  • Park, Sang-Bum;Lee, Min;Lee, Sang-Min;Kang, Yeong-Seok
    • Journal of the Korea Furniture Society
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    • v.26 no.1
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    • pp.22-30
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    • 2015
  • In order to prevent decay, distortion, bending, twist on wood products such as wooden furnitures, variety of coating materials were developed and used so far. The coating materials for wood finishing can be synthesized by natural resource or petroleum. However, these coating materials can cause contamination of indoor air quality due to emission of volatile organic compounds (VOCs). In this study, commercialized coating materials for wood finishing such as varnish, coat, and stain were evaluated on emission characteristics of VOCs. Among the varnish, eco-friendly products had about 15~46% lower TVOC emission ($1,042{\mu}g/m^2h{\sim}3,257{\mu}g/m^2h$, respectively, than typical product ($7,100{\mu}g/m^2h$). Natural resource based coating material showed lowest TVOC emission level. However, one of natural resource based waterborne stain showed higher TVOC emission level because waterborne stain already contained higher amount of natural VOC. Oil-based stain might not be suitable for indoor use on interior wall and furniture due to exceed amount of TVOC. Based on results, natural resource based coat or waterborne stain are recommenced to use on wood products.

Life cycle analysis of concrete and asphalt used in road pavements

  • lvel, Jocelyn;Watson, Rachel;Abbassi, Bassim;Abu-Hamatteh, Ziad Salem
    • Environmental Engineering Research
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    • v.25 no.1
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    • pp.52-61
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    • 2020
  • The article examines the impact differences between producing concrete and asphalt. Both materials are widely used in the construction industry. Construction activities account for a large portion of greenhouse gases. Therefore, it is important to consider the Life Cycle Analysis (LCA) to reduce environmental impacts. In this study, the material processes were inputted into an LCA program called SimaPro. The database used for the study was Ecoinvent as it is one of the major databases within SimaPro. The materials were compared against impacts per kg of material produced as the functional unit. Each process was created using the materials, energy and transportation required to produce the materials. Waste streams were also included in the process to determine the impacts after the product was done with its useful life. Using the ReCiPe method, an LCA was conducted. Midpoint and endpoint categories were examined for both the productions. The processes had similar results for the human health and ecosystems categories; however asphalt was marginally higher for both. Asphalt had exceeded concrete in the resource impact category by 100 mPt. The results indicate that concrete is the more sustainable building material. Determination of various impacts of the materials is important for material selection.

Effect of high energy ball milling on the structure of iron - multiwall carbon nanotubes (MWCNT) composite

  • Kumar, Akshay;Pandel, U.;Banerjee, M.K.
    • Advances in materials Research
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    • v.6 no.3
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    • pp.245-255
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    • 2017
  • High energy ball milling is employed to produce iron matrix- multiwall carbon nanotube (MWCNT) reinforced composite. The damage caused to MWCNT due to harsh ball milling condition and its influence on interfacial bonding is studied. Different amount of MWCNT is used to find the optimal percentage of MWCNT for avoidance of the formation of chemical reaction product at the matrix - reinforcement interface. Effect of process control agent is assessed by the use of different materials for the purpose. It is observed that ethanol as a process control agent (PCA) causes degradation of MWCNT reinforcements after milling for two hours whereas solid stearic acid used as process control agent, allows satisfactory conservation of MWCNT structure. It is further noted that at a high MWCNT content (~ 2wt.%), high energy ball milling leads to reaction of iron and carbon and forms iron carbide (cementite) at the iron-MWCNT interface. At low percentage of MWCNT, dissolution of carbon in iron takes place and the amount of reinforcement in iron matrix composite becomes negligibly small. However, under the present ball milling condition (ball to metal ratio~ 6:1 and 200 rpm vial speed) iron-1wt.% MWCNT composite of good interfacial bonding can retain the tubular structure of reinforcing MWCNT.

Analysis of Auxiliary Device in a Gas-solid Cyclone by Experimental and Computational Approaches

  • Lee, Ju-Yeol;Park, Duck-Shin;Jo, Young-Min
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.E1
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    • pp.21-28
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    • 2003
  • An auxiliary device, called Post Cyclone (PoC). had been introduced and primarily examined in earlier works which proved the reduction of the emission of fine dust from the gas-solid cyclones without incurring significant increase of cost and pressure drop. It has been known that the PoC has some advantages over other secondary dust treatment devices such as (a) simple design, (b) low cost of manufacture, (c) minimum additional pressure drop, (d) high recoverbility of the product dust, and (e) simplicity of operation. Despite the potential advantage, however, lack of practical data confined its plausible application in wide areas. Thus, in this work, a few serial experiments were conducted in terms of a few operation conditions, and the particle trajectories throughout the cyclone set-up were visually analyzed by using a commercial computer simulation program (FLUENT).

A Study on the VOCs Emission Characteristics in Leather Industries (피혁산업장의 휘발성유기화합물(VOCs) 배출 특성에 관한 연구)

  • Kim, Sun-Tae;Choi, Il-Hwan;Lee, Kyu-Sung
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.3
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    • pp.332-343
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    • 2007
  • The concentrations of major volatile organic compounds (VOCs) were measured using a passive sampler in the leather industries, Shihwa and Banwol industrial complex. The leather industries were classified into four groups in raw materials and main product. The concentrations of total VOCs measured in process for ${\ulcorner}$ manufacture of reconstituted leather and special treated leather${\lrcorner}$was highest. The main VOCs measured in the leather industries was found to be toluene with a average concentration of 1,200 ppb. The major group selected in the leather industries was divided into three groups by the fingerprint analysis and the principal component analysis. The major VOCs in the groups classified by fingerprint analysis were found to be dependent on the characteristics of raw materials and main products.

The Prediction of the Results of Drop Test Through Shock Analysis (충격해석을 통한 결과의 예측)

  • 박용석;홍성철;박철희;이우식;조항법
    • Journal of KSNVE
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    • v.4 no.3
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    • pp.345-352
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    • 1994
  • Electronic products can be subjected to many different forms of shock. These shocks are usually experienced during transporting the electronic products from a manufacturer to customers. Drop tests are performed to test the product fragility before shipment. Package cushioning materials are often used to protect electronic products from severs shock environments. In the present paper, an algorithm to predict the shock responses of the main mechanical parts is developed by use of the shock analysis in which the modal parameters extracted from vibration test are used. These results are in good agreement with the results of drop test. By use of the shock response prediction algorithm developed herein, it is possible to predict the results of drop test at various drop directions and also to select the optimal package cushioning materials.

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Development of thermo-sensor used liquid crystal-polymer composite films (온도센서로서 액정잉크의 개발)

  • 남수용
    • Journal of the Korean Graphic Arts Communication Society
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    • v.16 no.1
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    • pp.25-38
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    • 1998
  • The developing agent is the materials which first acts on silver grain and make it into metallic silver by reducing reaction. There are several types in developing agent, and according to Lumiere-Andresen principle, substitution product which has amino or hydroxyl group in benzen nucleus has a developing power, but all reduing substances are not in used. In the developing effect, not only the role of developing agent but also that of assistant materials are important. But in this work, we have studied effect, change by lith developing agent which require high contrast image. We made an developing experiment after having manufactured developing solution used hydroquinone and another developing agents like chlorohydroquinone, pyrocatechol and pyrogallol as developing agent. And we added that did in addition of diethanolamine and ascorbic acid, and then we examined the possibility of use.

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Proposal of the Stress Wave Concept and Its Applied Study as a Theory for the Dislocation Formation (전위생성에 대한 이론으로서의 응력파 개념에 대한 제안 및 적용 연구)

  • 서정현
    • Transactions of Materials Processing
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    • v.10 no.6
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    • pp.449-456
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    • 2001
  • The concept of stress wave was introduced through the quantized kinetic energy which is related to the potentional energy change of atom, molecular bond energy. Differentiated molecular bond energy $\varphi$() by the lst order displacement u becomes force F(F = d$\varphi$($u_i$)/du), if resversely stated, causing physically atomic displacement $u_i$. Such physical phenomena lead stress(force/area of applied force) can be expressed by wave equation of linearly quantized physical property. Through the stress wave concept, formation of dislocation, which could not explained easily from a theory of continuum mechanics, can be explained. Moreover, this linearly quantized stress wave equation with a stress concept for grains in a crystalline solid was applied to three typical metallic microstructures and a simple shape. The result appears to be a product from well treated equations of a quantized stress wave. From this result, it can be expected to answer the reason why the defect free and very fine diameters of long crystalline shapes exhibit ideal tensile strength of materials.

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Dental biomaterials for chairside CAD/CAM: State of the art

  • Lambert, Hugo;Durand, Jean-Cedric;Jacquot, Bruno;Fages, Michel
    • The Journal of Advanced Prosthodontics
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    • v.9 no.6
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    • pp.486-495
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    • 2017
  • The wide use of chairside CAD/CAM restorations has increased the diversity of the restorative material. For the practitioner, the selection of the appropriate material is difficult amongst the variety offered by the market. Information on the characteristics of the products can be difficult to assess due to the lack of up-to-date classification and the lack of reliability of manufacturer's advertising. The purpose of this article is to structure the data on restorative materials provided by various sources in order for the practitioner to choose the product most suited to the clinical situation. The objective is to classify chairside CAD/CAM materials and to define their characteristics and indications.