• Title/Summary/Keyword: Butadiene-nitrile

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Characteristics of Complex Foaming Composites' Normal Pressure Foaming of Using Rubber and Bio-Degradable Materials

  • Dong Hun Han;Young Min Kim;Dan Bi Lee;Kyu Hwan Lee;Han-Seong Kim
    • Korean Journal of Materials Research
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    • v.33 no.8
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    • pp.323-329
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    • 2023
  • There are many types of foam molding methods. The most commonly used methods are the pressure foaming method, in which foam resin is mixed with a foaming agent at high temperature and high pressure, and the normal pressure foaming method, which foams at high temperature without pressure. The polymer resins used for foaming have different viscosities. For foaming under normal pressure, they need to be designed and analyzed for optimal foaming conditions, to obtain resins with low melt-viscosity or a narrow optimal viscosity range. This study investigated how changes in viscosity, molding temperature, and cross-link foaming conditions affected the characteristics of the molded foam, prepared by blending rubber polymer with biodegradable resin. The morphologies of cross sections and the cell structures of the normal pressure foam were investigated by SEM analysis. Properties were also studied according to cross-link/foaming conditions and torque. Also, the correlation between foaming characteristics was studied by analyzing tensile strength and elongation, which are mechanical properties of foaming composites.

Finite Element Analysis on the Deformation Behavior Stability of Contact Sealing Rings (접촉식 밀봉 링의 변형거동 안정성에 관한 유한요소해석)

  • Kim, Chung Kyun;Kim, Do Hyun
    • Journal of the Korean Institute of Gas
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    • v.16 no.5
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    • pp.47-51
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    • 2012
  • In this study, the deformation behavior stability of sealing rings with three different cross sectional areas has been presented using a FEM technique. To investigate the deformation behavior stability, the initial compression rate of 25% has been applied to the sealing ring, which is molded with a nitrile butadiene rubber. The maximum strain, maximum stress, and maximum contact normal stress have been analyzed for the working fluid pressure of $25kgf/cm^2$. The FEM results show that the maximum strain of a hollow o-ring and a hollow rectangular ring with a hollow space in the center of a sealing ring is higher than that of a conventional o-ring, but the maximum stress and the maximum contact normal stress are low. In these results, the sealing rings with a hollow space in the center of the cross sectional area is recommended to increase an extended endurance stability of sealing rings. But, the solid sealing ring is designed to guarantee the sealing safety of a contact sealing ring.

The Effect of Fillers on Rubber Characteristics for Gasket to Lithium Ion Battery (리튬이온 전지용 가스켓 고무의 특성에 미치는 충전제의 영향)

  • Seo, Kwan-Ho;Cho, Kwang-Soo;Yun, In-Sub;Choi, Woo-Hyuk;Hur, Byung-Ki;Kang, Dong-Gug
    • Polymer(Korea)
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    • v.34 no.5
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    • pp.430-433
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    • 2010
  • The gasket materials of for the lithium ion battery requires chemical resistance to electrolyte, electrical insulating, compression set, anti-contamination and low temperature property. To check the special characteristics of fillers which are applied to rubber for gasket, compound of EPDM, NBR and FKM (fluoro elastomer) were made by adjusting weights of carbon black and silica additive. Using these compounds, we had done tests of long-term stability against electrolyte, compression set and low-temperature property with considering operating condition of the lithium ion battery. From this test, we investigated the physical and chemical characteristics of rubber with using of carbon black and silica additive in each.

A Study on the Emission Changes in Reduction Chemical Substances in Korea (유해화학물질 배출량 변화에 관한 연구: 배출저감계획서 작성 대상물질 중심으로)

  • Im, JiYoung;Lee, MyeongJi;Kim, HyunJi;Ryu, JiSung;Yun, DaeSik;Jang, YongChul;Lee, ChungSoo
    • Journal of Environmental Health Sciences
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    • v.46 no.2
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    • pp.159-169
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    • 2020
  • Objectives: The purpose of this study was to investigate changes among the nine kinds of reduction chemical substances in Korea over the period of 2008-2017. We will define basic data for improving the management methods for reducing chemical substances. Methods: A survey of hazardous pollutant emissions for 2008-2017 was conducted through the pollutant Release and Transfer Register homepage. Nine kinds of designated reduction chemical substances (Benzene, Vinyl chloride, Trichloro ethylene, 1,3-butadiene, Dichloro methane, Tetrachloro ethylene, N,N-dimethylformamide, Acrylo nitrile, and Chloroform) provided the study subjects. The emission of hazardous chemicals and health effects used the National Health Statistics and Integrated Chemicals Information System (ICIS) as a reference. Results: Hazardous pollutant emissions increased by 1.2 times over the past decade, and nine types of reduction chemical substances increased by 1.6 times. By region, the emissions of reduction chemical substances over the last 10 years were in the order of Chungbuk, Gyeonggi, and Gyeongbuk. Emissions of Dichloro methane was the highest in Chungbuk and Gyeongbuk. N,N-dimethylformamide was the highest in Gyeonggi. Carcinogen pollutant emissions showed a tendency to increase continuously. In addition, group 1 carcinogen emissions showed a tendency to decrease. Conclusion: In the last decade, the amount of hazardous chemical emissions has been continuously increasing. Hazardous chemical emissions require facility improvement for continuous emissions reduction. More research on reduction of emissions is needed.

Deposition of Uranium Ions with Modified Pyrrole Polymer Film Electrode (우라늄이온 포집을 위한 수식된 피를 고분자 피막전극)

  • Cha Seong-Keuck;Lee Sang Bong
    • Journal of the Korean Electrochemical Society
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    • v.3 no.3
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    • pp.141-145
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    • 2000
  • Anodically Polymerized conducting Polypyrrole film electrode was employed to Pick up uranyl ion with the type of Gr/ppy, xylenol orange modified electrode. To have Porous and oriented ppy film, NBR was applied as precoating agent. The rate constant of polymerization was $3.22\times10^{-3}s^{-1}$ which was 1.6 times smaller value than bare graphite surface. The deposited amount of uranyl iou on $1.70Ccm^{-2}$ of ppy was $1.55\times10^{-4}g$. The matrix effect in artificial seawater was $6.8\%$. The polymer film electrode has a diffusion controlled process in conduction, but the modified Gr/ppy, $X.O^{4-}UO^+$ type was influenced on the ion doping and electronic conduction of film itself owing to increasing of impedance. The capacitance of electrical double layer was respectively enhanced to 56 and 130 times in Gr/ppy, $X.O.^{4-}$ and Gr/ppy, $X.O^{4-}UO^+$ than Grippy type electrode.

The Study of Characteristics on EPDM, NBR, FKM, VMQ and FVMQ for Sealing Applications to Lithium Ion Battery (리튬 이온 전지 씰링에의 응용을 위한 EPDM, NBR, FKM, VMQ 및 FVMQ 특성연구)

  • Seo, Kwan-Ho;Cho, Kwang-Soo;Yun, In-Sub;Choi, Woo-Hyuk;Hur, Byung-Ki;Kang, Dong-Gug
    • Elastomers and Composites
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    • v.45 no.3
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    • pp.212-216
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    • 2010
  • The materials of the lithium ion battery gasket require chemical resistance to the electrolyte, electrical insulating, compression set, anti-contamination and heat resistance. To estimate suitability for rubber which has better performance to compression set than PFA, each compound were made with various rubbers, such as EPDM, NBR, FKM, FVMQ, VMQ and we checked the characteristics of each compound. Samples from each compound was deposited in Propylene Carbonate and tested for changing of Hardness and Volume during 1,000 hr with $80^{\circ}C$. EPDM and VMQ showed good performance to chemical resistance to the electrolyte, and also we could get the values over $10^{10}{\Omega}cm$ on volume resistance basis in electrical insulating. EPDM and VMQ were judged as the most suitable material.

Optimum Design of Cross Section Lateral Damper Oil Seals for High Speed Railway Vehicle (고속 철도 차량 횡댐퍼 오일 씰의 형상 단면 최적설계)

  • Hwang, Ji-Hwan;Kim, Chul-Su
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.1
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    • pp.579-584
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    • 2017
  • The damper oil seal of a high-speed railway vehicle is made from nitrile butadiene rubber (NBR) in order to prevent lubricant from leaking into the damper and to stop harmful contaminants from entering the external environment while in service. Oil leakage through the seal primarily occurs from fatigue failure of the damper. Cumulative damage of the seal occurs due to the contact force between the rod and the rubber during movement due to track irregularities and cants, among other factors. Thus, the design of the oil seal should minimize the maximum principal strain at weak points. In this study, the optimal cross section of the damper oil seal was found using the multi-island genetic algorithm method to improve the durability of the damper. The optimal shape of the oil seal was derived using process automation and design optimization software. Nonlinear material properties for finite element analysis (FEA) of the rubber were determined by Marlow's model. The nonlinear FEA confirmed that the maximum principal strain at the oil leakage point was decreased 24% between the initial design and the optimum design.

A Study on the Life-time Prediction for the Rubber O-ring applied to decoy through the Accelerated Life Test (기만기 적용 고무 O-ring의 온도에 따른 가속수명시험을 통한 수명예측에 관한 연구)

  • Jo, Hee-Jin;Kim, Minwoo;Gwak, Hyerim
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.10
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    • pp.182-188
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    • 2016
  • A decoy is a weapon system that can protect vessels from an enemy's torpedo. Thus, the decoy should be able to operate in the field without any failure. Because the decoy can be inoperable once its sealing is broken and water permeates inside the system, the hermetic sealing capability considering the operational environment is mandatory. To be hermetically sealed, a rubber-type O-ring is generally used in a decoy system. The sealed performance of rubber-type products, however, tends to age and deteriorate with time. Therefore, the O-ring needs to be maintained or changed periodically. This paper proposes a method to estimate the proper maintenance period using the hardness and elongation percentage, which represents the performance of the O-ring product and test data from Accelerated Life Test (ALT) of the product. The O-ring used in this paper is a NBR type, and the temperature was chosen to be the main accelerating factor as referenced in many studies. The criteria for the failure of the O-ring was set for the product to be 50% degraded compared to the initial performance. In addition, the Korean standard KS M 6518 was adopted and referenced for the preparation of test samples and the calculation of estimates. The O-ring's predicted life was simulated by analyzing the test results from a computer program, and the optimized maintenance period for the product was determined.