• Journal of Welding and Joining
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• v.25 no.4
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• pp.42-48
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• 2007

An inert gas atomized NiTiZrSiSn bulk metallic glass feedstock was sprayed onto the copper plate using vacuum plasma spraying process. In order to change the in-flight particle energy, that is, thermal energy, the hydrogen gas flow rate in plasma gas mixture was increased at the constant flow rate of argon gas. Coating and single pass spraying bead were produced with the least feeding rate. Regardless of the plasma gas composition, fully melted through unmelted particle could be observed on the overlay coating. However, the frequency of the unmelted particle number density was increased with the decrease of the hydrogen gas flow rate. The amorphous phase fraction within coating was also affected by the number density of the unmelted particle.

• Textile Coloration and Finishing
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• v.33 no.3
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• pp.147-152
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• 2021

Bulk polymerization was used to produce poly(vinyl acetate) with different molecular weights, which were then saponified to prepare poly(vinyl alcohol) (PVA) with different molecular weights. With P_n of 2,060 and 3,240, the optimum film formation concentrations of PVA were found 7.5wt.% and 6.5wt.%, respectively. The drawing characteristics of the PVA film prepared at the optimum film formation concentrations were experimented, as well as the thermal characteristics of the PVA film based on the drawing ratio were observed. When the drawing velocity was fixed, it was found that the drawing ratios of all samples decreased as the heat band gap increased, and the melting temperature of the PVA film slightly increased as the drawing ratio increased regardless of the P_n of PVA.

• The Journal of Engineering Research
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• v.1 no.1
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• pp.15-22
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• 1997

The crystallization behaviours of cordierite gel derived from sol-gel method and glass prepared from conventional melting method with or without $TiO_2$ as nucleants are compared. The densification temperature of gel is $810^{\circ}C$ and its chemical structure identified by IR analysis is same as that of glass melted by conventional method. The beginning crystallization temperature of gel is $965^{\circ}C$ lower than that of melted glass with 10wt% $TiO_2$, which is $978^{\circ}C$. The crystalline phases developed from gel during heat treatment are identified as spinel, $\beta$-quartz solid solution and $\alpha$-cordierite crystal and crystalline phases in case of glass are (Mg,Al)TiOn and $\beta$-quartz solid solution and $\alpha$-cordierite crystal, respectively. The crystallization in melted glass with nucleants occurs through bulk crystallization and in case of that without nucleants surface crystallization occurs, while the crystallization in gel is internal crystallization from interface between particles formed after densification.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.36 no.6
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• pp.591-598
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• 2012

In this study, the cutting characteristics of bulk metallic glass (BMG) cut using a computer numerically controlled (CNC) lathe were investigated for different insert tool materials and cutting speeds. The surface roughness, chip morphology, cutting forces, and tool wear during turning of $Zr_{50}Cu_{40}Al_{10}$ BMG alloy were examined. Four kinds of tool materials were used to cut an 8-mm-diameter BMG. The examination of the surface roughnesses of the BMG specimens machined at each cutting speed showed that the surface roughness became better as the cutting speed increased, and the tool materials also influenced the surface roughness. The chip morphology investigations showed that the unoxidized BMG chips had serrated curled chips with adiabatic shear bands, while the oxidized chips exhibited local melting and tangling rather than the usual spiral-shaped chips. The cutting force induced during machining of the Zr-based BMG was the largest for the TiN-WC tool, followed by the polycrystalline diamond (PCD) tool. The cermet tool exerted the smallest cutting force.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.48 no.4
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• pp.221-225
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• 1999

This paper shows the parameters to affect the critical characteristic of YBaCuO superconducting bulk fabricated by MPMG (Melt Powdered Melt Growth)process. In order to investigate proper processing variables, the effect of the holding time at the melting temperature and that of the slow cooling time in $O_2\; ambient\; on\; the\; J_c$ were experimented. And then with the above obtained heat treatment conditions, the effects of addition of $Y_2BaCuO_5\; and\; Ag\; on\; the\; J_c$ were also investigated. A proper slow cooling time yields phase transformation from Tetragonal $(YBa_2Cu_3O_6)$ to Orthorhombic $(YBa_2Cu_3O_7)$ during an annealing time in $O_2$. Ag addition plays a role in increasing the $T_c\; and\; the J_c$, but the magnetization decreases. The $J_c$ and the magnetization increase with addition of Y211. $J_c$ of the sample added Ag 10wt% is superiorover 3000 G. Proper holding time, slow cooling time and amount of impurity addition are important parameters in fabricating the YBaCuO bulk by MPMG process with high $J_c$.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1997.04a
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• pp.225-228
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• 1997

YBa$_2$Cu$_3$O$_{x}$ samples with different amounts of $Y_2$BaCuO$_{5}$ were prepared by MPMG (Melt Powder Melt Growth) method. The effects on the size of initial particles and Ag addition for $Y_2$BaCuO$_{5}$ distribution in YBa$_2$Cu$_3$O$_{x}$ were invesgated. The samples prepared by the melting process usually have large grains up to several ㎣ and precipitates of $Y_2$BaCuO$_{5}$. The distribution of the $Y_2$BaCuO$_{5}$ particles in the samples depends on the size of initial particles and the amounts of Ag addition.Ag addition.

• Journal of the Korean Ceramic Society
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• v.31 no.12
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• pp.1545-1551
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• 1994

Various kinetic parameters of the nucleation and crystallization in anorthite glass (CaO.Al2O3.2SiO2) were calculated by nonisothermal differential thermal analysis. Base glass and glass with TiO2 were prepared by melting. In base glass, the temperature where nucleation can occur ranges from 85$0^{\circ}C$ to 9$25^{\circ}C$ and the temperature for maximum nucleation was 900$\pm$5$^{\circ}C$. In glass with TiO2, the nucleation temperature range was 800~875$^{\circ}C$ and the maximum nucleation temperature was 850$\pm$5$^{\circ}C$. Kissinger equation, Bansal equation, and modified Ozawa equation were used for calculating activation energy for crystallization, Ec. The results showed the same activation energies for both glasses with and without TiO2 in the different equations. The shape of maximum exotherm peak and Ozawa equation were used for Avrami exponent, n. The n value for each glass was 2, indicating that each glass crystallized primarily by bulk crystallization.

• 한국초전도학회:학술대회논문집
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• v.10
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• pp.211-215
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• 2000

Bi-2212 HTS tube was fabricated by CFP(Centrifugal Forming Process). Slury was prepared in the mixing ratio of 8:2 between powder and binder and ball-milled for 24 hrs. Slurry was initially charged into the rotating mold with 300${\sim}$450 rpm and heated at the temperature ranges of 840${\sim}$860$^{\circ}$C for partial melting to finally obtain a uniformly textured tube shape. It was observed the plate-like grains with more than 20 ${\mu}$m were well oriented along the rotating axis and the measured T$_c$ was around 67K. In this paper we will discuss and analyze the tube characteristics depending on many different processing parameters such as, powder composition, binder mixing ratio between powder and binder, motor speed, heating temperature and etc.

• Journal of the Korean Ceramic Society
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• v.35 no.5
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• pp.493-498
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• 1998

ZnS doped borosilicate glass for nonlinear optical application was prepared by melting and precipitation process. The optical band gap of the precipitated ZnS particles ranged from 3.83 to 3.96 eV compared with the bulk ZnS energy gap of 3.53 eV. This result was interpreted in terms of a quantum confinement effect due to small crystal size. ZnS partilcle size estimated by effective mass approximation ranged from about 39 to 83 $\AA$ It increased wtih the increase of heat tratment time and temperature.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.13 no.9
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• pp.801-804
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• 2000

High-temperature superconductor of Bi-2212 system was fabricated by CFP(Centrifugal Forming Process). To make a uniform specimen slurry was prepared in the ratio of 7:3(powder : binder) and ball milled for 24 hours. Milled slurry was charged into a rotating mold with 450 rpm and dried at room temperature. Then the specimen was performed binder burn-out at 35$0^{\circ}C$ and heated for partial melting to 86$0^{\circ}C$. XRD analysis of most specimens were shown 2212 phase and observed a local plate shped microstructure with a well aligned c-axis direction from SEM images. Measured T$_{c}$(Critical temperature) was about 64 K.K.