• Title/Summary/Keyword: Bulk Reaction

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Growth of GaAs Single Crystal by Horizontal Bridgman method and Wetting (수평 Bridgman법에 의한 GaAs단결정 성장 및 Wetting에 관한 연구)

  • 강기문;홍봉식;한병성;온동만
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.35 no.1
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    • pp.1-7
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    • 1986
  • The GaAs bulk single crystals are grown by the Horizontal Bridgman method. During the growth, one of the problems in Bridgman method is the boat wetting between GaAs molten and silica boat. This boat wetting may result in another nucleation to form twin crystals. In this study, We find that the optimal size for sand blasting is 320 mesh. Backfilling the ampoule with argon gas during the vaccum bake-out decreaes the boat wetting. The reaction mechanism of Ga with quartz to produce suboxide, Ga2O, and sillion is discussed.

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Heat and mass transfer characteristics in steam reforming reactor (수증기 개질 반응기 내의 열 및 물질전달 특성에 관한 연구)

  • Lee, Shin-Ku;Lim, Sung-Kwang;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.340-343
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    • 2006
  • In this paper, heat and mass transfer characteristics through experimental and numerical study are extensively investigated in steam reform ins reactor under given operating conditions. In order to get simulated data at outlet of the reformer, heterogeneous reactor model is incorporated. As the reaction also takes place in porous media, two medium approach is used to take into account thermally non-equilibrium phenomena between catalyst and bulk gas. In steam reforming reaction, heat transfer issue is so significant that geometrical configuration study is also conducted.

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Electrical conductivity in oxide glasses subjected to $sodium \leftrightarrow silver$ ion exchange treatment (산화물유리에서의 $Na^+$이온과 $Ag^+$이온 교환에 따른 전기전도도 변화)

  • 한준수;강원호;이효경
    • Electrical & Electronic Materials
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    • v.9 no.3
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    • pp.284-290
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    • 1996
  • The electrical properties of bulk galsses in the system Na$_{2}$O-CaO-Al$_{2}$O$_{3}$-B$_{2}$O$_{3}$-SiO$_{2}$ containing 20 to 30mol% sodium which have been subjected to a sodium .tautm. silver ion exchange reaction for 24, 36 and 48 hrs. were analysed by impedance spectroscopy method. Ion exchanged glasses exhibit activation energy values lower than those of the untreated ones. The electrical conductivity increase with sodium content and ion exchanging time. In this experiment the electrical conductivity exhibits a manximum value of 1.78*10$^{-4}$ S/cm at 200.deg. C which contains 30mol% sodium and subjects ion exchange reaction for 48hrs.

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Oil Adsorption of Exfoliated Graphite Prepared by Direct Reaction between $SO_3$ Gas and Graphite

  • Lee, Beom-Jae;Kwon, Young-Bae
    • Carbon letters
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    • v.2 no.1
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    • pp.55-60
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    • 2001
  • Graphite intercalation compounds (GIC) were prepared by direct reaction of $SO_3$ gas with flake graphite. The intercalated $SO_3$ molecules were ejected by rapid heating to $950^{\circ}C$ under an oxidizing atmosphere for about 1 minute, resulting in surprisingly high expansion in the direction of c-axis. The characteristics of the micro-structure and pore size distribution were examined with a SEM and mercury intrusion porosimetry. The XRD analysis and spectroscopic analysis were used for the identification of the graphite and surface chemistry state. The pore size distribution of the exfoliated graphite (EG) was a range of $1{\sim}170{\mu}m$. The higher expanding temperature the higher expanded volume, so oil sorption capacities were 58.8 g of bunker-C oil and 34.7 g of diesel oil per 1 g of the the EG. The sorption equilibrium was achieved very rapidly within several minutes. As the treatment temperature increases, bulk density decreases.

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Preparation of Multi-Wall Carbon Nanotubes by Floating Catalyst Method

  • Song, Hee-Suk;Kang, Eun-Jin;Kim, Myung-Soo
    • Carbon letters
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    • v.3 no.1
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    • pp.25-32
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    • 2002
  • Aligned multi-wall carbon nanotubes (MWNTs) were synthesized through the catalytic decomposition of hydrocarbons in a quartz tube reactor. In this study, we investigated the influence of reaction parameters such as gas flow rate, ferrocene-xylene ratio and partial pressure, and reaction time on the yield and structure of vertically aligned carbon nanotubes produced by the floating catalyst method. The MWNTs produced had diameters in the range of 20~l00 nm, length around $100{\mu}m$ and bulk density about $0.51g/cm^3$ at a pressure of l0000 psi. It was possible to produce MWNTs with much faster growth rate of $12{\mu}m/min$ than that reported previously by the increase of ferrocene-xylene partial pressure.

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Biosorption of lead by Laminaria japonica

  • Jung-Ho;Il-Bae;Hak-Sung
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.208-211
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    • 2003
  • Characteristics of biosorption of lead by marine algae, Laminaria japonica, were examined. The biosorption capacity of lead by L. japonica was achieved up to 30% of its own weight and proportional to the initial lead concentration. However, the opposite result was shown in different initial weight of biomass. Ion exchange reaction between lead ions and calcium ions was observed on lead biosorption with Ca-Ioaded biomass. Stoichiometric coefficient, which can represent the exchange ratio between metal ions and protons during elution process, was determined as 1.39. Therefore, it was concluded that the reaction between lead ions already attached in biomass and protons in bulk solution was not fully stoichiometric ion exchange relation at elution process.

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Wetting properties between silver-copper-titanium braze alloy and hexagonal boron nitride

  • Sechi, Yoshihisa;Matsumoto, Taihei;Nakata, Kazuhiro
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.205-209
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    • 2009
  • Wetting properties between silver-copper-titanium braze alloys with different titanium contents up to 2.8 mass% and hexagonal boron nitride ceramics were investigated using sessile drop method at 1123K in Argon. The final contact angle is less than $30^{\circ}$ when the Ti content was over 0.41 mass%. Meanwhile, the contact angle curves show different behavior. In case of using braze alloy containing 2.8 mass% of titanium, the initial contact angle is acute angle just after the melting of braze. In case of brazes containing titanium less than 2.26 mass%, the contact angle is larger than $90^{\circ}$ at the beginning and slowly decreases to acute angle. The reaction layer of titanium nitride is observed at the interface. In addition, the reaction of Ti in the braze and N in the bulk h-BN seemed to show diffusion limited spreading.

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Heat and mass transfer characteristics in steam reforming reactor (수증기 개질 반응기 내의 열 및 물질전달 특성에 관한 연구)

  • Lee, Shin-Ku;Lim, Sung-Kwang;Bae, Joong-Myeon
    • New & Renewable Energy
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    • v.2 no.4 s.8
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    • pp.56-63
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    • 2006
  • In this paper, heat and mass transfer characteristics through experimental and numerical study are extensively investigated in steam reforming reactor under given operating conditions. In order to get simulated data at outlet of the reformer, heterogeneous reactor model is incorporated. As the reaction also takes place in porous media, two medium approach is used to take into account thermally non-equilibrium phenomena between catalyst and bulk gas. From various parametric studies, significance of heat transfer is emphasized in steam reforming reaction.

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Formation of $Al_2O_3$-Composites by the Melt Oxidation of an AlZnMg-alloy (AlZnMg-합금의 용융산화에 의한 $Al_2O_3$-복합재료의 형성)

  • 김일수;김상호;강정윤
    • Journal of the Korean Ceramic Society
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    • v.33 no.9
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    • pp.985-994
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    • 1996
  • The initiation and growth of $\alpha$-Al2O3/metal composites by the directed oxidation of molten commercial AlZnMg-alloy at 1223-1423K were investigated. Spontaneous bulk growth did not occur on the alloy alone. but the uniform initiation and growth of the composite were obtained by putting a thin layer of SiO2 particles on the surface of the alloy. Without SiO2 the external surface of the oxide layer was convered by MgO and MgAl2O4. But with the SiO2 reaction initiate the porous ZnO layers were found on the growth surface. The higher process temperature yielded a lower metal content. The oxidation product of $\alpha$-Al2O3 was found to be oriented with c-axis parallel to th growth direction. The growth rates increased with temperature and the apparent activation energy was 111.8 kJ/mol.

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