• Title/Summary/Keyword: Brown carbon

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Biosorption of Heavy-metal Ions by Waste Brown Seaweed and Their Derivatives (미역 폐기물 및 미역폐기물 유도체에 의한 중금속이온의 생물흡착)

  • 박권필;김태희;김영숙;차왕석;우명우
    • Journal of Environmental Science International
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    • v.10 no.2
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    • pp.153-158
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    • 2001
  • The biosorption abilities of different parts of waste brown seaweeds and their derivatives to remove heavy metals (Cd, Zn, Pb, Cu, Fe, Ni, Mn) from waste were evaluated. The two parts of waste brown seaweeds (Undaria pinnatifida) were stems and sporophyls, and the brown seaweed derivatives were alginic fibers, active carbon added alginate(AC-alginate) and dealginate. The abilities of the sporophyls to adsorb the heavy metal ions were higher than those of stems, and those of alginates were slightly higher than those of dealginate in single ion solution. With decreasing the size of biosorbents, the velocity and the amount of adsorption increased. The abilities of alginate to remove the heavy metal ions increased in multi-ion solutions by adding active carbon to alginate. The selectivity of these biosorbents(alginate, AC-alginate) to lead ion was highest and to manganese ion was lowest.

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Adsorption Equilibrium, Kinetics and Thermodynamic Parameters Studies of Bismarck Brown R Dye Adsorption on Granular Activated Carbon (입상 활성탄에 대한 비스마르크 브라운 R 염료의 흡착평형, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong-Jib
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.327-332
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    • 2013
  • Batch experiments were carried out for adsorption equilibrium, kinetics and thermodynamic parameters of the brilliant brown R onto granular activated carbon. The operating variables studied were the initial dye concentration, contact time and temperature. Experimental equilibrium adsorption data were fitted to Langmuir and Freundlich adsorption isotherm by linear regression method. The equilibrium process was well described by Freundlich isotherm model and from the determined separation factor (1/n), granular activated carbon could be employed as an effective treatment for the removal of bismarck brown R. From kinetic experiments, the adsorption processes were found to confirm the pseudo second order model with a good correlation and the adsorption rate constant ($k_2$) increased with increasing adsorption temperature. Thermodynamic parameters like the activation energy, change of Gibbs free energy, enthalpy, and entropy were also calculated to predict the nature of adsorption in the temperature range of 298~318 K. The activation energy was determined as 8.73 kJ/mol for 100 mg/L. It was found that the adsorption of bismarck brown R on the granular activated carbon was physical process. The negative Gibbs free energy change (${\Delta}G$ = -2.59~-4.92 kJ/mol) and the positive enthalpy change (${\Delta}H$ = +26.34 kJ/mol) are indicative of the spontaneous and endothermic nature of the adsorption process.

Adsorption of Chlorothalonil and Dicofol by the Soil of Cheju Island (제주도 토양에 의한 Chlorothalonil 및 Dicofol의 흡착)

  • 감상규
    • Journal of Environmental Science International
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    • v.6 no.3
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    • pp.285-291
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    • 1997
  • In order to Investigate the adsorption characteristics of organochlorine pesticides chlorothaloul and dicofol with soul colors and re참tons far souls of an orange orchard, the souls were sampled at 3 re삼tons, respectively. among black volcanic, dark brown volcanic, and broom nonvolcanlc sorts. Every so6 has a higher clay proportion (49-75%) In sol tcuture and the organic carbon content and cation ekchange capacity with soil decreased in the following sequence: Black volcanic > Dark brown volcanic > Brown nonvolcanic sorts. Especially those In black volcauc trolls were much higher than others. The retention time, quantitative detection limit, and extractian , efficiencies of chlorothalonil and dicofol were 2.82min, 1.5ng/mL, 93.6% and 3.64min, 4.5ng/mL. 94 2%, repectlvely. The Freundlich constant, Kd, was higher in dicofol compared to chlorothalonil and In the black volcanic souls that have higher organic carbon content and cation Bkchange capacity. The Freundlich constant, 1 In, was In the range of 0.76-0.89 In the black volcanic sorts that have a higher organic matter(16.4-19.8%), whereas It was In the range of 1.02-1.13 In the brown nonvolcanic souls that have a lower organic matter(2.4-3.4%), and so It was considered that 1 In was dependent on the organic matter.

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Physicochemical Properties of Jeung-pyun Dough Containing with Different Amounts of Brown Rice (현미가루를 첨가한 증편반죽의 이화학적 특성)

  • Jeong, Sang-Yeol;Park, Mi-Jung;Lee, Sook-Young
    • Korean journal of food and cookery science
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    • v.27 no.2
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    • pp.9-17
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    • 2011
  • In this study, the physicochemical properties of polished rice flour, brown rice flour, and Jeung-pyun dough were studied. The protein, lipid, dietary fiber, pH of brown rice flour were higher than those of polished rice flour. The total polyphenol contents and electron donating ability (EDA) of brown rice flour (83.60 mg%, 2.44%, respectively) were higher than those of polished rice flour (56.91 mg%, 1.43%, respectively). The temperature gelatinization of brown rice flour higher than that of polished rice flour. The counts in Jeung-pyun dough were not significantly decreased brown-rice flour. The addition of brown rice flour decreased the amount of carbon dioxide gas evoluted from Jeung-pyun dough. The pH values of brown rice Jeung-pyun dough generally decreased fermentation time.

Biomass and PE Gasification with High Temperature Steam of Brown Gas (브라운 가스 고온(高溫) 수증기(水蒸氣)를 이용한 바이오매스 및 PE 가스화)

  • Roh, Seon-Ah;Yun, Jin-Han;Kim, Woo-Hyun;Keel, Sang-In;Min, Tai-Jin
    • Resources Recycling
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    • v.18 no.2
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    • pp.51-55
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    • 2009
  • Sawdust and sewage sludge and PE gasification by high temperature steam of Brown gas have been performed in this study. Steam/carbon ratio has been changed from 1 to 5 and the effect of steam/carbon ratio on the produced gas concentrations, gasification rate and tar generation has been determined. Also, the temperature distribution in the gasification reactor has been studied. Highest combustible content in the produced gas is around 70vol% and $H_2$ shows highest content among the combustible compounds. However, the heating value of the produced gas and tar content have been reduced with increasing steam/carbon ratio.

Anatomical Differentiation and Photosynthetic Adaptation in Brown Algae

  • Garbary, David J.;Kim, Kwang-Young
    • ALGAE
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    • v.20 no.3
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    • pp.233-238
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    • 2005
  • The photosynthetic parameters of dark- adapted minimum fluorescence (Fo) and maximum quantum yield of charge separation in PSII (Fv/Fm) were measured in transverse sections of eight species of marine Phaeophyceae (species of Laminariales, Fucales, Desmarestiales, Chordariales) using pulse amplified modulation (PAM) fluorometry. Within each transverse section fluorescence was measured in three regions corresponding to outer cortical and meristoderm cells, inner cortical cells and innermost medullary cells. Minimum fluorescence declined from 19-74% (mean of 39%) from outermost to innermost cells. Maximum quantum yield varied from 0.51-0.59 in outermost cell layers and this was reduced to 0.23-0.40 in innermost cell layers, with an average reduction of 50%. Despite the reduction Fo in medullary cells (inner), medullas of all species showed maximum quantum yields consistent with a photosynthetic role in carbon fixation. These results show that medullary cells of complex brown algae have more than a role in structure, storage or transport, and may also provide an important role in carbon fixation.

Estimation of the Light Absorption Contribution for Asian Dust and Polluted Particles at Gosan, Jeju during the Asian Dust Episode in the Spring 2011 (2011년 봄 황사시기 제주도 고산에서의 황사와 오염입자의 광흡수 기여도 산정)

  • Lee, Si-Hye;Kim, Sang-Woo;Yoon, Soon-Chang
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.4
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    • pp.411-422
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    • 2012
  • Ground-based in-situ measurements of aerosol optical properties at Gosan climate observatory have been analyzed to investigate the optical contribution of Asian dust and polluted particles on light absorption in springtime 2011. During the Asian dust episode, the contribution of Asian dust particle to aerosol absorption coefficient estimated about 45% at 370 nm and about 23% at 520 nm. Especially, black carbon in dust plume contributes about 48% to aerosol light absorption at 520 nm since the airmass are transported from the Gobi and inner Mongolia deserts, and this airmass comes across the northeastern coast of China, near the Shandong Peninsula. In pollution case, the contributions of dust particle and black carbon to aerosol absorption coefficient estimated about 41% and 11% at 370 nm, respectively. However, pollution case shows the highest light absorption of 48% for brown carbon at 370 nm, which indicates the significantly high mass concentration of organic carbon ($6.3{\pm}2.2{\mu}g\;m^{-3}$) in pollution plume can contribute to the increase of light absorption at near-UV spectral region.

High-fat diet alters the thermogenic gene expression to β-agonists or 18-carbon fatty acids in adipocytes derived from the white and brown adipose tissue of mice

  • Seonjeong Park;Seung A Ock;Yun Jeong Park;Yoo-Hyun Lee;Chan Yoon Park;Sunhye Shin
    • Journal of Nutrition and Health
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    • v.57 no.2
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    • pp.171-184
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    • 2024
  • Purpose: Although activating thermogenic adipocytes is a promising strategy to reduce the risk of obesity and related metabolic disorders, emerging evidence suggests that it is difficult to induce adipocyte thermogenesis in obesity. Therefore, this study aimed to investigate the regulation of adipocyte thermogenesis in diet-induced obesity. Methods: Adipose progenitor cells were isolated from the white and brown adipose tissues of control diet (CD) or high-fat diet (HFD) fed mice, and fully differentiated white and brown adipocytes were treated with β-agonists or 18-carbon fatty acids for β-adrenergic activation or peroxisome proliferator-activated receptor (PPAR) activation. Results: Compared to the CD-fed mice, the expression of uncoupling protein 1 (Ucp1) was lower in the white adipose tissue of the HFD-fed mice; however, this was not observed in the brown adipose tissue. The expression of peroxisome proliferator-activated receptor gamma (Pparg) was lower in the brown adipose progenitor cells isolated from HFD-fed mice than in those isolated from the CD-fed mice. Norepinephrine (NE) treatment exerted lesser effect on peroxisome proliferator-activated receptor-γ coactivator (Pgc1a) upregulation in white adipocytes derived from HFD-fed mice than those derived from CD-fed mice. Regardless which 18-carbon fatty acids were treated, the expression levels of thermogenic genes including Ucp1, Pgc1a, and positive regulatory domain zinc finger region protein 16 (Prdm16) were higher in the white adipocytes derived from HFD-fed mice. Oleic acid (OLA) and γ-linolenic acid (GLA) upregulated Pgc1a expression in white adipocytes derived from HFD-fed mice. Brown adipocytes derived from HFD-fed mice had higher expression levels of Pgc1a and Prdm16 compared to their counterparts. Conclusion: These results indicate that diet-induced obesity may downregulate brown adipogenesis and NE-induced thermogenesis in white adipocytes. Also, HFD feeding may induce thermogenic gene expression in white and brown primary adipocytes, and OLA and GLA could augment the expression levels.

Humus Analysis for the Geomorphic Development and Climatic Environment Change of Alluvial Plain in Hampyeongcheon Basin during the Late Holocene (휴무스분석을 이용한 함평천 유역의 홀로세 후기 충적평야의 지형발달과 기후환경변화)

  • Jung, Hea-Kyung;Kim, Cheong-Bin
    • Journal of the Korean earth science society
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    • v.33 no.4
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    • pp.320-328
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    • 2012
  • To investigate geomorphic development of alluvial plains and climatic environment change during the late Holocene carbon dating, soil organic carbon analysis and humus analysis of sediments from alluvial plain of Hampyeongcheon basin were performed. The lowest peat layer was formed under warm and humid climates, which is considered to correspond to the Atlantic period in the Holocene. Yellowish brown sandy clay layer was deposited in the natural levee, which we think were deposited in the generally warm and dry climates. The carbon dating age is 1,879-1,532 BC, and this period correspond to the Sub-boreal period in the Holocene. Light brown clay layer is assumed to have been deposited in transitional environment from the natural levee to the back marsh. The climatic environment was warm and humid, which is considered as transitional period from the Sub-boreal to the Sub-Atlantic in the Holocene. Light yellowish brown and light brown clay layer of the upper part are regarded as sediments of the back marsh. Light yellowish brown clay layer was deposited in the cold and dry climates, which is considered to correspond to the Sub-Atlantic period in the Holocene. Light brown clay layer was deposited in the warm and dry climates. The carbon dating age is 211-427 AD, this period corresponds to the Post Roman Warm Period in the Holocene.

Quality Characteristics of Frozen Brown-rice Jeung-pyun Dough Containing Different Amounts of Buckwheat Flour (메밀가루의 첨가량을 달리하여 제조한 냉동 현미증편반죽의 품질특성)

  • Jeong, Sang-Yeol;Park, Mi-Jung;Lee, Sook-Young
    • Korean journal of food and cookery science
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    • v.27 no.1
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    • pp.11-19
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    • 2011
  • In this study, the physicochemical properties of buckwheat flour and quality characteristics of brown-rice doughs containing various concentrations of buckwheat flour stored at $-18^{\circ}C$ for 4 weeks and fermented were studied. The total polyphenolic contents, electron donating ability (EDA) of 0.5%, gelatinization onset temperature (To), gelatinization peak temperature (Tp), and gelatinization conclusion temperature (Tc) of buckwheat flour were 1,920.10mg%, 6.95%, $70.11^{\circ}C$, $78.21^{\circ}C$, and $84.05^{\circ}C$, respectively. There were no significant differences in the amount of yeast between brown-rice Jeung-pyun dough samples containing different levels of buckwheat flour and stored for different time periods. The amounts of carbon dioxide gas evolved from the brown-rice doughs were increased by increasing the concentration of buckwheat flour. The pH of brown-rice dough samples decreased with increasing storage period. Therefore, frozen brown-rice dough containing 6-15% buckwheat flour and stored for 3 weeks were the most desirable.