• 한국재료학회지
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• 제20권2호
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• pp.82-89
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• 2010

Benzotriazole (B.T.A) which has been mainly used for the stabilization processing method of excavated copper and bronze artifacts is vaporized within 2~3 years after the usage because it is unstable at the acid conditions and cannot protect the surface of artifacts. In this study, NaOH method which has been used for the steel artifacts was applied as a stabilization process for the method of copper and bronze artifacts to gush chlorine ion out. For the reproduction of excavated samples, copper and bronze plates were dipped in 0.1M HCl for 26 hrs to form CuCl, rusted at $70^{\circ}C$ with RH 75% for the formation of corrosion products, and desalted in 0.1 M NaOH solution. The concentration of chlorine ion was measured by using ionchromatography. During the desalting process, a large quantity of chlorine ions was gushed out in early period and corrosion products were not additionally generated through the re-corrosion experiment. This NaOH desalting process was found to be a method of stabilization process for copper and bronze artifacts from the formation of Tenorite (CuO) during desalting as a protection layer for corrosion.

• 보존과학회지
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• 제1권1호
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• pp.60-79
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• 1992

In relation to the scientific conservation treatment of ancient gilt bronze, the gold film coated on the bronze excavated from Hwangnam Great Tomb of Old Silla Kingdom(A. D. 5C) was studied in the view of coating technology and metallurgy of bronze. The uniform and dense gold film containing $2.44\sim12.40%$ of Hg with the thickness of $5.99\sim12.97{\mu}m$ was found to be coated on the bronze objects by amalgam coating method. On silver objects, the film with the thickness of $19.96{\mu}m$ was coated also continously and uniformly with gold by the same method. The bronze objects was fabricated by forging technique and contained almost $4.7\sim11.5%$ of Pb. Its microstructure was $\alpha-phase$ solid solution including Pb segregation in the matrix. The amount of $0.4\sim2.0%$ Zn was added in the bronze for the purpose of easy fabricating of Cu alloy. Based on the data studied, the gold film on bronze sample was reproduced by amalgam coating method and compared with the ancient gold film.

• 헤리티지:역사와 과학
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• 제55권2호
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• pp.24-48
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• 2022

탑에서 발견된 동경은 단순 공양품으로 여겨져 동경 연구에서도 크게 관심 받지 못했다. 그리고 탑 내 봉안 동경 연구는 오월국 탑에서 발견된 선각불상문경에 집중되어 있어, 탑 내 봉안 동경에 대한 전반적 특징을 알기 어려웠다. 그렇기에 본고는 오대~송대 시기 많은 탑들에서 발견된 동경이 목적을 갖고 봉안되었을 것으로 생각했으며, 이를 파악하기 위해 봉안 위치와 방식에 중점을 두었다. 오대 오월국시기에 탑 내 동경을 봉안하는 사례가 증가했고, 동경은 단순한 공양품이 아닌 목적을 갖고 불교와 관련된 도상이나 명문이 새겨져 있는 봉안품이었다. 이는 동경의 사용 목적이 변화했음을 보여주는 것으로 송대까지 영향을 끼친다. 송대는 오월국의 영향이 꾸준히 이어지면서도 송대 문화와 사회 분위기로 인해 동경 봉안 양상도 변화한다. 봉안된 동경의 종류는 소문경이 다수를 차지하며, 당대 동경도 꾸준히 사용되었다. 소문경은 오월국의 영향으로 선각불상문과 같은 도상과 명문을 새기기 용이했기에 적극적으로 사용했다. 또한 당대 동경은 송대 방고동기에 대한 관심과 황제의 영향으로 인해 귀하게 여겨져 탑을 조성할 때 당경을 공양품으로 봉안한 것으로 추정된다. 오대~송대 탑 내 동경 봉안은 그 방식에서 변화가 있었다. 당대 지궁 바닥이나 철함 내 놓아두던 동경은 의도적으로 벽에 붙이거나 천장에 매달아 놓았다. 이 방식을 크게 두가지로 구분하여 벽이나 천장에 감입하는 방식(감입경: 嵌入鏡)과 천장에 매달아 놓는 방식(현경: 懸鏡)으로 분류했다. 천장에 매달아 놓는 방식으로는 대표적으로 하북 정지사탑(靜志寺塔)이 있으며, 천장에 감입한 예로는 하남(河南) 복승사탑(福勝寺塔)이 있다. 이렇게 동경을 천장에 매달고 감입하는 방식은 중국 묘실과의 관련성이 높다. 송대 묘실은 넓고 높은 구조를 갖고 있어, 벽사용 동경을 이용해 묘실을 지키고자했다. 그렇기에 높은 곳에 동경을 두어 묘실을 비추게 했으며, 이는 앞서 언급한 두가지 방식으로 이루어졌다. 탑 역시 지궁이 넓고 높아짐에 따라 지궁의 중요한 부분을 지키고, 내부를 밝게 비추고자 했다. 따라서 오대~송대 탑 내 동경 봉안방식은 당시 묘실에 동경을 봉안하던 방식을 차용했던 것으로 생각되며, 이후 섬서(陝西) 묘각사탑(妙覺寺塔)과 같이 적극적으로 설계 때부터 감입을 고려하여 동경을 놓을 자리를 마련해 놓은 예도 등장하게 된다.

• 보존과학연구
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• 통권21호
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• pp.77-99
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• 2000

Tumuli located in Chodang-dong in Kangreung City are sitesexcavated by the Museum of Kangreung University in 1993.Ofthese sites, a gilt bronze crown and gilt bronze sword with ring pommel with a tri-leaf ornament were excavated from the B-16tumulus. Underneath the gilt bronze crown was the gilt bronzes word with ring pommel with tri-leaf ornament, and these artifacts were treated with Polyurethane foams on the spot followed by special measures for conservation. This manuscript describes measures for conservation andanalysis with regard to the gilt bronze crown, gilt bronze sword with ring pommel with tri-leaf ornament and gilt bronze beltornaments. Bronze on the gilt bronze crown was completely corroded, therefore it was consolidated together with soil in the back of the artifact with Paraloid B72 after cleaning. Polyurethanefoams bottom was finished by applying the mixture of Epoxy resinAW106 and HV935K with soil. On the sword with ring pommel, the wooden part of the hilt was coated with Paraloid B72 (in Xylene) and the blade was consolidated with Paraloid NAD-10 30% after desalting with Sodium sesquicarbonate method. The gilt bronzebelt ornaments were treated with 3% Benzotriazole, coated with Paraloid B72 and then joined by using Cyanlacrylate. Specimens for the gilt bronze crown and gilt bronze belt ornaments were produced and gilding layers were examined under a metallographic microscope. The gilt bronze crown and the gilt bronze belt ornament maintained relatively good gilding quality with uniform gilding layers. Analysis of wood for the sheath of the sword with ring pommel revealed it to be Juglans mandshurica. Further more, analysis of constituents for a blue colored grassbead from dissolution of Polyurethane foams found it to be from the $Na_2O$-CaO-$AI_2O_3$-$SiO_2$ family.

• 한국표면공학회지
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• 제46권5호
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• pp.197-207
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• 2013

In the midst of increasing importance of modern cultural assets, especially, most modern bronze objects are exposed to outdoor environment, and as the objects are corroded steadily due to environmental factors the objects lost their original colors on the surface. We performed artificial patinas on the bronze sample per each color of red, black and green and checked cuprite and tenorite which are detected from actual bronze corrosion by analyzing the components. In addition, we applied the existing corrosion removal methods of grinder and sand blaster on a similar sample of bronze mirror per injection pressure and performed comparative analysis on the result with Nd:YAG laser. As a result of Nd:YAG laser cleaning artificial patina from bronze samples, all of the patinas were removed by laser wavelength 1064 nm better than 532 nm. Upon applying to a similar sample of bronze mirror, the artificial patina could be selectively removed from substrates without surface damage when Nd:YAG laser was conducted other than the existing removal method, and so it showed the possibility of application.

• 대한화학회지
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• 제62권2호
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• pp.118-123
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• 2018

The hexagonal tungsten bronze $Cs_xWO_3$ nanoparticle was synthesized by a chemical coprecipitation method of ammonium tungstate and $Cs_2CO_3$ in acidic condition. This synthetic method for cesium tungsten bronze is reported for the first time as far as we know. The synthesized $Cs_xWO_3$ as precipitated showed a weak crystallinity of hexagonal unit cell with a crystallite size of about 4 nm without annealing. When the synthesized $Cs_xWO_3$ was annealed in $N_2$ atmosphere, the crystallinity and crystallite size systematically increased maintaining the typical hexagonal tungsten bronze structure as the annealing temperature increased. The analyzed Cs content in the bronze was about 0.3 vs W, which is very close to the theoretical maximum value, 1/3 in cesium tungsten bronze. According to XPS analysis, the reduced tungsten ions existed as both the forms of $W^{5+}$ and $W^{4+}$ and the contents systematically increased as the annealing temperature increased up to $800^{\circ}C$. The $Cs_xWO_3$ thin films on PET substrate were also prepared by a wet-coating method using the ball-milled solution of the annealed $Cs_xWO_3$ nanoparticles at various temperatures. The near-infrared shielding property of these thin films increased systematically as the annealing temperature increased up to $800^{\circ}C$ as expected with the increased contents of reduced tungsten ions.

• 박물관보존과학
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• 제26권
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• pp.119-142
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• 2021

금동은제식리는 무령왕릉에서 출토된 무령왕의 식리로 결실된 부분이 많아 재조사의 필요성이 꾸준히 제기되었다. 이에 과학적인 보존처리 및 분석을 진행하여 제작기법을 연구하였다. 보존처리는 형태 복원 및 편 접합에 중점을 두고 실시하였다. 그 결과, 우측 식리 상연과 뒤축 일부 편을 접합하여, 결합방법 및 발등 결합에 사용된 원두정의 개수를 확인하였다. 성분 분석결과, 외판 등은 순동에 수은 아말감 금도금을 한 것으로 추정되며, 내판은 순은을 사용하였다. 금동은제식리의 주문양은 봉황문, 연화문, 6엽 화문이며, 전체적으로 연화문의 비율이 높다. 각 판의 결합은 영락사, 금동사, 원두정, 사면정을 사용하였다. 내·외판 결합은 영락사를 사용하였는데, 내측판의 중앙과 후면에는 금동사로만 결합하여 장식 기능과 결합 기능을 구분하여 사용한 것으로 추정된다. 또한 제작과정에서 금동제판과 은제판의 외면에는 광쇠질한 흔적이 확인되지만, 은제판의 내면에서는 확인되지 않아 내면보다 외면의 마무리에 중점을 둔 것으로 추정된다.

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2001년도 춘계총회 및 학술발표회
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• pp.38-38
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• 2001

• 박물관보존과학
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• 제20권
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• pp.1-12
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• 2018

익산시 웅포면 입점리 1호분 출토 금동제유물 편들은 1986년 2월 마을 뒷산에서 한 고등학생에 의해 발견매장문화재로 신고되었고, 이에 국립문화재연구소에서 긴급발굴조사를 실시하였다. 금동대륜, 금동입식, 금동관모, 금동식리 등은 신고자에 의해 수습되어 있었다. 또한 발굴조사 당시 석실 내부가 심하게 훼손되어 많은 수의 금동제유물 편들은 정확한 출토위치를 알 수 없어, 지금까지도 금동관의 조합 관계가 확인되지 않고 있다. 중요 유물인 금동관모, 금동식리 등은 보존처리 후 편 접합을 통해 외형적 모습이 복원되었으며, 금속공예기법으로 새긴 봉황문, 물고기 비늘문, 연화문 등의 문양을 관찰할 수 있었다. 본 글에서는 여러 편들로 파손되어 있는 금동제유물 편들에 대한 특징적 요소와 제작기법을 소개하여 복원의 기초적 학술자료로 제공하고, 이 자료를 바탕으로 입점리 금동관의 원형이 복원될 수 있기를 기대한다.

• Advances in nano research
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• 제12권6호
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• pp.583-592
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• 2022

In this paper, a pulsed picosecond laser dressing method for bronze-bonded diamond wheel is studied systematically and comprehensively. The picosecond laser pulse ablation experiment is carried out, and the ablation thresholds of bronze-bonded and diamond abrasive particle are measured respectively. The results indicate that the single-pulse ablation thresholds of bronze-bonded are 0.89J/cm², 0.24J/cm² during strong/weak ablation stages. And the multi-pulse ablation thresholds of diamond abrasive particle are 1.69J/cm², 0.49J/cm² during strong/weak ablation stages. Obviously, diamond grains have less thermal damage during the process of gentle ablation. The diamond grains of the grinding wheel surface are graphitized during laser dressing. The bronze-bonded is relatively smooth and organizational stability, and the diamond grits have suitable prominent height, which are beneficial to maintain the good grinding performance of dressed bronze-bonded diamond grinding wheels.