• 제목/요약/키워드: Breakdown Energy

검색결과 357건 처리시간 0.03초

Quality Characteristics of Frozen Stored Mungbean Starch Gels Added with Sucrose Fatty Acid Ester

  • Choi, Eun-Jung;Oh, Myung-Suk
    • Food Quality and Culture
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    • 제3권2호
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    • pp.53-58
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    • 2009
  • This study was conducted to investigate the quality characteristics of frozen stored mungbean starch gels added with sucrose fatty acid ester (SE). The study showed a delay of gelatinization of mungbean starch by SE addition through the measurements conducted by using Rapid Visco Analyzer (RVA) and Differential Scanning Calorimeter (DSC). In the color of SE added frozen stored gels, lightness (L) and yellowness (b) values were increased compared to those of values measured from freshly prepared gel, whereas redness (a) value was decreased. The addition of 1% SE on mungbean starch gel prevented the color change during frozen storage. Rupture stress and rupture energy of frozen stored gel was higher than those of freshly prepared gel, whereas rupture strain of frozen stored gel was lower than that of freshly prepared gel. The addition of 1% SE on mungbean starch gel prevented the change of rupture characteristics during frozen storage. Texture profile analysis(TPA) characteristics revealed a significant change of the gel texture during frozen storage by showing an increase of hardness of the frozen stored gels compared to the freshly prepared gels with newly discovered fracturability, which resulted to show a large difference of gel texture by showing the disappearance of adhesiveness and large reduction of cohesivenes. The addition of 1% SE on mungbean starch gel prevented the change of TPA characteristics during frozen storage. Scanning electron micrographs showed that network structure of frozen stored gel was more rough than that of freshly prepared gel, and the addition of 1% SE on mungbean starch gel could suppress the breakdown of network structure. Thus the addition of 1.0% SE on mungbean starch gel was appropriate method for remaining gel characteristics during frozen storage.

전.자계상의 전원장치변화에 따른 비열방전 플라즈마의 $SO_2$와 CO가스 제거특성 ($SO_2$ and CO Removal Characteristics in Various Applied Voltage of Nonthermal Discharge Plasma in a Crossed DC Magnetic Field)

  • 이근택;금상택;문재덕
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제48권3호
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    • pp.215-220
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    • 1999
  • $SO_2$and CO gas removal characteristics of a wire-to-cylinder type nonthermal discharge plasma reactor in various applied voltage (-dc, ac, fast rising pulse and high frequency pulse) and a crossed dc magnetic field have been investigated. The experiment has been emphasized on the oxidizing characteristics of $SO_2$ and CO gas by $O_3$ and the applying of a crossed magnetic field, which would induce the cyclotronic and drift motions of electrons making the residual time longer in the removal airgap space. And it also would enhance the energy of electrons and the electrophysicochemical actions to remove the pollutant gases effectively. It is found thatthe corona onset voltage and the breakdown voltage were decreased with increasing the crossed magnetic field and decrease initial fed $SO_2$and CO concentration. As a result, a higher ozone generation and $SO_2$ and CO gas removal rate of 20[%] can be obtained with -dc, ac and fast rising pulse corona discharges in the crossed dc current-induced magnetic field. But high frequency pulse didn't show effect in applying of a crossed magnetic field.

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Theoretical Studies on the Addition Reactions of Ketene with NH3 in the Gas Phase and in Non-Aqueous Solutions

  • Kim, Chang-Kon;Lee, Kyung A;Chen, Junxian;Lee, Hai-Whang;Lee, Bon-Su;Kim, Chan-Kyung
    • Bulletin of the Korean Chemical Society
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    • 제29권7호
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    • pp.1335-1343
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    • 2008
  • Theoretical studies on the un-catalyzed and catalyzed aminations of ketene with $NH_3$ and $(NH_3)_2$, respectively, were studied using MP2 and hybrid density functional theory of B3LYP at the 6-31+G(d,p) and 6- 311+G(3df,2p) basis sets in the gas phase and in benzene and acetonitrile solvents. In the gas phase reaction, the un-catalyzed mechanism was the same as those previously reported by others. The catalyzed mechanism, however, was more complicated than expected requiring three transition states for the complete description of the C=O addition pathways. In the un-catalyzed amination, rate determining step was the breakdown of enol amide but in the catalyzed reaction, it was changed to the formation of enol amide, which was contradictory to the previous findings. Starting from the gas-phase structures, all structures were re-optimized using the CPCM method in solvent medium. In a high dielectric medium, acetonitrile, a zwitterions formed from the reaction of $CH_2$=C=O with $(NH_3)_2$, I(d), exists as a genuine minimum but other zwitterions, I(m) in acetonitrile and I(d) in benzene become unstable when ZPE corrected energies are used. Structural and energetic changes induced by solvation were considered in detail. Lowering of the activation energy by introducing additional $NH_3$ molecule amounted to ca. −20 $\sim$ −25 kcal/mol, which made catalyzed reaction more facile than un-catalyzed one.

라테라이트광의 건식분쇄가 니켈 및 코발트의 침출에 미치는 영향 (Effect of Dry Grinding of Laterite on the Extraction of Nickel and Cobalt)

  • 김완태;최도영;김상배
    • 한국광물학회지
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    • 제23권3호
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    • pp.227-234
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    • 2010
  • 본 연구에서는 라테라이트광의 건식 분쇄가 니켈 및 코발트의 침출에 미치는 영향을 조사하였다. 시료로 사용한 라테라이트광은 주로 $SiO_2$, $Fe_2O_3$, MgO로 이루어져 있으며, 니켈과 코발트의 함량은 0.81% Ni, 0.02% Co이었다. 주 구성 광물은 리자다이트와 석영이며, 미량의 포스터라이트와 엔스터타이트를 함유하고 있었다. 분쇄가 진행됨에 따라 시료의 평균입도, 비표면적, 밀도는 감소하는 경향을 보였으며, X-선 회절분석을 통해 리자다이트의 비정질화가 진행됨을 확인하였다. 분쇄에 의한 석영의 물성변화는 나타나지 않았으나, 리자다이트의 Mg-OH 결합이 파괴됨으로써 니켈 및 코발트의 침출율이 향상됨을 알 수 있었다. 분쇄가 진행됨에 따라 니켈과 코발트의 침출율은 증가하였으며, 60분 분쇄한 시료의 경우, 사용한 무기산의 종류에 관계없이 니켈과 코발트의 침출율은 약 80%로 나타났다.

Low-temperature crystallization of high-dielectric (Ba,Sr)$TiO_3$ thin films for embedded capacitors

  • Cho, Kwang-Hwan;Kang, Min-Gyu;Kang, Chong-Yun;Yoon, Seok-Jin
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 춘계학술회의 초록집
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    • pp.21-21
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    • 2010
  • (Ba,Sr)$TiO_3$ (BST) thin film with a perovskite structure has potential for the practical application in various functional devices such as nonvolatile-memory components, capacitor, gate insulator of thin-film transistors, and electro-optic devices for display. Normally, the BST thin films derived from sol-gel and sputtering are amorphous or partially crystalline when processed below $600^{\circ}C$. For the purpose of integrating BST thin film directly into a Si-based read-out integrated circuit (ROIC), it is necessary to process the BST film below $400^{\circ}C$. The microstructural and electrical properties of low-temperature crystallized BST film were studied. The BST thin films have been fabricated at $350^{\circ}C$ by UV-assisted rapidly thermal annealing (RTA). The BST films are in a single perovskite phase and have well-defined electrical properties such as high dielectric constant, low dielectric loss, low leakage current density, and high breakdown voltage. Photoexcitation of the organics contained in the sol-gel-derived films by high-intensity UV irradiation facilitates elimination of the organics and formation of the single-crystalline phase films at low temperatures. The amorphous BST thin film was transformed to a highly (h00)-oriented perovskite structure by high oxygen pressure processing (HOPP) at as low as $350^{\circ}C$. The dielectric properties of BST film were comparable to (or even better than) those of the conventionally processed BST films prepared by sputtering or post-annealing at temperature above $600^{\circ}C$. When external pressure was applied to the well-known contractive BST system during annealing, the nucleation energy barrier was reduced; correspondingly, the crystallization temperature decreased. The UV-assisted RTA and HOPP, as compatible with existing MOS technology, let the BST films be integrated into radio-frequency circuit and mixed-signal integrated circuit below the critical temperature of $400^{\circ}C$.

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정보통신설비공사 감리대가 품셈개정에 관한 연구 (A Study on the Revision of Man-day Cost Calculation Method for Information and Communication Facilities Construction Supervision)

  • 이진호;강병권
    • 융합정보논문지
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    • 제10권2호
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    • pp.1-8
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    • 2020
  • 국내 정보통신 설비공사에 대한 감리대가 표준품셈은 2009년 5월 (사)한국엔지니어링협회에서 정한 표준품셈을 최근까지 관련 공공기관 및 민간 산업계에서 사용해 왔다. 그러나 정보통신기술과 사회경제적 환경이 매우 빠르게 변화되고 발전되어 기존의 품셈은 최근의 현장 여건에 부합되지 않아 현장 적용률이 저조하고, 공종별 감리원수 산출을 위한 산출식이 복잡하여 적용에 많은 어려움을 갖고 있다. 이러한 여건과 최근의 정보통신 기술의 융복합화에 따른 새로운 공종을 표준품셈에 반영하여 기존 품셈의 보완 및 개정 필요성이 대두되었고, 산업통상자원부에서는 최근 새로운 표준감리 품셈을 개정 고시하였다. 본 논문에서는 저자들이 개정과정에 주도적으로 참여한 경험을 바탕으로 개정 고시된 표준품셈의 개정 배경과 새롭게 제시된 표준 품셈 계산식을 기존 품셈 계산식과 비교하여 설명을 제시하고자 한다. 연구방법으로서 기존의 품셈이 적용된 실사례 조사 결과와 타 분야 품셈을 비교 후 정보통신설비공사 분야의 품셈을 개선하기 위하여 WBS 방식에 기반한 새로운 품셈 산출 수식을 설명한다.

샌드위치형 복합재 하이브리드 차체의 경제성 분석에 관한 연구 (A Study on the Economic Feasibility of Hybrid Bodyshell Made of Sandwich Composite Plate)

  • 서승일;김정석;조세현
    • 한국철도학회논문집
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    • 제15권2호
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    • pp.97-103
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    • 2012
  • 허니컴 샌드위치 복합재는 가볍고 강하며, 제작하기가 편리한 장점이 있어 철도차량 차체에 적용되기 시작하였다. 보통 중량감소량은 27%에 달하나, 재료비가 알루미늄 압출재에 비해 높기 때문에 차체에 널리 적용되지 못하였다. 본 논문에서는 두 가지 경량화 재질에 대하여 제작 과정을 고찰하고 원가를 분류하여 과거 자료를 기초로한 경제성을 분석하였다. 복합재 차체의 재료비 상승분을 제작의 용이성으로 상쇄할 수 있으며, 대량생산에 따른 장비비를 저감하면 알루미늄 차체에 비해 경쟁력을 가질 수 있음을 알 수 있었다. 지하철 노선의 통계자료를 참고로 하여 중량 감소에 따른 운행 에너지 감소량도 제시하였다.

폐경후 여성의 치주질환 심도에 따른 골다공증 소견 (Osteoporotic Condition in Postmenopausal Women with Periodontitis)

  • 김강문;김영준;정현주
    • Journal of Periodontal and Implant Science
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    • 제32권1호
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    • pp.225-234
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    • 2002
  • The purpose of this study was to evaluate the relationship between the osteoporotic condition and periodontal condition in postmenopausal women with periodontitis. Forty three female postmenopausal patients with no systemic disease were grouped into 3 groups by their periodontal conditions; 12 mild periodontitis, 11 moderate periodontitis and 20 advanced periodontitis. From each patient, age of menopause was taken, alkaline phosphatase(ALP) and osteocalcin (OC) in blood and deoxypyridinoline (DPD) in urine were measured. Bone mineral density (BMD) of lumbar spine (L2-L4) was measured by dual energy X-ray absorptiometry. Periodontal and osteoporotic parameters were compared among the groups and correlation coefficient between them was evaluated. The blood ALP and OC levels were similar among the groups with different periodontal condition, whereas the urine DPD level and BMD were significantly lower in advanced periodontitis group than the other groups(p<0.01). Probing depth was negatively related with BMD (r=-0.5, p<0.01) and positively related with patient age and the duration of menopause (r= 0.32 and 0.35 respectively, p<0.05). Clinical attachment loss was negatively related with BMD (r=-0.66, p<0.01), and positively related with urine DPD (r= 0.37, p<0.05). These results showed that postmenopausal women with advanced periodontitis had significantly decreased bone mineral density and suggests that decreased bone mineral density in postmenopausal women could be associated with periodontal tissue breakdown.

이온주입 공정을 이용한 4H-SiC p-n diode에 관한 시뮬레이션 연구 (Simulation study of ion-implanted 4H-SiC p-n diodes)

  • 이재상;방욱;김상철;김남균;구상모
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.131-131
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    • 2008
  • Silicon carbide (SiC) has attracted significant attention for high frequency, high temperature and high power devices due to its superior properties such as the large band gap, high breakdown electric field, high saturation velocity and high thermal conductivity. We performed Al ion implantation processes on n-type 4H-SiC substrate using a SILVACO ATHENA numerical simulator. The ion implantation model used a Monte-Carlo method. We studied the effect of channeling by Al implantation simulation in both 0 off-axis and 8 off-axis n-type 4H-SiC substrate. We have investigated the Al distribution in 4H-SiC through the variation of the implantation energies and the corresponding ratio of the doses. The implantation energies controlled 40, 60, 80, 100 and 120 keV and the implantation doses varied from $2\times10^{14}$ to $1\times10^{15}cm^{-2}$. In the simulation results, the Al ion distribution was deeper as increasing implantation energy and the doping level increased as increasing implantation doses. After the post-implantation annealing, the electrical properties of Al-implanted p-n junction diode were investigated by SILV ACO ATLAS numerical simulator.

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복합 권선형 송전급 고온초전도 변압기의 절연설계 연구 (The Research on Insulation Design for Transmission Class HTS Transformer with Composite Winding)

  • 천현권;곽동순;최재형;정종만;김현희;김상현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.204-205
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    • 2006
  • In the response to the demand for electrical energy, much effort aimed to develop and commercialize high temperature superconducting (HTS) power equipments has been made around the world. In Korea, companies and universities are developing a power distribution and transmission class HTS transformer that is one of the 21st century superconducting frontier projects. The composite winding of transmission class HTS transformer is concentrically arranged H1-L-H2 from center. H1 is continuous disk type, L is layer type and H3 is continuous disk type. For the development of transmission HTS transformer with composite winding, the cryogenic insulation technology should be established. We have been analyzed insulation composition and investigated electrical characteristics such as breakdown of $LN_2$, barrier, kapton films, surface flashover on FRP in $LN_2$. We are going to compare with measured each value and apply the value to most suitable insulating design of the HTS transformer.

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