• Title/Summary/Keyword: Boundary effects

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Fates of water and salts in non-aqueous solvents for directional solvent extraction desalination: Effects of chemical structures of the solvents

  • Choi, Ohkyung;Kim, Minsup;Cho, Art E.;Choi, Young Chul;Kim, Gyu Dong;Kim, Dooil;Lee, Jae Woo
    • Membrane and Water Treatment
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    • v.10 no.3
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    • pp.207-212
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    • 2019
  • Non-aqueous solvents (NASs) are generally known to be barely miscible, and reactive with polar compounds, such as water. However, water can interact with some NASs, which can be used as a new means for water recovery from saline water. This study explored the fate of water and salt in NAS, when saline water is mixed with NAS. Three amine solvents were selected as NAS. They had the same molecular formula, but were differentiated by their molecular structures, as follows: 1) NAS 'A' having the hydrophilic group ($NH_2$) at the end of the straight carbon chain, 2) NAS 'B' with symmetrical structure and having the hydrophilic group (NH) at the middle of the straight carbon chain, 3) NAS 'C' having the hydrophilic group ($NH_2$) at the end of the straight carbon chain but possessing a hydrophobic ethyl branch in the middle of the structure. In batch experiments, 0.5 M NaCl water was blended with NASs, and then water and salt content in the NAS were individually measured. Water absorption efficiencies by NAS 'B' and 'C' were 3.8 and 10.7%, respectively. However, salt rejection efficiency was 98.9% and 58.2%, respectively. NAS 'A' exhibited a higher water absorption efficiency of 35.6%, despite a worse salt rejection efficiency of 24.7%. Molecular dynamic (MD) simulation showed the different interactions of water and salts with each NAS. NAS 'A' formed lattice structured clusters, with the hydrophilic group located outside, and captured a large numbers of water molecules, together with salt ions, inside the cluster pockets. NAS 'B' formed a planar-shaped cluster, where only some water molecules, but no salt ions, migrated to the NAS cluster. NAS 'C', with an ethyl group branch, formed a cluster shaped similarly to that of 'B'; however, the boundary surface of the cluster looked higher than that of 'C', due to the branch structure in solvent. The MD simulation was helpful for understanding the experimental results for water absorption and salt rejection, by demonstrating the various interactions between water molecules and the salts, with the different NAS types.

Development of Panel-Based Rapid Aerodynamic Analysis Method Considering Propeller Effect (프로펠러 효과를 반영 가능한 패널 기반 신속 공력 해석 기법 개발)

  • Tai, Myungsik;Lee, Yebin;Oh, Sejong;Shin, Jeongwoo;Lim, Joosup;Park, Donghun
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.49 no.2
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    • pp.107-120
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    • 2021
  • Electric-powered distributed propulsion aircraft possess a complex wake flow and mutual interference with the airframe, due to the use of many propellers. Accordingly, in the early design stage, rapid aerodynamic and load analysis considering the effect of propellers for various configurations and flight conditions are required. In this study, an efficient panel-based aerodynamic analysis method that can take into account the propeller effects is developed and validated. The induced velocity field in the region of propeller wake is calculated based on Actuator Disk Theory (ADT) and is considered as the boundary condition at the vehicle's surface in the three-dimensional steady source-doublet panel method. Analyses are carried out by selecting an isolated propeller of the Korea Aerospace Research Institute (KARI)'s Quad Tilt Propeller (QTP) aircraft and the propeller-wing configuration of the former experimental study as benchmark problems. Through comparisons with the results of computational fluid dynamics (CFD) based on actuator methods, the wake velocity of propeller and the changes in the aerodynamic load distribution of the wing due to the propeller operation are validated. The method is applied to the analysis of the Optional Piloted Personal Aerial Vehicle (OPPAV) and QTP, and the practicality and validity of the method are confirmed through comparison and analysis of the computational time and results with CFD.

Numerical Study on Seismic Performance Evaluation of Circular Reinforced Concrete Piers Confined by Steel Plate (강판으로 보강된 원형철근콘크리트교각의 내진성능 평가에 관한 해석적 연구)

  • Lee, Myung-Jin;Park, Jong-Sup
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.1
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    • pp.116-122
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    • 2021
  • This study quantitatively evaluated the performance improvement of a circular reinforced concrete pier under dynamic load with strengthening using a steel plate. Various three-dimensional elements were applied using the finite element program ABAQUS. The analytical parameters included the ratios of the steel cover length to the pier's total height and the ratios of the steel cover thickness to the pier diameter for inelastic-nonlinear analysis. The lower part of the pier had fixed boundary conditions, and lateral repetitive loads were applied at the top of the pier. The pier was investigated to evaluate the dynamic performance based on the load-displacement curve, stress-strain curve, ductility, energy absorption capability, and energy ratio. The yield and ultimate loads of piers with steel covers increased by 3.76 times, and the energy absorption capability increased by 4 times due to the confinement effects caused by the steel plate. A plastic hinge part of the column with a steel plate improved the ductility, and the thicker the steel plate was, the greater the energy absorption capacity. This study shows that the reinforced pier should be improved in terms of the seismic performance.

Multiscale Finite Element Analysis of Needle-Punched C/SiC Composites through Subcell Modeling (서브셀 모델링을 통한 니들 펀치 C/SiC 복합재료의 멀티스케일 유한요소해석)

  • Lim, Hyoung Jun;Choi, Ho-Il;Lee, Min-Jung;Yun, Gun Jin
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.34 no.1
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    • pp.51-58
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    • 2021
  • In this paper, a multi-scale finite element (FE) modeling methodology for three-dimensional (3D) needle-punched (NP) C/SiC with a complex microstructure is presented. The variations of the material properties induced by the needle-punching process and complex geometrical features could pose challenges when estimating the material behavior. For considering these features of composites, a 3D microscopic FE approach is introduced based on micro-CT technology to produce a 3D high fidelity FE model. The image processing techniques of micro-CT are utilized to generate discrete-gray images and reconstruct the high fidelity model. Furthermore, a subcell modeling technique is developed for the 3D NP C/SiC based on the high fidelity FE model to expand to the macro-scale structural problem. A numerical homogenization approach under periodic boundary conditions (PBCs) is employed to estimate the equivalent behavior of the high fidelity model and effective properties of subcell components, considering geometry continuity effects. For verification, proposed models compare excellently with experimental results for the mechanical behavior of tensile, shear, and bending under static loading conditions.

Evaluation of NDVI Retrieved from Sentinel-2 and Landsat-8 Satellites Using Drone Imagery Under Rice Disease (드론 영상을 이용한 Sentinel-2, Landsat-8 위성 NDVI 평가: 벼 병해 발생 지역을 대상으로)

  • Ryu, Jae-Hyun;Ahn, Ho-yong;Na, Sang-Il;Lee, Byungmo;Lee, Kyung-do
    • Korean Journal of Remote Sensing
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    • v.38 no.6_1
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    • pp.1231-1244
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    • 2022
  • The frequency of exposure of field crops to stress situations is increasing due to abnormal weather conditions. In South Korea, large-scale diseases in representative paddy rice cultivation area were happened. There are limits to field investigation on the crop damage due to large-scale. Satellite-based remote sensing techniques are useful for monitoring crops in cities and counties, but the sensitivity of vegetation index measured from satellite under abnormal growth of crop should be evaluated. The goal is to evaluate satellite-based normalized difference vegetation index (NDVI) retrieved from different spatial scales using drone imagery. In this study, Sentinel-2 and Landsat-8 satellites were used and they have spatial resolution of 10 and 30 m. Drone-based NDVI, which was resampled to the scale of satellite data, had correlation of 0.867-0.940 with Sentinel-2 NDVI and of 0.813-0.934 with Landsat-8 NDVI. When the effects of bias were minimized, Sentinel-2 NDVI had a normalized root mean square error of 0.2 to 2.8% less than that of the drone NDVI compared to Landsat-8 NDVI. In addition, Sentinel-2 NDVI had the constant error values regardless of diseases damage. On the other hand, Landsat-8 NDVI had different error values depending on degree of diseases. Considering the large error at the boundary of agricultural field, high spatial resolution data is more effective in monitoring crops.

Effect of sintering temperature on microstructure and dielectric properties in (Dy, Mg)-doped BaTiO3 (Dy 및 Mg가 첨가된 BaTiO3에서 소결 온도가 미세구조와 유전특성에 미치는 영향)

  • Woo, Jong-Won;Kim, Sung-Hyun;Choi, Moon-Hee;Jeon, Sang-Chae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.5
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    • pp.175-182
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    • 2022
  • Rare-earth elements were doped with Mg to enhance the temperature stability of dielectric properties of BaTiO3 for its application to MLCC (Multi-Layer Ceramic Capacitor). The additives strongly affect both grain growth and densification behaviors during sintering, and hence dielectric properties. The additive effects therefore should be examined in each system with different additives. This study investigated the crystal structure, grain growth and densification behaviors and related variations in dielectric constant with respect to sintering temperature. Dielectric constant appears to be varied with grain size in a temperature range between 1200 and 1300℃, suggesting the importance of grain size control. The temperature dependence of grain size variation was well explained by an established theory correlating the grain growth behavior with grain boundary structure. This accordance provides a basis for sintering technique to control grain growth thus to improve dielectric constant in rare-earth doped BaTiO3.

Evaluation of the Air Temperature and Wind Observation Environments Around Automated Synoptic Observing Systems in Summer Using a CFD Model (전산유체역학 모델을 활용한 여름철 종관기상관측소의 기온과 바람 관측 환경 평가)

  • Kang, Jung-Eun;Rho, Ju-Hwan;Kim, Jae-Jin
    • Korean Journal of Remote Sensing
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    • v.38 no.5_1
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    • pp.471-484
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    • 2022
  • This study examined the effects of topography and buildings around the automated synoptic observing system (ASOS) on the observation environment of air temperatures and wind speeds and directions using a computational fluid dynamics(CFD) model. For this, we selected 10 ASOSs operated by the Korea Meteorological Administration. Based on the data observed at the ASOSs in August during the recent ten years, we established the initial and boundary conditions of the CFD model. We analyzed the temperature observation environment by comparing the temperature change ratios in the case considering the actual land-cover types with those assuming all land-cover types as grassland. The land-cover types around the ASOSs significantly affected the air temperature observation environment. The temperature change ratios were large at the ASOSs around which buildings and roads were dense. On the other hand, when all land covers were assumed as grassland, the temperature change ratios were small. Wind speeds and directions at the ASOSs were also significantly influenced by topography and buildings when their heights were higher or similar to the observation heights. Obstacles even located at a long distance affected the wind observation environments. The results in this study would be utilized for evaluating ASOS observation environments in the relocating or newly organizing steps.

Groundwater control measures for deep urban tunnels (도심지 대심도 터널의 지하수 변동 영향 제어 방안)

  • Jeong, Jae-Ho;Kim, Kang-Hyun;Song, Myung-Kyu;Shin, Jong-Ho
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.23 no.6
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    • pp.403-421
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    • 2021
  • Most of the urban tunnels in Korea, which are represented by the 1st to 3rd subways, use the drainage tunnel by NATM. Recently, when a construction project that actively utilizes large-scale urban space is promoted, negative effects that do not conform to the existing empirical rules of urban tunnels may occur. In particular, there is a high possibility that groundwater fluctuations and hydrodynamic behavior will occur owing to the practice of tunnel technology in Korea, which has mainly applied the drainage tunnel. In order to solve the problem of the drainage tunnel, attempts are being made to control groundwater fluctuations. For this, the establishment of tunnel groundwater management standard concept and the analysis of the tunnel hydraulic behavior were performed. To prevent the problem of groundwater fluctuations caused by the construction of large-scale tunnels in urban areas, it was suggested that the conceptual transformation of the empirical technical practice, which is applied only in the underground safety impact assessment stage, to the direction of controlling the inflow in the tunnel, is required. And the relationship between the groundwater level and the inflow of the tunnel required for setting the allowable inflow when planning the tunnel was derived. The introduction of a tunnel groundwater management concept is expected to help solve problems such as groundwater fluctuations, ground settlement, depletion of groundwater resources, and decline of maintenance performance in various urban deep tunnel construction projects to be promoted in the future.

Effects of Perceived Quality on Consumers' Intention to Use O2O Services: Focusing on Technology Acceptance Model Perspective (O2O서비스에 대한 지각된 품질이 소비자들의 O2O서비스 사용 의도에 미치는 영향: 기술수용모델 관점에서의 접근)

  • Je, Jiyeon;Kim, Mikyoung;Oh, Sangjin
    • The Journal of the Korea Contents Association
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    • v.22 no.9
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    • pp.126-146
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    • 2022
  • With the development of IT technology, consumers' shopping behaviors have diversified, and O2O services that remove the boundary between online and offline are increasing. With the development of O2O services, it is bringing about new changes in offline retailers that are facing limitations against the continuous growth of online. Drawing upon Technology Acceptance Model, this study investigates the effect of service quality perceived by O2O service users on consumers' intention to use O2O services. The result confirmed that the perceived quality, an external variable, affects the perceived usefulness and perceived ease of use, which are the main variables of the Technology Acceptance Model, and the perceived usefulness and perceived ease of use in turn have a significant effect on attitude and behavioral intention. In particular, it was found that the higher the perceived ease of use of the user, the higher the perceived usefulness and positive influence on the attitude. The results of this study suggest that in order to increase the utilization of O2O service by users, it is necessary to highlight the perceived quality of service and at the same time manage convenience and usefulness. This is expected to provide meaningful directions for companies attempting to advance O2O services.

Experimental Assessment of the Methanol Addition Effect on the Tribological Characteristics of Ni-based Alloy (메탄올 첨가에 따른 Ni 기반 합금의 트라이볼로지 특성 변화에 대한 실험적 연구)

  • Junemin Choi;Sangmoon Park;Youngjun Kim;Sunghoon Kim;Hyemin Kim;Jeongeon Park;JeongWon Yu;Myeonggyu Lee;Hyeonwoo Lee;Koo-Hyun Chung
    • Tribology and Lubricants
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    • v.39 no.2
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    • pp.49-55
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    • 2023
  • Currently, the demand for green technologies toward a sustainable future is rapidly increasing due to growing concern over environmental issues. Methanol is biodegradable and can provide clean combustion to reduce sulfur oxide and nitrogen oxide emissions, and therefore it is a candidate fuel for marine engines. However, the effect of methanol on tribological characteristic degradation should be addressed for methanol-fueled engines. In this study, the methanol addition effects on tribological characteristic degradation is experimentally assessed using a pin-on-disk tribo-tester. Ni-based alloy is used as a target material due to its broad applicability as an engine component material. For a lubricant, engine oil with and without methanol are used. The tests are conducted for up to 10,000 cycles under boundary lubrication while the change in friction force is monitored. Additionally, the wear rate is determined based on laser scanning confocal microscope data. An additional test in which methanol is added at regular intervals is performed with an aim to directly observe its effect on friction. Overall, the friction coefficient increases slightly with increasing methanol concentration. Furthermore, the wear rate of the pin and disk increase significantly with methanol addition. The results also indicate that the friction increases instantaneously with methanol addition at the contacting interface. These findings may be useful for better understanding the methanol effect on the tribological characteristics of Ni-based alloys for methanol-fueled engines with improved performance.