• Title/Summary/Keyword: Boron analysis

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Wear Resistance of c-BN Surface Modified 316L Austenitic Stainless Steel by R.F. Sputtering (R.F. sputtering 방법에 의해 c-BN 표면처리된 316L 오스테나이트계 스테인리스 강의 내마모특성 향상)

  • Lee, Kwang-Min;Jeong, Se-Hoon;Park, Sung-Tae
    • Korean Journal of Materials Research
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    • v.20 no.4
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    • pp.194-198
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    • 2010
  • Cubic boron nitride (c-BN) is a promising material for use in many potential applications because of its outstanding physical properties such as high thermal stability, high abrasive wear resistance, and super hardness. Even though 316L austenitic stainless steel (STS) has poor wear resistance causing it to be toxic in the body due to wear and material chips, 316L STS has been used for implant biomaterials in orthopedics due to its good corrosion resistance and mechanical properties. Therefore, in the present study, c-BN films with a $B_4C$ layer were applied to a 316L STS specimen in order to improve its wear resistance. The deposition of the c-BN films was performed using an r.f. (13.56 MHz) magnetron sputtering system with a $B_4C$ target. The coating layers were characterized using XPS and SEM, and the mechanical properties were investigated using a nanoindenter. The friction coefficient of the c-BN coated 316L STS steel was obtained using a pin-on-disk according to the ASTM G163-99. The thickness of the obtained c-BN and $B_4C$ were about 220 nm and 630 nm, respectively. The high resolution XPS spectra analysis of B1s and N1s revealed that the c-BN film was mainly composed of $sp^3$ BN bonds. The hardness and elastic modulus of the c-BN measured by the nanoindenter were 46.8 GPa and 345.7 GPa, respectively. The friction coefficient of the c-BN coated 316L STS was decreased from 3.5 to 1.6. The wear property of the c-BN coated 316L STS was enhanced by a factor of two.

The characteristic analysis of TCO/p-layer interface in Amorphous Silicon Solar cell (비정질 실리콘 태양전지에서 투명전도막/p층 계면 특성분석)

  • Lee, Ji-Eun;Lee, Jeong-Chul;O, Byung-Sung;Song, Jin-Soo;Yoon, Kyung-Hoon
    • New & Renewable Energy
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    • v.3 no.4
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    • pp.63-68
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    • 2007
  • 유리를 기판으로 하는 superstrate pin 비정질 실리콘 태양전진에서 전면 투명전도막(TCO)과 p-층의 계면은 태양전지 변환효율에 큰 영향을 미친다. 면투명전도막(TCO)으로 현재 일반적으로 사용되는 ZnO:Al는 $SnO_2:F$보다 전기, 광학적으로 우수하고, 안개율 (Haze)높으며, 수소 플라즈마에서 안정성이 높은 특징을 갖고 있다. 그래서 박막 태양전지의 특성향상에 매우 유리하나, 태양전지로 제조했을 때, $SnO_2$보다 충진율(Fill Factor:F.F)과 $V_{oc}$가 감소한다는 단점을 가지고 있다. 본 실험실에서는 $SnO_2:F$dml F.F.가 72%이 나온 반면 ZnO:Al의 F.F은 68%에 그쳤다. 이들 원인을 분석하기 위해 TCO/p-layer의 전기적 특성을 알아 본 결과, $SnO_2:F$보다 ZnO:Al의 직렬저항이 높게 측정되었다. 이러한 결과를 바탕으로 p-layer에 $R=(H_2/SiH_4)=25$로 변화, p ${\mu}c$-Si:H/p a-SiC:H로 p-layer 이중 증착, p-layer의 boron doping 농도를 증가시키는 실험을 하였다. 직렬저항이 가장 낮았던 p ${\mu}c$-Si:H/p a-SiC:H 인 p-layer 이중 증착에서 $V_{oc}$는 0.95V F.F는 70%이상이 나왔다. 이들 각 p층의 $E_a$(Activiation Energy)를 구해본 결과, ${\mu}c$-Si:H의 Ea 가 가장 낮은 것을 관찰 할 수 있었다.

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Radiation Effects on Fiber Bragg Grating Sensors Written in UV KrF Laser Process Condition (UV KrF 레이저 공정조건에 따른 FBG 센서의 방사선 영향)

  • Kim, Jong-Yeol;Lee, Nam-Ho;Jung, Hyun-Kyu
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.20 no.1
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    • pp.161-166
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    • 2016
  • We studied the effect of $Co^{60}$ gamma-radiation on the FBGs by a variation of grating the fabrication parameters. The FBGs were fabricated in a different UV KrF laser intensity using the same boron co-doped photo-sensitive fiber and exposed to gamma-radiation up to a dose of 33.8 kGy. According to the experimental data and analysis results, We confirmed that the laser intensity for grating inscription has a highly effect on the radiation sensitivity of the FBGs and the radiation-induced Bragg wavelength shift by the change of laser process condition showed a difference more than about 30 %.

A effect of the back contact silicon solar cell with surface texturing size and density (표면 텍스쳐링 크기와 밀도가 후면 전극 실리콘 태양전지에 미치는 영향)

  • Jang, Wanggeun;Jang, Yunseok;Pak, Jungho
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.112.1-112.1
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    • 2011
  • The back contact solar cell (BCSC) has several advantages compared to the conventional solar cell since it can reduce grid shadowing loss and contact resistance between the electrode and the silicon substrate. This paper presents the effect of the surface texturing of the silicon BCSC by varying the texturing depth or the texturing gap in the commercially available simulation software, ATHENA and ATLAS of the company SILVACO. The texturing depth was varied from $5{\mu}m$ to $150{\mu}m$ and the texturing gap was varied from $1{\mu}m$ to $100{\mu}m$ in the simulation. The resulting efficiency of the silicon BCSC was evaluated depending on the texturing condition. The quantum efficiency and the I-V curve of the designed silicon BCSC was also obtained for the analysis since they are closely related with the solar cell efficiency. Other parameters of the simulated silicon BCSC are as follows. The substrate was an n-type silicon, which was doped with phosphorous at $6{\times}10^{15}cm^{-3}$, and its thickness was $180{\mu}m$, a typical thickness of commercial solar cell substrate thickness. The back surface field (BSF) was $1{\times}10^{20}\;cm^{-3}$ and the doping concentration of a boron doped emitter was $8.5{\times}10^{19}\;cm^{-3}$. The pitch of the silicon BCSC was $1250{\mu}m$ and the anti-reflection coating (ARC) SiN thickness was $0.079{\mu}m$. It was assumed that the texturing was anisotropic etching of crystalline silicon, resulting in texturing angle of 54.7 degrees. The best efficiency was 25.6264% when texturing depth was $50{\mu}m$ with zero texturing gap in case of low texturing depth (< $100{\mu}m$).

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Simulations of BEAVRS benchmark cycle 2 depletion with MCS/CTF coupling system

  • Yu, Jiankai;Lee, Hyunsuk;Kim, Hanjoo;Zhang, Peng;Lee, Deokjung
    • Nuclear Engineering and Technology
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    • v.52 no.4
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    • pp.661-673
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    • 2020
  • The quarter-core simulation of BEAVRS Cycle 2 depletion benchmark has been conducted using the MCS/CTF coupling system. MCS/CTF is a cycle-wise Picard iteration based inner-coupling code system, which couples sub-channel T/H (thermal/hydraulic) code CTF as a T/H solver in Monte Carlo neutron transport code MCS. This coupling code system has been previously applied in the BEAVRS benchmark Cycle 1 full-core simulation. The Cycle 2 depletion has been performed with T/H feedback based on the spent fuel materials composition pre-generated by the Cycle 1 depletion simulation using refueling capability of MCS code. Meanwhile, the MCS internal one-dimension T/H solver (MCS/TH1D) has been also applied in the simulation as the reference. In this paper, an analysis of the detailed criticality boron concentration and the axially integrated assembly-wise detector signals will be presented and compared with measured data based on the real operating physical conditions. Moreover, the MCS/CTF simulated results for neutronics and T/H parameters will be also compared to MCS/TH1D to figure out their difference, which proves the practical application of MCS into the BEAVRS benchmark two-cycle depletion simulations.

Construction of Vehicle Door Impact Beam Using Hot Stamping Technology (핫스탬핑에 의한 자동차 도어 임팩트빔의 개발)

  • Lee, Hyun-Woo;Hwang, Jung-Bok;Kim, Sun-Ung;Kim, Won-Hyuck;Yoo, Seung-Jo;Lim, Hyun-Woo;Yum, Young-Jin
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.6
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    • pp.797-803
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    • 2010
  • A vehicle door impact beam made of a thin sheet of steel has been constructed using hot stamping technology with the aim of ensuring occupant safety in the event of a side collision. This technology has been used to increase the strength of the vehicle body parts and to reduce the weight of the door impact beam as well as the number of work processes. Mechanical tests were performed to determine the material properties of the hot-stamped specimen and the results of the tests were used as input data in stamping and structural simulation in order to obtain the optimal design of door impact beam. The strength of the hot-stamped door impact beam increased to a value that was 102% higher than that of conventional pipe-shaped door impact beam. A weight reduction of 34% was also achieved.

Key Factors for the Development of Silicon Quantum Dot Solar Cell

  • Kim, Gyeong-Jung;Park, Jae-Hui;Hong, Seung-Hwi;Choe, Seok-Ho;Hwang, Hye-Hyeon;Jang, Jong-Sik
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.207-207
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    • 2012
  • Si quantum dot (QD) imbedded in a $SiO_2$ matrix is a promising material for the next generation optoelectronic devices, such as solar cells and light emission diodes (LEDs). However, low conductivity of the Si quantum dot layer is a great hindrance for the performance of the Si QD-based optoelectronic devices. The effective doping of the Si QDs by semiconducting elements is one of the most important factors for the improvement of conductivity. High dielectric constant of the matrix material $SiO_2$ is an additional source of the low conductivity. Active doping of B was observed in nanometer silicon layers confined in $SiO_2$ layers by secondary ion mass spectrometry (SIMS) depth profiling analysis and confirmed by Hall effect measurements. The uniformly distributed boron atoms in the B-doped silicon layers of $[SiO_2(8nm)/B-doped\;Si(10nm)]_5$ films turned out to be segregated into the $Si/SiO_2$ interfaces and the Si bulk, forming a distinct bimodal distribution by annealing at high temperature. B atoms in the Si layers were found to preferentially substitute inactive three-fold Si atoms in the grain boundaries and then substitute the four-fold Si atoms to achieve electrically active doping. As a result, active doping of B is initiated at high doping concentrations above $1.1{\times}10^{20}atoms/cm^3$ and high active doping of $3{\times}10^{20}atoms/cm^3$ could be achieved. The active doping in ultra-thin Si layers were implemented to silicon quantum dots (QDs) to realize a Si QD solar cell. A high energy conversion efficiency of 13.4% was realized from a p-type Si QD solar cell with B concentration of $4{\times}1^{20}atoms/cm^3$. We will present the diffusion behaviors of the various dopants in silicon nanostructures and the performance of the Si quantum dot solar cell with the optimized structures.

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Design Study of A Spent Fuel Shipping Cask for Korea Nuclear Unit-1 (고리 1호기의 기사용 핵연료 집합체 수송용기 설계에 관한 연구)

  • Moo Han Kim;Chang Sun Kang
    • Nuclear Engineering and Technology
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    • v.14 no.4
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    • pp.196-203
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    • 1982
  • To transport the spent fuel assemblies of Korea Nuclear Unit 1, which is a Westinghouse type two loop pressurized water reactor, it has been found that steel is the most appropriate material for the design of a shipping cask in comparison with lead and depleted uranium. The proposed shipping cask will transport nine fuel assemblies at the same time and is well within the weight limit of transportation by unrestricted rail car. The cask requires 33cm thick steel shield and 27cm thick water region to satisfy the 3 feet apart dose rate limit set forth in 10 CFR 71, and 1.27cm thick steel boron fuel basket to hold the fuel elements inside the cask and control the effective multiplication factor. As a safety analysis, the fuel cladding and centerline temperatures were calculated under the accident condition of complete loss of water coolant, and it was found that the temperature was much lower than the limit of the melting point. k$_{eff}$ was calculated with fresh fuel assemblies, which was found to be well lower than 0.95. For shielding computation, the multipurpose Monte Carlo code MORSE-CG and one dimensional discrete ordinates transport code ANISN were used, and the Monte Carlo codes KENO and MORSE-CG were used for criticality calculation. The radiation source terms were calculated using ORIGEN-79.9.

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Chemical Characterization of Oscillatory Zoned Tourmaline from Diaspore Nodule, an Aluminum-rich Clay Deposit, Milyang, South Korea (밀양 고알루미나 점토광상 다이아스포아 단괴내의 진동누대 전기석의 화학적 특징)

  • Choo, Chang-Oh;Kim, Yeong-Kyoo
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.3 s.45
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    • pp.227-236
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    • 2005
  • Hydrothermal tourmaline occurs as aggregates or dissemination in the diaspore nodule from an aluminum-rich clay deposit, Milyang, southeastern Korea. Most crystals of tourmaline show complex textures that are finely zoned. The fine-scale chemical zonation of hydrothermal tourmaline reflects the fluctuation conditions that would be expected from fluid mixing in open systems. Oscillatory chemical zoning in tourmaline formed and showed similar patterns, regardless of its crystallographic directions. Mg was enriched in the early stage of crystal growth while Fe was enriched in the later stage, with fluctuations of the ratio of Fe to Mg. Chemical analysis, BSE images, and X-ray compositional maps confirm that the oscillatory Boning in tourmaline is exclusively controlled by the variations of Fe and Mg contents, but the contribution of boron to the zonation is insignificant. The fact that tourmaline altered to diaspore and dickite indicates that tourmaline was unstable with respect to these aluminous minerals as the B, Fe, and Mg activities decreased. Therefore, the aluminum activity may control the stability of tourmaline in the hydrothermal system.

Cross Talk Experiment with Two-element CdTe Detector and Collimator for BNCT-SPECT

  • Manabe, Masanobu;Ohya, Ryosuke;Saraue, Nobuhide;Sato, Fuminobu;Murata, Isao
    • Journal of Radiation Protection and Research
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    • v.41 no.4
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    • pp.328-332
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    • 2016
  • Background: Boron Neutron Capture Therapy (BNCT) is a new radiation therapy. In BNCT, there exists some very critical problems that should be solved. One of the severest problems is that the treatment effect cannot be known during BNCT in real time. We are now developing a SPECT (single photon emission computed tomography) system (BNCT-SPECT), with a cadmium telluride (CdTe) semiconductor detector. BNCT-SPECT can obtain the BNCT treatment effect by measuring 478 keV gamma-rays emitted from the excited state of $^7Li$ nucleus created by $^{10}B(n,{\alpha})$ $^7Li$ reaction. In the previous studies, we investigated the feasibility of the BNCT-SPECT system. As a result, the S/N ratio did not meet the criterion of S/N > 1 because deterioration of the S/N ratio occurred caused by the influence of Compton scattering especially due to capture gamma-rays of hydrogen. Materials and Methods: We thus produced an arrayed detector with two CdTe crystals to test cross talk phenomenon and to examine an anti-coincidence detection possibility. For more precise analysis for the anti-coincidence detection, we designed and made a collimator having a similar performance to the real BNCT-SPECT. Results and Discussion: We carried out experiments with the collimator to examine the effect of cross talk of scattering gamma-rays between CdTe elements more practically. As a result of measurement the coincidence events were successfully extracted. Conclusion: We are now planning to carry out evaluation of coincidence rate from the measurement and comparison of it with the numerical calculations.