• Title/Summary/Keyword: Boratabenzene

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The Study on the Mechanism for Oxidation Reaction of Boratabenzene by Cyclic Voltammetry (Cyclic Voltammetry를 이용한 Boratabenzene의 산화반응 Mechanism 연구)

  • Shin, Ueon-Sang
    • Analytical Science and Technology
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    • v.15 no.6
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    • pp.550-555
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    • 2002
  • The oxidation mechanism of boratabenzene was studied. As a model compound the ferrocene analogue (${\eta}^6$-1-Methylboratabenzene)(${\eta}^5$-Pentamethylcyclopentadiennyl)iron 3 was chosen. The complex underwent irreversible oxidation in the presence of ortho proton on the ring and a methyl group on the boron atom in methanol medium. Chemical oxidations with $Hg(OAc)_2$, $HgSO_4$, $Cu(OH)_2$, $AgCF_3SO_3$ or $FeCl_3$ in MeOH gave, via a transition state [3], at first the derivates 6 and 7, which were converted to each 8 and 9.