• Journal of the Korean Society for Heat Treatment
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• v.6 no.1
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• pp.9-16
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• 1993

To investigate the properties of diffusion bonding of 7050 Al alloy, the diffusion bonding joints have been produced in self-made diffusion bonding hot-press which admits a defined application of the bonding pressure during the heating phase and also rapid cooling after the bonding process with various bonding condition. The strength of the bond increases with increasing the bonding time and temperature. Shear test at toom temperature showed that high strength up to 70% that of parent metal (320 MPa), 220 MPa for the specimen bonded 14 hr at $560^{\circ}C$, with 3 MPa. In this case, however, there is large deformation more than 20% reduction in thickness. The results were correlated with joint characteristics found by optical microstructure and by fractography by SEM. When the strengths of the bonds are more than 50% that of parent metal, a great deal of dimples stretched along the direction of shear stress are observed over the fractured surface of the bond. On the microstructure of the bond line, initial mophology of the bond line disapeared for the grain boundary migration with increasing the bonding time.

• Bulletin of the Korean Chemical Society
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• v.35 no.9
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• pp.2797-2802
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• 2014

Nucleophilic substitution reactions of Y-aryl methyl (8) and Y-aryl propyl (10) chlorothiophosphates with substituted anilines and deuterated anilines are investigated kinetically in acetonitrile at $55.0^{\circ}C$. A concerted mechanism is proposed for 8 based on the negative ${\rho}_{XY}$ (= -0.23) value, while a stepwise mechanism with a rate-limiting leaving group departure from the intermediate is proposed for 10 based on the positive ${\rho}_{XY}$ (= +0.68) value. The deuterium kinetic isotope effects (DKIEs; $k_H/k_D$) are 0.89-1.28 and 0.62-1.20 with 8 and 10, respectively. Primary normal and secondary inverse DKIEs are rationalized by a frontside attack involving hydrogen bonded, four-center-type transition state and backside attack involving in-line-type transition state, respectively.

• Bulletin of the Korean Chemical Society
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• v.34 no.6
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• pp.1829-1834
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• 2013

The nucleophilic substitution reactions of Y-aryl ethyl isothiocyanophosphates with substituted X-anilines and deuterated X-anilines were investigated kinetically in acetonitrile at $75.0^{\circ}C$. The free energy relationships with X in the nucleophiles exhibited biphasic concave downwards with a break point at X = H. A stepwise mechanism with rate-limiting bond formation for strongly basic anilines and with rate-limiting bond breaking for weakly basic anilines is proposed based on the negative and positive ${\rho}_{XY}$ values, respectively. The deuterium kinetic isotope effects (DKIEs; $k_H/k_D$) changed gradually from primary normal with strongly basic anilines, via primary normal and secondary inverse with aniline, to secondary inverse with weakly basic anilines. The primary normal and secondary inverse DKIEs were rationalized by frontside attack involving hydrogen bonded, four-center-type TSf and backside attack involving in-line-type TSb, respectively.

• Proceedings of the KSME Conference
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• 2004.11a
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• pp.226-231
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• 2004

Press fitting method for joining of a hybrid tube and steel ring with small teeth for automotive aluminum/composite hybrid propeller shaft was devised to improve reliability and to reduce manufacturing cost, compared to other joining methods such as an adhesively bonded joint, bolted joint or welded joint. To obtain high strength of the press fit joint, an optimal design method for the teeth was devised with respect to number and shape of the steel teeth. Torsional static, fatigue tests and finite element analysis of the press fit joint were performed with respect to experimental variables. The developed optimal design method predicted well the static torque capability and failure mode of the press fit joint. Also, it provided design guide line of press fit joint for improving torsional static and fatigue characteristics.

• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3811-3816
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• 2013

Nucleophilic substitution reactions of ethyl methyl (2), ethyl propyl (4) and diisopropyl (7) chlorothiophosphates with substituted anilines and deuterated anilines are investigated kinetically in acetonitrile at $55.0^{\circ}C$. A concerted mechanism is proposed based on the selectivity parameters. The deuterium kinetic isotope effects (DKIEs; $k_H/k_D$) are secondary inverse ($k_H/k_D=0.66-0.99$) with 2, primary normal and secondary inverse ($k_H/k_D=0.78-1.19$) with 4, and primary normal ($k_H/k_D=1.06-1.21$) with 7. The primary normal and secondary inverse DKIEs are rationalized by frontside attack involving hydrogen bonded, four-center-type transition state, and backside attack involving in-line-type transition state, respectively. The anilinolyses of ten chlorothiophosphates are examined based on the reactivity, steric effect of the two ligands, thio effect, reaction mechanism, DKIE and activation parameter.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 1998.10a
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• pp.313-322
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• 1998

Tappet has wear problems like scuffing or pitting because of high Hertzian contact stress by line contact type between cam and tappet. To overcome this wear problems, we developed the high wear resistant tappet. Developed tappet consists of WC base alloyed tip and steel body. These two parts were directly bonded each other at high temperature under vacuum condition. To estimate the wear resistance of tungsten carbide tappet, we perform the scuffing test and engine dynamo test. As the result, tungsten carbide tappet has better wear resistance than conventionally chilled iron tappet.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2004.08a
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• pp.240-248
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• 2004

Recently, the customer's demands for automotive steel sheet have been diversified and sterned more. Therefore, as the tendency of auto industry light-weight, one among these requirements is the trend for high strength together with the thinness of automotive steel sheet. Because Mn added essentially in producing high strength steel sheet is bonded strongly with oxygen, the Fine oxidation layer was created at the welding face after the flash butt welding operated in entry section of pickling line. Thereby it was caused the crack or breakage of welding part in process of cold rolling. At this research, in order to protect the contact Mn with oxygen in atomosphere it was considered to fire oxygen with LNG and the related researches have been gone forward with the find out concrete and to apply them to operation.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 2005.05a
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• pp.264-271
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• 2005

This study investigates the behavior of fatigue crack propagating between holes or holes filled with another materials. When holes or the holes bonded with another materials exist near center crack symmetrically, crack propagation rate is influenced by the bonding force of brazing part and the elastic modulus ratio of another material to matrix. It is experimentally and analytically confirmed that the center crack stops when its tip reaches near the center line of the holes and a small crack is initiated from the boundaries of holes or the holes filled with another materials and it propagates to final fracture. The mechanical behaviors of center crack near another materials are also investigated.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.14 no.6
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• pp.74-82
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• 2005

This study investigates the behavior of fatigue crack propagating between holes or holes filled with another materials. When holes or the holes bonded with another materials exist near center crack symmetrically, crack propagation rate is influenced by the bonding force of brazing part and the elastic modulus ratio of another material to matrix. It is experimentally and analytically confirmed that the center crack stops when its tip reaches near the center line of the holes and a small crack is initiated from the boundaries of holes or the holes filled with another materials and it propagates to final fracture. The mechanical behaviors of center crack near another materials are also investigated.

• Bulletin of the Korean Chemical Society
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• v.22 no.4
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• pp.383-387
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• 2001

The kinetics and mechanism of the reactions of thiophenyl dimethylacetates (TDA) and trimethylacetates (TTA) with benzylamines in acetonitrile are studied. The reactions are first order in both the amine and the substrate. Relatively large values of ${\beta}X(\betanuc$ = 1.1-1.5; TDA and 1.1-1.5; TTA) and ${\beta}Z({\beta}lg$ = -1.8~-2.0; DTA and -1.3~-1.6; TTA) for benzylamines, significantly large kH/kD values (=1.2-1.5; DTA and 1.2-1.5; TTA) involving deuterated benzylamines, and large ${\rho}XZ$ (=0.82; TDA and 1.05; TTA) values are interpreted to indicate stepwise acyl transfer mechanism, but with the hydrogen bonded four center type transition state for benzylamine. The relatively greater magnitudes of ${\rho}XZ$ and the secondary kinetic isotope effects involving deuterated nucleophiles are in line with the proposed mechanism.