• 한국동물학회지
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• 제13권3호
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• pp.75-84
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• 1970

蛋白質의 放射線分解의 기작을 밝히는 연구의 일환으로, 특히 peptide 結合의 분해의 기작을 구명하기 위하여 Glycylglycylglycine의 水溶液과 固體를 酸素의 존재하에서와 無酸素하에서 r 線을 조사하여 分解生成物을 여지크로마토그라프로 분리하였고, carbonyl 化合物과 amide를 각각 分光光度法과 微凉摘定法으로 정량하였으나 放射線障害를 평가하기 위하여 赤外線 spectrum과 紫外線 spectrum을 얻어 검토하였다. 水溶液과 固體에 있어서의 peptide 結合의 분해기작은 근본적인 차이가 있는 것으로 여겨지며, 전자에서는 월등하게 분해가 많이 일어난데 반해서 후자에서는 무시할 정도에 지나지 않았다. 한편, 水溶液의 경우 酸素의 유무에 따라 현저한 영향은 보이지 않았으나 無酸素하에서는 遊離基의 再結合이 일어나는 점이 특기할만 하였다. 水溶液에 있어서의 peptide 結合의 분해기구는 Garrison 一派가 주장한 기작에 의해서 일어나는 것이 분명하여 脫水素反應에 뒤이어 加水分解反應에 의해서 amide 와 carbonyl 이 생성되는 것으로 보이며, 固體의 경우도 $\\alpha$-炭素의 부위가 방사선의 공격을 가장 많이 받는 것으로 추정되나 그 정도는 미미한 것에 지나지 않는 것으로 생각되었다.

• Computers and Concrete
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• 제14권3호
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• pp.233-245
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• 2014

In this paper, a rule based Mamdani type fuzzy logic model for prediction of slippage at maximum tensile strength and slippage at rupture of structural lightweight concretes were discussed. In the model steel rebar diameters and development lengths were used as inputs. The FL model and experimental results, the coefficient of determination R2, the Root Mean Square Error were used as evaluation criteria for comparison. It was concluded that FL was practical method for predicting slippage at maximum tensile strength and slippage at rupture of structural lightweight concretes.

• 대한화학회지
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• 제59권2호
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• pp.132-135
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• 2015

Bonding force and stiffness in amine-linked single-molecule junctions for Ag electrodes were measured using a home-built conducting atomic force microscope under ambient conditions at room temperature. For comparison, Au electrodes were used to measure the rupture force and stiffness of the molecular junctions. The traces of the force along with the conductance showed a characteristic saw-tooth pattern owing to the breaking of the metal atomic contacts or the metal-molecule- metal junctions. We found the rupture force and stiffness for Ag are smaller than those for Au electrodes. Furthermore, we observed that the force required to break the amine-Ag bond in the conjugated molecule, 1,4-benzenediamine, is smaller than in 1,4-butanediamine which is fully saturated. These results consist with the previous theoretical calculations for the binding energies of the nitrogen bonded to Ag or Au atoms.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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• pp.84-87
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• 2004

Nominal flexural strength of RC members strengthened with FRP sheets is generally based on the tensile strength of composite materials obtained from coupon tests. This method is based on the assumption that bond failure does not occur until the FRP sheet reaches its rupture strength. According to the previous researches, however, bond failure often occurs before the FRP sheet reaches its rupture strength. Some attempts were made to control debonding failure by increasing the bonded length of sheet or wrapping the section around their side of the member(U-wrap). In this study, the flexural failure mechanism of RC beams strengthened with AFRP sheets with different bond lengths is investigated. Their strengthening details to prevent the premature debonding failure are also suggested and its effectiveness is verified.

• Journal of the Korean Wood Science and Technology
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• 제23권2호
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• pp.70-76
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• 1995

본 연구는 왁스첨가순서(添加順序), 첨가량(添加量), 왁스종류(種類)가 Isocyanate 접착(接着) PB의 성질(性質)과 내수성(耐水性)에 미치는 영향(影響)을 구명(究明)하기 위해서 실시(實施)되었다. 왁스첨가순서(添加順序)는 PB의 기계적(機械的) 성질(性質) 및 내수성(耐水性)에 유의적(有意的)인 영향(影響)을 미치지는 않았다. 왁스에멀젼 첨가량(添加量)을 증가(增加)시킴으로써 접착력(接着力) 및 휨강도(强度) 내수(耐水) MOR은 감소(減少)되었지만 상태(常態) MOR 및 MOE는 감소(減少)되지 않았다. 상태접착력(常態接着力), 상태(常態) 및 내수(耐水) MOR과 MOE는 솔리드왁스량(量)을 증가(增加)시킴으로써 감소(減少)되지 않았지만 내수접착력(耐水接着力)은 감소(減少)되었다. 1% 및 1.5% 왁스량(量)을 첨가(添加)한 보드는 0.5% 왁스를 첨가(添加)한 보드와 비교(比較)해 보았을 때 내수성(耐水性)이 증가(增加)되지는 않았다. 솔리드왁스를 첨가(添加)한 보드의 접착력(接着力)은 왁스에멀젼을 첨가(添加)한 보드보다 더 좋은 결과(結果)를 나타내었다. 휨강도(强度)의 MOR 및 MOE, 내수성(耐水性)은 솔리드왁스와 왁스에멀젼간에 유의적(有意的)인 차이(差異)를 보이지는 않았다.

• Journal of the Korean Wood Science and Technology
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• 제25권3호
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• pp.96-104
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• 1997

The objective of this research project was to develop the wooden footpath block to reuse of wood waste. Some physical and mechanical properties of the wooden block such as water absorption, thickness swelling, modulus of rupture, internal bond, density profile and impact resistance were studied. Water absorption and thickness swelling of the wooden block were greatly reduced when the wooden block was pressed inside the forming device than by conventional hot pressing. Also, Modulus of rupture and internal bond of the wooden block were increased greatly when the pressing was completed inside the forming device. The density profile of the wooden block was improved up to 93.5%, minimum to average density ratio. The wooden block manufactured in this study have excellent physical and mechanical prperties in comparison with existing wood based materials. So, these wooden blocks are applicable to footpth block or other exterior members.

• Architectural research
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• 제11권1호
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• pp.25-33
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• 2009

This study presents the testing of 15 hwangtoh-based cementless concrete mixes to explore the significance and limitations of the development of eco-friendly concrete without carbon dioxide emissions while maintaining various beneficial effects. Hwangtoh, which is a kind of kaolin, was incorporated with inorganic materials, such as calcium hydroxide, to produce a cement-less binder. The main variables investigated were the water-to-binder ratio and fine aggregate-to-total aggregate ratio to ascertain the reliable mixing design of hwangtoh-based cementless concrete. The variation of slump with elapsed time was recorded in fresh concrete specimens. Mechanical properties of hardened concrete were also measured: including compressive strength gain, splitting tensile strength, moduli of rupture and elasticity, stress-strain relationship, and bond resistance. In addition, mechanical properties of hwangtoh-based cement-less concrete were compared with those of ordinary portland cement (OPC) concrete and predictions obtained from the design equations specified in ACI 318-05 and CEB-FIP for OPC concrete, wherever possible. Test results show that the mechanical properties of hwangtoh-based concrete were significantly influenced by the water-to-binder ratio and to less extend by fine aggregate-to-total aggregate ratio. The moduli of rupture and elasticity of hwangtoh-based concrete were generally lower than those of OPC concrete. In addition, the stress-strain and bond stress-slip relationships measured from hwangtoh-based concrete showed little agreement with the design model specified in CEB-FIP. However, the measured moduli of rupture and elasticity, and bond strength were higher than those given in ACI 318-05 and CEB-FIP. Overall, the test results suggest that the hwangtoh-based concrete shows highly effective performance and great potential as an environmental-friendly building material.

• Bulletin of the Korean Chemical Society
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• 제11권5호
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• pp.399-402
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• 1990

Activation parameters of the exchange between two types of glycinate groups in (nitrilotriacetato)dioxovanadate(V) ion, $[VO_2(NTA)]^{2-}$, have been determined as the results of $^{13}C$ NMR measurements over a range of temperatures between 277 and 306$^{\circ}K$. The exchange mechanism is proposed on the basis of the chelate ring opening-closing process, assuming rupture of the metal-oxygen (glycinate) bond trans to V = O bond to give a five-coordinated intermediate.

• Journal of the Korean Wood Science and Technology
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• 제18권4호
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• pp.86-101
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• 1990

The primary objective of this research was to investigate the strength properties of Comply, a composite panel. fabricated with particle board as core material and veneer or plywood as face and back. 20types of comply composites were manufactured according to the four specific gravity levels(0.5, 0.6, 0.7 or 0.8) of particleboard core and three veneer or two plywood thicknesses for face and back. They were tested and compared with matching particleboard (control) on moisture content. specific gravity, bending properties(MOE, MOR SPL). nail resistance and internal bond strength. The obtained results were summarized as follows: The increasing effect of modulus of elasticity was shown by the increase of face and back veneer or plywood thickness. The modulus of rupture and stress at proportional limit of the comply composites bonded with 3mm thick veneers or 3mm thick plywood face and back were higher than 2mm thick veneer or 2mm thick plywood as face and back. Both of modulus of rupture and stress at proportional limit on bending of Comply were higher than those of control board. Also the modulus of elasticity of Comply showed much higher than that of control board. The nail resistance of Comply, composed of plywood as face and back was higher than that of veneer. The nail resistance of control board was higher than that of Comply at Sp.Gr 0.7 and 0.8 core boards. Internal bond of Comply, composed of 1mm and 2mm thick veneer as face and back was higher than that of 3mm thick veneer. The increasing effect of modulus of elasticity was shown by the increase of shelling ratio in Comply composed of veneer and plywood as face and back. The modulus of rupture was increased by the increment of shellmg ratio in Compiy, composed of plywood as face and back. The modulus of elasticity and modulus of. rupture of comply were higher than those of particleboard(control) in effect of shelling ratio. Therefore it was concluded that the mechanical property values of Comply were clearly greater than those of particleboard(control).

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 봄 학술발표회 논문집(I)
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• pp.153-159
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• 1999

The objective of this study was to investigate the bond strength properties of antiwashout underwater concrete. The fine aggregate(river sand, blended sand (river sand : sea sand = 1 : 1), condition of cast and cure(sea water, fresh water), and compressive strength of proportion(210kgf/$\textrm{cm}^2$ ~ 330kgf/$\textrm{cm}^2$) were chosen as the experimental parameters. The experimental results show that the underwater segregation resistance was increased, but flowability (slump flow) and air contents were decreased as the compressive strength of proportion increased. Bond strength of antiwashout underwater concrete was similar to plain concrete. From this study, rational analytic formula for the modulus of rupture and bond stress are to be from compressive strength of concrete.