• Title/Summary/Keyword: Bond order

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A study on the Problems and Improvement of Export Credit Guarantee System in the Trade Insurance (무역보험의 수출신용보증제도의 문제점과 개선방안)

  • La, Kong-Woo
    • International Commerce and Information Review
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    • v.15 no.1
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    • pp.259-283
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    • 2013
  • In this study has been suggested on the basis of the Court of Audit's report on trade insurance issues presented and the Export Credit Guarantee Insurance Improvement. First, the improvement insurance underwriting standards and come up with measures to improve the soundness of the insurance fund trading. In order to do this, (1) warranty for a lower credit companies strengthen underwriting standards, (2) raise short-term solvency and the accuracy of financial statements Review criteria Borrowings calculated based, (3) trustee companies Warranty Terms for improvement, (4) for closure of businesses quickly take measures of bond conservation measures. Second, through improved risk management measures to strengthen risk management for export credit guarantees are to be provided.

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Hydrogen Bonding Analysis of Hydroxyl Groups in Glucose Aqueous Solutions by a Molecular Dynamics Simulation Study

  • Chen, Cong;Li, Wei Zhong;Song, Yong Chen;Weng, Lin Dong;Zhang, Ning
    • Bulletin of the Korean Chemical Society
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    • v.33 no.7
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    • pp.2238-2246
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    • 2012
  • Molecular dynamics simulations have been performed to investigate hydrogen bonding characteristics of hydroxyl groups in glucose aqueous solutions with different concentrations. The hydrogen bonding abilities and strength of different O and H atom types have been calculated and compared. The acceptor/donor efficiencies have been predicted and it has been found that: (1) O2-HO2 and O3-HO3 are more efficient intramolecular hydrogen bonding acceptors than donors; (2) O1-HO1, O4-HO4 and O6-HO6 are more efficient intramolecular hydrogen bonding donors than acceptors; (5) O1-HO1 and O6-HO6 are more efficient intermolecular hydrogen bonding acceptors than donors while hydroxyl groups O2-HO2 and O4-HO4 are more efficient intermolecular hydrogen bonding donors than acceptors. The hydrogen bonding abilities of hydroxyl groups revealed that: (1) the hydrogen bonding ability of OH2-$H_w$ is larger than that of hydroxyl groups in glucose; (2) among the hydroxyl groups in glucose, the hydrogen bonding ability of O6-HO6 is the largest and the hydrogen bonding ability of O4-HO4 is the smallest; (3) the intermolecular hydrogen bonding ability of O6-HO6 is the largest; (4) the order for intramolecular hydrogen bonding abilities (from large to small) is O2-HO2, O1-HO1, O3-HO3, O6-HO6 and O4-HO4.

Novel Activation by Electrochemical Potentiostatic Method

  • Lee, Hak-Hyeong;Lee, Jun-Gi;Jeong, Dong-Ryeol;Gwon, Gwang-U;Kim, Ik-Hyeon
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.29.1-29.1
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    • 2009
  • Fabrication of good quality P-type GaN remained as a challenge for many years which hindered the III-V nitrides from yielding visible light emitting devices. Firstly Amano et al succeeded in obtaining P-type GaN films using Mg doping and post Low Energy Electron Beam Irradiation (LEEBI) treatment. However only few region of the P-GaN was activated by LEEBI treatment. Later Nakamura et al succeeded in producing good quality P-GaN by thermal annealing method in which the as deposited P-GaN samples were annealed in N2 ambient at temperatures above $600^{\circ}C$. The carrier concentration of N type and P-type GaN differs by one order which have a major effect in AlGaN based deep UV-LED fabrication. So increasing the P-type GaN concentration becomes necessary. In this study we have proposed a novel method of activating P-type GaN by electrochemical potentiostatic method. Hydrogen bond in the Mg-H complexes of the P-type GaN is removed by electrochemical reaction using KOH solution as an electrolyte solution. Full structure LED sample grown by MOCVD serves as anode and platinum electrode serves as cathode. Experiments are performed by varying KOH concentration, process time and applied voltage. Secondary Ion Mass Spectroscopy (SIMS) analysis is performed to determine the hydrogen concentration in the P-GaN sample activated by annealing and electrochemical method. Results suggest that the hydrogen concentration is lesser in P-GaN sample activated by electrochemical method than conventional annealing method. The output power of the LED is also enhanced for full structure samples with electrochemical activated P-GaN. Thus we propose an efficient method for P-GaN activation by electrochemical reaction. 30% improvement in light output is obtained by electrochemical activation method.

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A Very Compact 60 GHz LTCC Power Amplifier Module (초소형 60 GHz LTCC 전력 증폭기 모듈)

  • Lee, Young-Chul
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.17 no.11 s.114
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    • pp.1105-1111
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    • 2006
  • In this paper, using low-temperature co-fired ceramic(LTCC) based system-in-package(SiP) technology, a very compact power amplifier LTCC module was designed, fabricated, and then characterized for 60 GHz wireless transmitter applications. In order to reduce the interconnection loss between a LTCC board and power amplifier monolithic microwave integrated circuits(MMIC), bond-wire transitions were optimized and high-isolated module structure was proposed to integrate the power amplifier MMIC into LTCC board. In the case of wire-bonding transition, a matching circuit was designed on the LTCC substrate and interconnection space between wires was optimized in terms of their angle. In addition, the wire-bonding structure of coplanar waveguide type was used to reduce radiation of EM-fields due to interconnection discontinuity. For high-isolated module structure, DC bias lines were fully embedded into the LTCC substrate and shielded with vias. Using 5-layer LTCC dielectrics, the power amplifier LTCC module was fabricated and its size is $4.6{\times}4.9{\times}0.5mm^3$. The fabricated module shows the gain of 10 dB and the output power of 11 dBm at P1dB compression point from 60 to 65 GHz.

Fabrication and Characterization of 7.5 wt% Y2O3-ZrO2 Thermal Barrier Coatings Deposited by Suspension Plasma Spray (서스펜션 플라즈마 용사법을 이용한 7.5 wt% Y2O3-ZrO2 열차폐코팅 제조 및 평가)

  • Lee, Won-Jun;Oh, Yoon-Suk;Lee, Sung-Min;Kim, Hyung-Tae;Lim, Dae-Soon;Kim, Seongwon
    • Journal of the Korean Ceramic Society
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    • v.51 no.6
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    • pp.598-604
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    • 2014
  • Considerable research efforts have been explored attempting to enhance the thermal durability of thermal barrier coatings (TBCs) at the high operating temperatures of gas turbines. In this study, the suspension plasma spray (SPS) process was applied to produce TBCs with a segmented structure by using an yttria-stabilized zirconia (YSZ) suspension. Four different experiment sets were carried out by controlling the ratio between surface roughness of the bond coat and feed stock size ($R_a/D_{50}$) in order to examine the effect of $R_a/D_{50}$ ratio on the microstructure of SPS-prepared coatings. When the $R_a/D_{50}$ had a high value of 11.8, a deposited thick coating turned out to have a cone-type columnar microstructure. In contrast, at the low $R_a/D_{50}$ values of 2.9 and 0.18, a deposited thick coating appeared to have a dense, vertically-cracked microstructure. However, with the very low $R_a/D_{50}$ value of 0.05 the coating was delaminated.

An Experimental Study of Perfobond FRP-Concrete Composite Beam (퍼포본드 FRP-콘크리트 합성보의 실험적 연구)

  • Yoo, Seung-Woon;Kook, Moo-Sung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.2
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    • pp.121-127
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    • 2010
  • An experimental study of composite beam with perforated fiber reinforced polymer(FRP) plank as a permanent formwork and the tensile reinforcement was performed. A combined formwork and reinforcement system can facilitate rapid construction of concrete members since no conventional formwork is needed, which requires time consuming assembly and dismantling. In order for a smooth FRP plank to act compositely with the concrete, the surface of the FRP needs to be treated to increase its bond properties. Aggregates were bonded to the FRP plank using a commercially available epoxy and perforated web of plank. No additional flexural or shear reinforcement was provided in the beams. For comparison, two control specimens were tested. One control had no perforated hole in the web of FRP plank and the other had internal steel reinforcing bars instead of the FRP plank. The beams were loaded by central patch load to their ultimate capacity. This study demonstrates that the perforated FRP plank has the potential to serve as a permanent formwork and reinforcing for concrete beam.

Analysis for Nonlinear Behavior of Concrete Panel Considering Steel Bar Buckling (철근 좌굴을 고려한 콘크리트 패널의 비선형 거동에 대한 해석)

  • Lee, Sang-Sup;Park, Keum-Sung;Bae, Kyu-Woong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.6
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    • pp.130-137
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    • 2018
  • Many constitutive models for concrete have been developed to predict the nonlinear behavior of concrete members considerably. The constitutive model for reinforcing bar that include the tension stiffening effect due to the bond characteristics between steel bars and concrete is being studied but the bilinear model is generally used. It was found that the buckling of the longitudinal reinforcing bars is controlled the nonlinear behavior of hybrid precast concrete panel, which is being developed for core wall. In this study, the constitutive models that can consider the embedding and buckling effects of reinforcing bar are investigated and a new model combing these constitutive models is proposed. In order to verify the proposed model, the analysis results are compared with experimental results of the concrete wall and hybrid precast concrete panel. The analysis of embedding-effect-only modeling predicted that the deformation increases continually without the decrease in the load carrying capacity. However, the analysis results of proposed model showed good agreement with some experimental results, thus verifying the proposed computational model.

Enhancements in Performance and Manufacturing Efficiencies of GFRP Rebar (GFRP 보강근의 성능 및 제작 효율화 방안)

  • You, Young Jun;Kim, Jang Ho;Park, Young Hwan;Park, Ji Sun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.1
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    • pp.110-119
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    • 2012
  • Fiber reinforced polymer (FRP) reinforcing rebar with non-corrosive property is suggested as an alternative replacement to steel reinforcing rebar due to its enhanced durability and non-corrosive characteristics. Currently, a limited number of glass fiber reinforced polymer rebar (GFRP) are sold commercially due to their high cost, relatively low performances, and brittle failure characteristics. Therefore, the performance enhancements and cost reduction of GFRP rebar are needed to increase its applications in construction fields. The intent of this study is to develop high performance GFRP rebar by improving its tensile and shear properties. Also, in order to reduce manufacturing costs, factors such as material composition and manufacturing process were evaluated to improve manufacturing efficiency. Finally a GFRP rebar with enhanced material properties and less expensive than the GFRP rebar currently sold in the market was manufactured and evaluated for its application possibility in construction fields.

Analysis of the Load Carrying Behavior of Shear Connection at the Interface of Encased Composite Beams (매입형 합성보의 전단합성거동에 대한 비교분석)

  • Shin, Hyun Seop;Heo, Byung Wook;Bae, Kyu Woong;Kim, Keung Hwan
    • Journal of Korean Society of Steel Construction
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    • v.20 no.1
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    • pp.67-79
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    • 2008
  • In this study, a bending test with three encased composite beams were carried out and analyzed using FEM in order to find how chemical adhesion, interface interlock, friction and composite action by shear studs contribute to stiffness, strength and composite action in the interface of encased compo site beams. The test and results of the FEM analysis showed that the difference in the ultimate moment capacity of the composite beams with and without studs is under 10%. The reason is that the effect of chemical adhesion, interface interlock, and friction in the interface on the composite action is so high that the encased beams have a moment capacity above some defined magnitude. Also, the increment of moment capacity up to plastic moment is not large and the increase of linearly proportioned.

Analysis of mixing ratio of lacquer and glue for lacquer drying in low relative humidity environment (상온저습 환경에서의 옻의 건조를 위한 옻과 교의 배합 분석 연구)

  • Kim, Eun-Kyung;Jeong, Se-Ri;Yu, Jae-Eun
    • 보존과학연구
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    • s.32
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    • pp.37-52
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    • 2011
  • This study investigates the hardening characteristics of the mixture lacquer and glue at room temperature. Diverse samples were made from manufacturing of glue to the adding ratio in sap of the lacquer tree. After the examination of moisture content of samples, it has been seen that there is no relation with glue's kinds or adding ratio, but only with contain level of moisture. The samples made with film shape in order to examine the drying time. Samples with isinglass needed for over three days and had smooth surface. However, samples mixed with animal glue dried within a day and had ripples on the surface because of fast drying rate. In addition, the samples with isinglass had slow change of colour in early step of drying and no colour difference after completely drying although it had significant changes to black oxide as soon as contact with air. In structural analysis with FT-IR showed that the carbonyl bond increased in the samples of mixed with glue, compared to raw lacquer and treated lacquer.

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