• Proceedings of the Korea Concrete Institute Conference
• /
• 2004.05a
• /
• pp.536-539
• /
• 2004

This paper focues on the flexural behavior of RC beams externally reinforced using Carbon Fiber Reinforced Plastics plates. (CFRP) A non-linear finite element (FE) analysis is proposed in order to complete the experimental analysis of the flexural behaviour of the beams. This paper is a part of a complete program aiming to set up design formulate to predict the strength of CFRP strengthende beams, particularly when premature failure through plates-end shear or concrete cover delamination occurs. An elasto-plastic behaviour is assumed for reinforced concrete and interface elements are used to model the bond and slip.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2005.10a
• /
• pp.681-688
• /
• 2005

The Green Wall is the highest eco-system among a segmental retaining wall systems. Recently, the demand of high segmental retaining wall (SRW) is increased in domestic. The soil nailing system is applied in order to maintain the high SRW stability for steeper slope. However, the proper design approach that can consider the earth pressure reduction effects in soil nailing system has not been proposed. Hence, the purpose of this study was to provide the design and analysis technique of the segmental retaining wall reinforced by soil nailing. Also, in this study, various parametric studies using numerical method as shear strength reduction (SSR) technique were carried out. In the parametric study, the length ratio and the bond ratio of the soil nailing were changed to identify the earth pressure reduction effect of the retaining wall reinforced by soil nailing.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 1995.11a
• /
• pp.105-108
• /
• 1995

The inter-metal dielectric SiOF films were fabricated using remote plasma-enhanced chemical vapour deposition with addition of SF$\sub$6/ gas. SiOF bond formation in these films was recognized by a chemical bonding structural study using FT-IR. The deposition rate and the dielectric constant of a deposited films were decreased with increasing SF$\sub$6/ gas. It was observed that leakage current of SiOF film was reduced the one order compared to a film without addtion of SF$\sub$6/ gas.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2005.11a
• /
• pp.73-76
• /
• 2005

This paper discussed finite element method(FEM) models of the reinforced concrete frame retrofitted with cast-in plate infilled shear wall and analysed under constant axial and monotonic lateral load using ABAQUS. Detailed finite element models are created by studying the monotonic load response of the designed connection of reinforced concrete frame and cast-in plate infilled shear wall. The developed models account for the effect of material inelasticity, concrete cracking, geometric nonlinearity and bond-slip of steel, frame and infilled shear wall. In order to verify the proposed FEM, this study behaved analysis considered a diagonal reinforced steel. The analytical results compared with the experimental results.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1995.10a
• /
• pp.293-298
• /
• 1995

This study experimentally evaluate the bonding performance of repair and strengthening materials. It is very important problem to justify bonding properties between repair and strengthening materials and old concrete. Many previous research and investigation showed that bonding strength of reinforcing materials determines the strengthening effect and the durability of repair work. Therefore, menifestation of bonding properties and the improvement of bonding performance of repair and strengthening materials are very important. In order to improve the perforamnce of repair work, it needs to investigate the behavior of bonding materials, such as stress distribution along the bonding area and the long term performance of the material. The target repair methods are steel plate addition technique and repair mortar method, and the test parameters studied in this paper include epoxy thickness, bonding surface texture, and bonding area.

• BMB Reports
• /
• v.30 no.4
• /
• pp.253-257
• /
• 1997

Negative ion fast atom bombardment (FAB) mass spectra were found to allow the determination of the linkage positions in a series of underivatized linkage-isomeric oligosaccharides. A previous work (Laine et al., 1988) reported that ion patterns of linkage-isomeric trisaccharides could be distinguished by a positive ion. Negative ion FAB collison-activated dissociation (CAD) mass spectrometry (MS) spectra of trisaccharides exhibited better sensitivity than the positive ion mode and provided specific fragmentation patterns according to the linkage positions. Especially, the fragmentations, m/z 205 in F6 and m/z 221 in G6, not occuring in 1-3 or 1-4 linkage. were an indication of 1-6 linkage, by changing collision energies from + 10 eV to +60 eV. The survival ratios of molecular ions in each collision energy set gave support to previous results in which the order of bond stability was 1-6>1-4>1-3 linkage.

• Bulletin of the Korean Chemical Society
• /
• v.23 no.9
• /
• pp.1267-1271
• /
• 2002

The conformation dependences of basis set superposition errors (BSSE) for 1,2-difluoroethane (DFE) and 1,2-dimethoxyethane (DME) molecules have been estimated using counterpoise method at the Moller-Plesset second order perturbation (MP2) level of theory with various basis sets, assuming that all BSSE dependences on conformations are due to the change in CC bond. The BSSE on the energy differences between eclipsed and gauche forms of DFE are in the range of 0.2-1.2 kcal/mol and those between local minima, gauche and anti forms, are less than 0.2 kcal/mol. For the larger DME molecule, the BSSE differences between local minima are still less than 0.4 kcal/mol, but may not be ignored compared to the energy differences of 0.2-3.0 kcal/mol between conformers.

• Journal of the Korean Chemical Society
• /
• v.57 no.4
• /
• pp.461-471
• /
• 2013

Optimized geometrical structure, atomic charges, molecular electrostatic potential, nonlinear optical (NLO) effects and thermodynamic properties of the title compound N-(2,5-methylphenyl)salicylaldimine (I) have been investigated by using ab initio quantum chemical computational studies. Calculated results showed that the enol form of (I) is more stable than keto form. The solvent effect was investigated for obtained molecular energies, hardneses and the atomic charge distributions of (I). Natural bond orbital and frontier molecular orbital analysis of the title compound were also performed. The total molecular dipole moment (${\mu}$), linear polarizability (${\alpha}$), and first-order hyperpolarizability (${\beta}$) were calculated by B3LYP method with 6-31G(d), 6-31+G(d,p), 6-31++G(d,p), 6-311+G(d) and 6-311++G(d,p) basis sets to investigate the NLO properties of the compound (I). The standard thermodynamic functions were obtained for the title compound with the temperature ranging from 200 to 450 K.

• Journal of Photoscience
• /
• v.6 no.4
• /
• pp.171-176
• /
• 1999

The spectral and photophysical properties of trans-1-pyrazinyl-2-(3-quinolinyl)ethylene (trans-3- PyQE) are investigated under various conditions in order to obtain information on ground and excited states. The absorption spectrum of trans-3-PyQE changes slightly with varying degree of solvent polarity ; the. fluorescence spectrum is shifted to the red and becomes broad and structureless as the solvent polarity increases. The fluorescence quantum yield increases with increasing solvent polarity. The fluorescence intensity of trans-3-PyQE decreases as the concentration of methyl iodide increases. The fluorescence spectra of trans-3-PyQE changes markedly upon the variation of the excitation wavelength, presumably due to an equilibrium between conformers originating from the rotation of a quasi-single bond between the quinolinyl group and ethylenic carbon atom. These results indicate that the spectral and photophysical properties of trans-3-PyQE are strongly influenced by solvent, heavy atom, and an equilibrium between conformers

• Proceedings of the Korean Society of Machine Tool Engineers Conference
• /
• 2004.10a
• /
• pp.54-59
• /
• 2004

A measure for good products manufactured by grinding process is the surface roughness that is affected by a lot of operating parameters such as types of abrasive, grain size, bond material, wheel speed, table speed, depth of cut, hardness of workpiece and stiffness of grinding machine. In this study, an application of the design of experiments was tried for evaluating the effect of operating parameters on the surface roughness. The workpiece was a high speed tool steel(SKH51) and the surface grinding was conducted. In order to obtain the best surface roughness within constraints of the working range, the optimal grinding conditions were selected. The usefulness of this method was evaluated by the statistical strategy.