• Title/Summary/Keyword: Bond order

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The effect of CFRP-concrete bond mechanism on dynamic parameters of repaired concrete girders

  • Fayyadh, Moatasem M.;Razak, Hashim A.
    • Structural Engineering and Mechanics
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    • v.82 no.3
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    • pp.343-354
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    • 2022
  • An understanding of the mechanism of concrete girders repaired with CFRP plates and its influence on the dynamic parameters is presented in this paper. Dynamic parameters are governed by the relationship with the physical properties of concrete girders and CFRP plates as well as the adhesive layer between them. A brief explanation of the mechanism of the composite action of concrete girders repaired with CFRP is also given in this paper. Experimental work was carried out to validate the theory of the composite action. The results show a decrease in the modal parameters of CFRP repaired girders that were turned over during the repair procedure, which contrasts with the proven static-based results that CFRP plates increase the stiffness of repaired girders. The composite action theory has explained the results based on the tension and compression forces' growth at the adhesive layer between the CFRP plates and girder surface during the repair procedure. Other girders were prepared and repaired without turning over in order to avoid tension and compression forces at the adhesive layer. The experimental results show an increase in the dynamic parameters of CFRP repaired girders that were not turned over during the repair procedure, which aligns with the static-based results. The study concludes that the dynamic parameters are excellent indicators for the assessment of CFRP repaired concrete girders. The study also suggests that researchers should not turn over damaged concrete girders to repair them with CFRP plates if they intend to study the dynamic parameters, in order to avoid the proposed composite action effect on modal parameters.

Preparation and characterization of new perovskite compounds $(Na_{0.5}Sr_{0.5})(M_{0.5}N_{0.5})O_3$(MTi,Zr N=Ta,Nb)

  • Chung, Hoon-Taek;Tetsuro Nakamura;Mitsuru Itoh
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.06a
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    • pp.49-51
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    • 1997
  • New complex perovskite compounds (Na0.5Sr0.5)(Ti0.5Nb0.5)O3, (Na0.5Sr0.5)(Zr0.5Ti0.5)O3 and (Na0.5Sr0.5)(Ti0.5Ta0.5)O3 have been prepared. The crystal structures of these compounds were determined by powder X-ray Rietveld analysis. The crystal structure of (Na0.5Sr0.5)(Ti0.5Nb0.5)O3 and (Na0.5Sr0.5)(Zr0.5Ta0.5)O3 was Pmmn, and that of (Na0.5Sr0.5)(Ti0.5Nb0.5)O3 was I4/mmm. All these compounds showed the superstructure due to the oxygen octahedron distortion. The selected bond distances and bond angles were calculated by the OFFER. The octahedron distortion for each sample, which was measured from the bond distances and bond angles, showed the following order: (Na0.5Sr0.5)(Z0.5Ta0.5)O3> (Na0.5Sr0.5)(Ti0.5Nb0.5)O3 > (Na0.5Sr0.5)(Ti0.5Ta0.5)O3. Dielectric properties were measured for the samples. In this study, the crystal structure and dielectric properties of the new complex perovskite structures and discussed.

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Density Functional Theory (DFT) Study of Gas-phase O.C Bond Dissociation Energy of Models for o-TEMPO-Bz-C(O)-Peptide: A Model Study for Free Radical Initiated Peptide Sequencing

  • Kwon, Gyemin;Kwon, Hyuksu;Lee, Jihye;Han, Sang Yun;Moon, Bongjin;Oh, Han Bin;Sung, Bong June
    • Bulletin of the Korean Chemical Society
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    • v.35 no.3
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    • pp.770-774
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    • 2014
  • The bond dissociation energy (BDE) of the chemical bond between the carbon and oxygen atoms of a simple TEMPO-derivative is calculated by employing the density functional theory, the $2^{nd}$ order M${\phi}$ller-Plesset (MP2) perturbation theory, and complete basis set (CBS) methods. We find that BDE of the positive ion of the TEMPO-derivative is larger at least by 7 kcal/mol than that of the negative ion, which implies that the dissociation reaction rate of the positive ion should be slower than that of the negative ion. Such theoretical predictions are contrary to the results of our previous experiments (Anal. Chem. 2013, 85, 7044), in which the larger energy was required for negative o-TEMPO-Bz-C(O)-peptides to undergo the dissociation reactions than for the positive ones. By comparing our theoretical results to those of the experiments, we conclude that the dissociation reaction of o-TEMPO-Bz-C(O)-peptide should occur in a complicated fashion with a charge, either positive or negative, probably being located on the amino acid residues of the peptide.

A comparison of retentive strength of implant cement depending on various methods of removing provisional cement from implant abutment

  • Keum, Eun-Cheol;Shin, Soo-Yeon
    • The Journal of Advanced Prosthodontics
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    • v.5 no.3
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    • pp.234-240
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    • 2013
  • PURPOSE. This study evaluated the effectiveness of various methods for removing provisional cement from implant abutments, and what effect these methods have on the retention of prosthesis during the definitive cementation. MATERIALS AND METHODS. Forty implant fixture analogues and abutments were embedded in resin blocks. Forty cast crowns were fabricated and divided into 4 groups each containing 10 implants. Group A was cemented directly with the definitive cement (Cem-Implant). The remainder were cemented with provisional cement (Temp-Bond NE), and classified according to the method for cleaning the abutments. Group B used a plastic curette and wet gauze, Group C used a rubber cup and pumice, and Group D used an airborne particle abrasion technique. The abutments were observed using a stereomicroscope after removing the provisional cement. The tensile bond strength was measured after the definitive cementation. Statistical analysis was performed using one-way analysis of variance test (${\alpha}$=.05). RESULTS. Group B clearly showed provisional cement remaining, whereas the other groups showed almost no cement. Groups A and B showed a relatively smooth surface. More roughness was observed in Group C, and apparent roughness was noted in Group D. The tensile bond strength tests revealed Group D to have significantly the highest tensile bond strength followed in order by Groups C, A and B. CONCLUSION. A plastic curette and wet gauze alone cannot effectively remove the residual provisional cement on the abutment. The definitive retention increased when the abutments were treated with rubber cup/pumice or airborne particle abraded to remove the provisional cement.

Bond Capacity of Pseudo-Ductile FRP Hybrid Sheet to Strengthen RC Members (철근콘크리트 부재 보강용 유사연성 FRP 하이브리드 시트의 부착 특성)

  • Yoon, Hye-Sun;Lee, Jung-Mi;Lee, Chin-Yong;Choi, Dong-Uk;Kim, Kil-Hee
    • Journal of the Korea Concrete Institute
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    • v.21 no.1
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    • pp.47-53
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    • 2009
  • 12 concrete blocks, on which hybrid fibrous sheets (carbon fiber and glass fiber) had been bonded, were subjected to tensile load in order to estimate properties of the bonded interface. the sheet length was varied by 100mm, 200mm and 400mm. It was found that more than 150mm bond length is required to achieve the maximum bearing capacity of the interface. In this study, maximum bond stress $\tau_{F,max}$, ultimate slip $S_{FU}$ of the interface were estimated $\tau_{F,max}$=3.0MPa and $S_{FU}$= 0.175mm, respectively.

Bond Characteristics of Ultra High Performance Concrete (초고성능 콘크리트(UHPC)의 부착특성에 관한 연구)

  • Kook, Kyung-Hun;Shin, Hyun-Oh;Kwahk, Im-Jong;Yoon, Young-Soo
    • Journal of the Korea Concrete Institute
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    • v.22 no.6
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    • pp.753-760
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    • 2010
  • Ultra high performance concrete (UHPC), is characterized by its high compressive strength and advanced tensile behavior that is much superior to those of conventional concrete. In order to apply this new material in practice, the bond characteristics of UHPC were evaluated in this study. Pull-out tests between UHPC and deformed steel rebar were carried out according to the modified RILEM test method, and were verified by finite element analysis. From the test results showed that UHPC presents 5 to 10 times higher bond strength compared to normal strength concrete, this study suggested remarkably reduced development length and concrete cover comparing to existing specifications. The test results of 700 MPa high strength steel rebar demonstrated the applicability of high strength steel to UHPC. In addition, the transfer length measurements of seven-wire strand in UHPC specimens indicated that the transfer length limit set by the current design code is very conservative for UHPC.

Evaluation of Domestic Tack-Coating Material's Properties for Asphalt Concrete Pavement (국내 아스팔트 콘크리트 포장용 택코팅제의 기초물성 평가)

  • Lee, Jaejun;Kim, Seung-Hoon;Lim, Jaekyu;Han, Jongmin;Lee, Kwang-Joon
    • International Journal of Highway Engineering
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    • v.16 no.6
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    • pp.121-128
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    • 2014
  • PURPOSES : The objective of this study is to evaluate the tack-coating material's properties using the bitumen bond strength(BBS) test and damping test as function of changed curing times. In this study, bonding strength tests were performed according to the curing time of tack coating materials. METHODS : In order to investigate bonding characteristic of tack coating materials, the Pneumatic Adhesion tensile Testing Instrument(PATTI) device is used to measure the bond strength between the tack coating materials and aggregate substrate based on the AASHTO TP-91. Also, damping test as in situ test was used to determine an appropriate traffic openting time for construction vehicle. Four different tack-coating materials were used in this study. The BBS tests were performed a one hour curing and testing temperatures of $5^{\circ}C$, $15^{\circ}C$, and $25^{\circ}C$. Damping test was conducted at 30min, 60min, 90min, and 120 min of curing times with temperatures of $20^{\circ}C$ and $30^{\circ}C$. RESULTS and CONCLUSIONS : The BBS test results show various bond strength as function of tack coat materials. At the same testing condition, A tack coat material shows almost two times higher than D tack coat materials although both materials are satisfied the criteria of material's physical properties. Also, Dampting test results shows similar trend with BBS test result. The damping test result was significantly changed as function of tack coat materials. Based on this study, the tack coating material's curing time is very important. Therefore, both curing time and the bond strength's characteristic has to be considered in standard specification.

Study on the Development of Finishing Design Methods for Building Structures Using the Metal Films (금속피막에 의한 건축 마감 의장 기법 개발에 관한 연구)

  • Lim, Ji-Taek;Jung, Hwa-Rang
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.1
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    • pp.183-189
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    • 2018
  • In this study, the bond strength between concrete and metal films was investigate according to changing water content ratio of substrate concrete by pull-out test in order to develop the new finishing design methods for building structures using the metal films. The following conclusions were obtained as a result of the studies. It was find that the colour of metal did not change before and after the metal spraying. Also, the water content ratio of substrate concrete must be controlled under 10% weight to confirm the standard bond strength of finishing material to concrete. 2.5 MPa. To enhance the bond strength between concrete and metal films, it is very effective to strengthen the concrete surface using the agent which strengthen the concrete surface and seal the pore of metal film by the sealing agents. Therefore, the control of concrete surface treatment and water content ratio are necessary to secure the bond strength of metal films.

A STUDY ON THE REDUCTION OF GALVANIC CURRENT BETWEEN AMALGAM AND GOLD ALLOY WITH VARIOUS CHEMICAL AGENTS (수종 아말감과 금합금의 갈바닉 전류 측정에 관한 연구)

  • Kim, Seung-Soo;Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.18 no.2
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    • pp.469-481
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    • 1993
  • The purpose of this study was to achieve the reduction of the galvanic current between the dental amalgam alloy and gold alloy. In order to measure the galvanic current between these two metals a prep in the size of $4{\times}13mm$ which was filled with amalgam and another prep of $4{\times}2mm$ was filled with gold alloy was made in the acrylic resin. These two preps were then connected to a 2mm diameter copper wire. Using an ammeter to measure the galvanic current, six different kinds of amalgam and gold alloy were immersed in saline solution with approximately 10mm distance between the two alloys. Chemical agents that are thought to reduce the galvanic current such as hydrazine. silver nitrate, potassium chromate, and bonding agents such as Scotch bond 2(3M) and All bond 2(Bisco) were applied to the alloy surface. Cathodic inhibitor such as hydrazine was applied to gold alloy where as anodic inhibitor such as silver nitrate and potassium chromate were applied to amalgam. Both bonding agents, Scotch bond 2(3M) and All bond 2 (Bisco), were applied to amalgam. The following results were obtained when the currency on the coated alloy surface was compared to the uncoated surface. 1. The galvanic currency went down as the time elapsed and after 30 minutes no change was detected. 2. Initial currency was higher in low copper amalgam compared to high copper amalgam. Intitial currency was the highest in low copper lathe-cut amalgam. 3. Group of gold coated with hydrazine had the most reduction in galvanic currency. 4. Group of amalgam coated with silver nitrate or potassium chromate also showed significant reduction in galvanic currency. 5. The bonding agents also helped reduce galvanic currency. 6. Of all the agents used to reduce galvanic currency, silver nitrate showed the best result.

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Behaviors of Concrete Segmented Composites Using Polymer Mortar Under Static and Impact Loadings (폴리머 모르타르를 이용한 콘크리트 분절 복합체의 정하중 및 충격하중에서의 거동 평가)

  • Min, Kyung Hwan;Lee, Jin Young;Kim, Mi Hye;Yoon, Young Soo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.5
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    • pp.169-177
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    • 2011
  • In this study, an impact resistance of concrete segmented composites adopted shell's structures which have the excellent impact resistance was assessed. In order to enhance the performances of concrete segmented composite, the bond strength of mortar between the concrete blocks should be improved. Hence, in this study polymer mortars were applied to increase the bond strength of mortar. From the results of bond tests, the 15% latex mortar was selected and static and low-velocity impact tests were carried out for the specimens applied the plain and latex mortar. The concrete segmented composites, of which the bond strength of mortar was enhanced, showed improved low-velocity impact resistances. A Nonlinear finite element analysis using the discrete crack model showed similar energy dissipating capacities to the impact test's results. Consequently, by improving the analysis models for segmented composites, the impact resistances for manifold variables can be predicted and assessed.