• Title/Summary/Keyword: Bond mechanism

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Adsorption Mechanism of Alkyl Ketones on Cation Supported by Layer Silicate. Link Formation of Hydroxyl Group (Layer Silicate에 지지된 양이온상에서 일어나는 Alkyl Ketones의 흡착기구. 水酸基의 Link 形成理論)

  • Jong Taik Kim;Jong Rack Sohn
    • Journal of the Korean Chemical Society
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    • v.17 no.4
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    • pp.247-255
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    • 1973
  • The self supported film specimen of Wyoming montmorillonite as a layer silicate saturated by cations,$Li^{+},\;Na^{+},\;K^{+},\;Ca^{2+},\;Ni^{2+},\;Al^{3+}$and$F^{3+}$ were allowed to contact acetone, methyl-ethyl ketone and diethyl ketone within the heatable gas cell. The i.r. spectra between $4000{\sim}1200cm^{-1}$ at different pressures of adsorbates indicated bond formation through carbonyl oxygen. Two types of carbonyl bond shift with maxima at $1713cm^{-1}$ and $1690cm^{-1}$ are attributed as coordinate bond formation of carbonyl with either surface hydroxyl or cationic hydroxyl group. The intensity of the vOH was analyzed and resonance form of cationic hydroxyl was proposed as an adsorption site. The tendency to form coordinate bond was in good agreement with calculated formal charge of carbonyl oxygen in an increasing order, acetone < methyl-ethyl ketone < diethyl ketone. As an additional mechanism of adsorption, weak hydrogen bonding of methyl hydrogen with surface oxygen was observed.

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An Analytical Study on the Pullout Properties of Axial Bars Embedded in Massive Concrete (매시브 콘크리트에 배근된 축방향 주철근의 인발특성에 관한 해석적 연구)

  • 장일영;송재호;변근주
    • Proceedings of the Korea Concrete Institute Conference
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    • 1993.04a
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    • pp.194-200
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    • 1993
  • The objective of this study is to clarify analytically the pullout behavior of axial bars from a footing. The bond stress-slip model obtained from the results by the finite element method as well as the pullout tests in massive concrete was used in order to evaluate the slip of bars from the footing. Also, the process of bond mechanism was taken into consideration on order to express the deterioration of bond stress along bars, The shape and magnitude of bond stress distribution depends upon each loading steps. Using equilibrium equation of axial force, $\tau$-S relationship and $\sigma$s-$\varepsilon$s relationship, the differential equations of each loading steps are derived. Applying both boundary and equilibrium conditions to the equations, the amount of slip could be determined. Calculated values on the basis of proposed method evaluation of the slip of bars have a good agreement with the experimental results.

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Analytical study on the Bond Behavior of FRP Rebar in Concrete (FRP Rebar의 부착거동 해석)

  • You Young-Jun;Park Young-Hwan;Park Ji-Sun;You Young-Chan;Kim Hyeong-Yeol;Kim Keung-Hwan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.636-639
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    • 2004
  • Reinforced concrete structures have been used for a long time. However, corrosion problem in reinforcing steel is inevitable, which results in the degradation of performance and the shortening of the life of structures. To overcome such problems, FRP(Fiber Reinforced Polymer) rebars have been developed. Due to their corrosion resistance and their superior mechanical properties, FRP rebars are increasingly applied to concrete structures in other countries. To obtain the composite action between FRP rebars and concrete, sufficient bond between two materials must be secured. But, the behavior of FRP rebars is different from that of steel rebars. Therefore, it is necessary to understand and develop the proper bond mechanism of FRP rebars to use them in concrete structures. This paper presents analytical results to investigate the bond-slip relationship between FRP rebars and concrete based on pull out tests.

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Bond-slip constitutive model of concrete to cement-asphalt mortar interface for slab track structure

  • Su, Miao;Dai, Gonglian;Peng, Hui
    • Structural Engineering and Mechanics
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    • v.74 no.5
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    • pp.589-600
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    • 2020
  • The bonding interface of the concrete slab track and cement-asphalt mortar layer plays an important role in transferring load and restraining the track slab's deformation for slab track structures without concrete bollards in high-speed railway. However, the interfacial bond-slip behavior is seldom considered in the structural analysis; no credible constitutive model has been presented until now. Elaborating the field tests of concrete to cement-asphalt mortar interface subjected to longitudinal and transverse shear loads, this paper revealed its bond capacity and failure characteristics. Interfacial fractures all happen on the contact surface of the concrete track slab and mortar-layer in the experiments. Aiming at this failure mechanism, an interfacial mechanical model that employed the bilinear local bond-slip law was established. Then, the interfacial shear stresses of different loading stages and the load-displacement response were derived. By ensuring that the theoretical load-displacement curve is consistent with the experiment result, an interfacial bond-slip constitutive model including its the corresponding parameters was proposed in this paper. Additionally, a finite element model was used to validate this constitutive model further. The constitutive model presented in this paper can be used to describe the real interfacial bonding effect of slab track structures with similar materials under shear loads.

Bond behaviors of shape steel embedded in recycled aggregate concrete and recycled aggregate concrete filled in steel tubes

  • Chen, Zongping;Xu, Jinjun;Liang, Ying;Su, Yisheng
    • Steel and Composite Structures
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    • v.17 no.6
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    • pp.929-949
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    • 2014
  • Thirty one push-out tests were carried out in order to investigate the bond behavior between shape steel, steel tube (named steels) and recycled aggregate concrete (RAC), including 11 steel reinforced recycled aggregate concrete (SRRAC) columns, 10 recycled aggregate concrete-filled circular steel tube (RACFCST) columns and 10 recycled aggregate concrete-filled square steel tube (RACFSST) columns. Eleven recycled coarse aggregate (RCA) replacement ratios (i.e., 0%, 10%, 20%, 30%, 40%, 50%, 60%, 70%, 80%, 90% and 100%) were considered for SRRAC specimens, while five RCA replacement ratios (i.e., 0%, 25%, 50%, 75% and 100%), concrete type and length-diameter ratio for recycled aggregate concrete-filled steel tube (RACFST) specimens were designed in this paper. Based on the test results, the influences of all variable parameters on the bond strength between steels and RAC were investigated. It was found that the load-slip curves at the loading end appeared the initial slip earlier than the curves at the free end. In addition, eight practical bond strength models were applied to make checking computations for all the specimens. The theoretical analytical model for interfacial bond shear transmission length in each type of steel-RAC composite columns was established through the mechanical derivation, which can be used to design and evaluate the performance of anchorage zones in steel-RAC composite structures.

Modeling of Shear Mechanism of RC Deep Beams Incorporating Bond Action between Re-Bar and Concrete (주근의 부착작용에 기초하는 깊은보의 전단저항 기구의 모델화)

  • Kim, Kil-Hee
    • Journal of the Korea Concrete Institute
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    • v.18 no.5 s.95
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    • pp.639-648
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    • 2006
  • A shear experiment of one-way monotonic loading was carried out with the shear span ratio as the main experimental variable for reinforced concrete beam. Using the finite element analysis as the experimental analysis tool and the analysis method to compute the shear resistance of small shear span ratio, a new macro-model composed of crooked main strut and sub strut is proposed in consideration of the effect of bond action between re-bar and concrete based on the experimental result. The experimental finding affirmed the validity of the proposed macro-model when the shear span ratio was at or below 0.75 and confirmed that the experimental result was the most consistent with the computed analysis result when the effective factor of concrete compressive strength was set at 0.75.

ENGINEERING CERAMICS의 평면연삭가공 특성에 관한 연구

  • 김호철;김원일;강재훈
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1992.10a
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    • pp.136-144
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    • 1992
  • Recently, Silicon Nitrde ceramic is regarded as the representative engineering ceramic with the excellent mechanical properties and many functions for mechanical components and parts among various kinds of ceramics in the mechanical industry. But, during the manufacturing of engineering ceramics, there is many volumetric shrinkage coupled with a distortion of the parts which is produced. Due to the requirement for high accuracy of size, form, and surface finish of the components, machining is needed surely. Nowdays, grinding with a resin bond type diamond wheels has been generally applied to machining of the engineering ceramics in the whole world because that it can be conveniently proceeded for workers to dress of tool and made with high reliability in producing factories among many bond type super-abrasive wheels yet. It is important task for attaining prescribed mechanical components with high reliability to observe the grinding mechanism of ceramics as like generation of cracks and chipping of material during process. Because they considerably effects on the strength characteristic of machined mechanical components. In this study, various surface grinding experiments using resin bond type diamond wheels are carried out for Silicon Nitride ceramic. Grinding mechanism of ceramics is observed experimentally and the relationship with various conditions is also attained. Form this experimental study, some useful machining data and information to determine proper machining condition for grinding of Silicon Nitride ceramic is obtained.

Effect of bond and bidirectional bolting on hysteretic performance of through bolt CFST connections

  • Ajith, M.S.;Beena, K.P.;Sheela, S.
    • Earthquakes and Structures
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    • v.19 no.5
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    • pp.315-329
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    • 2020
  • Through bolt connections in Concrete Filled Steel Tubes (CFSTs) has been proved to be good in terms of seismic performance and constructability. Stiffened extended end plate connection with full through type bolt helps to avoid field weld altogether, and hence to improve the quality of joints. An experimental study was conducted on the hysteretic performance of square interior beam-column connections using flat extended end plates with through bolt. The study focuses on the effect of the bond between the tie rod and the core concrete on the cyclic performance of the joint. The study also quantifies how much the interior joint is getting strengthened due to the confinement effect induced by bi-directional bolting, which is widely used in 3D moment resisting frames. For a better understanding of the mechanism and for the prediction of shear capacity of the panel zone, a mathematical model was generated. The various parameters included in the model are the influence of axial load, amount of prestress induced by bolt tightening, anchorage, and the concrete strut action. The study investigates the strength, stiffness, ductility, and energy dissipation characteristics. The results indicate that the seismic resistance is at par with American Institute of Steel Construction (AISC) seismic recommendations. The bidirectional bolting and bond effect have got remarkable influence on the performance of joints.

Identification of Damage Characteristics Due to Cracking of Concrete Structures Using Acoustic Emission (음향방출 특성을 이용한 콘크리트 부재종류 및 하중상태에 따른 균열손상 연구)

  • 오병환;김응재;김광수;유성원
    • Journal of the Korea Concrete Institute
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    • v.11 no.4
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    • pp.107-116
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    • 1999
  • The damage in concrete structures generally starts with microcracking and thus it is important to find and explore these microcracks in concrete in order to ensure appropriate safety and serviceability. The purpose of the present study is to identify the damage characteristics of concrete structures due to cracking by employing the acoustic emission techniques. A comprehensive experimental study has been done. The cracking damage under tensile and flexural loadings have been identified and the bond damage between steel and concrete have been also characterized. It is seen that the amplitudes and energy level of Acoustic Emission(AE) events are found to be relatively small for bond cracking damages and large for tensile cracking damages. The characteristic equations of the AE events for various cracking damages have been proposed based on the present test data. The internal microcracks are progressively developed ahead of a visible actual crack and the present study clearly exhibits these damage mechanism for various types of cracking in concrete. The present study provides useful data which can be used to identify the various types of cracking damages in concrete structures. This will allow efficient maintenance of concrete structures through monitoring of internal cracking based on acoustic emission.

Dual potential capacity model for predicting failure of RC beams damaged by corrosion of tensile reinforcement

  • Sun-Jin Han;Deuckhang Lee;Hyo-Eun Joo;Kang Su Kim
    • Computers and Concrete
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    • v.34 no.4
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    • pp.503-517
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    • 2024
  • This study presents an analysis model to estimate the shear strength of a reinforced concrete (RC) member with corroded tensile reinforcements. The thick-walled cylinder theory was modified to fit the dual potential capacity model to reflect interdependent failure mechanisms, including the degradation effect of bonds in corroded tensile reinforcement. In the proposed model, it is considered that the shear failure of corroded RC members with no proper anchorage detail is primarily dominated by the flexural-bond mechanism, where insufficient bond strength is provided owing to corrosion damage. However, when tensile reinforcements are properly anchored in the end regions using end hooks or mechanical devices, it is assumed that the tied-arch action can be developed as a secondary shear transfer mechanism, even under severe corrosion damage. The proposed model was verified by comparison with shear test results of corroded RC members collected from the literature, and it appeared that the proposed model can estimate their shear strengths with a good level of accuracy, regardless of various anchorage details and corrosion rates in tensile reinforcements.