• Textile Coloration and Finishing
• /
• v.17 no.2 s.81
• /
• pp.10-18
• /
• 2005

Silk fabrics mordanted with $Fe^{2+},\;Ni^{2+},\;and\;Cu^{2+}$ were dyed with the aqueous extract of Cassia tora L. seed which was known to include water soluble colorant kaempferol, one of flavonol compounds. Kaempferol can react with free radicals and chelate transition metal ions, which is thought to catalyze processes leading to the appearance of free radicals and have antioxidant activity. In relation to the coordinating and chelating mechanism of the ions with the silk protein and kaempferol, reasonable conclusions should be made on the colorant uptake and the water fastness of the fabric. The amount of the colorant on the fabric was in the order of $Fe^{2+}>Ni^{2+}>Cu^{2+}$. In case of dyeing through coordinaiton bonds between transition metal ions and silk protein and colorants, it was thought that the ions with the smaller secondary hydration shell, the higher preference to the atoms of the ligand coordinated, and the suitable bonding stability for the substitution of primarily hydrated water molecules for colorants led to the higher colorant uptake. The water fastnsess of the fabric was in the order of $Fe^{2+}>Cu^{2+}>Ni^{2+}$. It should be reasonable to choose transition metal ions with weak and strong tendency to the ionic and the coordination bond, respectively, to the carboxylate anion of the silk protein. Although further research needs to be done, the conclusions above may be generally applied to the natural dyeing through the coordination bond mechanism between transition metal ions and colorants and substrates.

• Journal of the Earthquake Engineering Society of Korea
• /
• v.10 no.3 s.49
• /
• pp.113-123
• /
• 2006

An experimental investigation on the behavior of reinforced concrete coupling beams is presented. The test variables are the span-to-depth ratio, the ratio of flexural reinforcements and the ratio of shear rebars. The distribution of arch action and truss action which compose the mechanism of shear resistance is discussed. The increase of plastic deformation after yielding transforms the shear transfer by arch action into by truss action. This study proposes the deformation model for reinforced concrete coupling beams considering the bond slip of flexural reinforcement. The strain distribution model of shear reinforcements and flexural reinforcements based on test results is presented. The yielding of flexural reinforcements determines yielding states and the ultimate states of reinforced concrete coupling beam are defined as the ultimate compressive strain of struts and the degradation of compressive strength due to principal tensile strain of struts. The flexural-shear failure mechanism determines the ultimate state of RC coupling beams. It is expected that this model can be applied to displacement-based design methods.

• Journal of Mechanical Science and Technology
• /
• v.16 no.7
• /
• pp.911-918
• /
• 2002

The tribological performance of A1$_2$O$_3$/NiCr coating deposited on steel (SH45C) was investigated under lubrication. The parameters of sliding wear consist of normal load and coating thickness. Test result showed that there was no evidence of an improved bonding strength in the coating. However, the wear resistance of the A1$_2$O$_3$/NiCr coaling was significantly greater than that of the Al$_2$O$_3$ coating. It was eviclent that the residual stress for the A1$_2$O$_3$coating was higher than that of the A1$_2$O$_3$/NiCr coating from the Scratch test failure of coating. The bond coating played an important role in decreasing the residual stress. Also, it was found that the residual stress had d notable influence on the wear mechanism.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2002.05a
• /
• pp.5-8
• /
• 2002

The use of the co-cured joining method for composite structures is attractive due to several benefits. However, since the design stress level in cyclic loads is often smaller than the joint strength obtained from the static tensile load test, it is important to establish proper fatigue design criteria. Although some researchers have reported on co-cured joints, there are only a few papers published on the fatigue characteristics of co-cured joints. In this paper, the effect of bond parameters on the fatigue characteristics of a steel-composite co-cured double lap joint under cyclic tensile loads was experimentally investigated. We considered the surface roughness of the steel adherend and the stacking sequence of the composite adherend as bond parameters. A fatigue failure mechanism of the co-cured double lap joint was explained systematically by investigating the surfaces of failed specimens.

• Proceedings of the KWS Conference
• /
• 2002.10a
• /
• pp.65-69
• /
• 2002

An Al film deposited on the Kovar alloy substrate was anodically-bonded to the borosilicate glass, and the bond interfaces was closely investigated by transmission electron microscopy. Al oxide was found to form a layer ~l0 nm thick at the bond interface, and fibrous structure of the same oxide was found to grow epitaxially in the glass from the oxide layer. The fibrous structure grew with the bonding time. The mechanism of the formation of this fibrous structure is proposed on the basis of the migration of Al ions under the electric field. Penetration of Al into glass beyond the interfacial Al oxide was not detected. The comparison of the amount of excess oxygen ions generated in the alkali depletion layer with that incorporated in the Al oxide suggests that the growth of the alkali-ion depletion layer is controlled by the consumption of excess oxygen to form the interfacial Al oxide.

• The korean journal of orthodontics
• /
• v.19 no.2
• /
• pp.155-163
• /
• 1989

Indirect bonding is done by placing the brackets on a model in the laboratory and using a template or tray to transfer the laboratory positioning to the teeth. The advantages of this technique are 1. decreased chair time 2. less patient discomfort 3. accuracy of a attachment placement 4. good adaptation of attachment to tooth contour 5. occlusal relationship of brackets and opposing teeth can be checked The disadvantages of the technique are 1. complex laboratory procedure 2. sometimes difficult on very short clinical crowns 3. teeth with crowns, large buccal restoration will not bond 4. may not be fitted close, if poor adaptation 5. likely to be disturbed setting Several indirect bonding techniques have proved reliable in clinical practice. However, they differ in the way the brackets are attached temporarily to the model, the type of transfer tray or other mechanism used, the adhesive or sealant employed, whether segmented or full bonding used, and the way the transfer is removed so as not to exert excessive force on a still maturing bond.

• Bulletin of the Korean Chemical Society
• /
• v.34 no.12
• /
• pp.3591-3596
• /
• 2013

The enantioselective aza-Morita Baylis Hillman reaction of nitroalkene and N-tosylimine catalyzed by thiourea-tertiary amine has been investigated using density functional theory. Enantioselectivity is dominated by the cooperative effect of non-covalent and weak covalent interactions imposed by different units of catalyst. As Lewis base, the tertiary amine unit activates nitroalkene via weak covalent bond. The weak covalent interaction orients the reaction in a major path with smaller variations of this bond. The aromatic ring unit activates N-tosylimine via ${\pi}-{\pi}$ stacking. The non-covalent interaction selects the major path with smaller changes of the efficient packing areas. Thiourea unit donates more compact H-bonded network for species of the major path. The calculated ee value in xylene solution phase (97.6%) is much higher than that in N,N-Dimethylformamide (27.2%). Our conclusion is also supported by NBO analysis.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1999.04a
• /
• pp.543-546
• /
• 1999

The purpose of the present study is to identify the damage characteristics of concrete structures due to cracking by employing the acoustic emission techniques. A comprehensive experimental study has been done. The cracking damages under tensile and flexural loadings have been identified and the bond damage between steel and concrete have been also characterized. It is seen that the amplitudes and energy level of AE events is found to be smaller for bond cracking damages and larger for tensile cracking damages. The characteristic equations of the AE events for various cracking damages have been proposed based on the present test data. The internal microcracks are progressively developed ahead of a visible actual crack and the present study clearly exhibits thses damage mechanism for various types of cracking in concrete. The present study provides very useful data which can be used to identify the various types of cracking damages in concrete structures. This will allow very efficient maintenance of concrete structures through monitoring of internal cracking based on acoustic emission.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.23 no.7 s.166
• /
• pp.1245-1252
• /
• 1999

The sliding wear behavior of $Al_2O_3/NiCr$ coating deposited on steel(SM45C) was investigated under lubrication. The parameters of sliding wear are normal loads, coating thickness. As a result, the wear resistance of $Al_2O_3/NiCr$ coating was remarkably greater than that of $Al_2O_3$ coating. The optimized coating thickness was found to be $300{\mu}m$ to ensure good anti-wear. The bond coating played important role in decreasing residual stress. The residual stress had much influence on wear mechanism. These results were correlated with the stress state of coating and the microstructure of coating.

• Journal of the Korean Chemical Society
• /
• v.14 no.2
• /
• pp.161-168
• /
• 1970

In order to obtain the more effective evidence, supporting the hypothesis which have been previously described by former report that pepsin (EC 3.4. 4.1) forms a hydrophobic bond with the nonpolar side chain of its substrate, the inhibitory effect of carboxylic acids(from formic acid to iso-butyric acid) on the activity of pepsin to the synthetic dipeptide, N-Carbobenzoxy-L-glutamyl-L-tyrosine, was discussed. The kinetic study showed that the inhibition by carboxylic acids was competitive. The Kidecreased with increasing size of the inhibitor molecule. The $-{\Delta}F^{\circ}$increased linearly with increasing number of carbon atoms in the hydrocarbon chain of the inhibitor. It was confirmed that the hydrophobic bond between more than one side chain of amino acid residues(phenylalanine) in the binding region of the active center of pepsin and the side chain of amino acid residues in the substrate was formed as the first step of its enzymic mechanism. The inhibitory effect of carboxylic acids was due to the competition of the hydrocarbon group of the carboxylic acids with the side chain of the substrate for the hydrophobic binding site(the side chain of phenylalanine) of the pepsin.