• 콘크리트학회논문집
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• 제11권4호
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• pp.129-136
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• 1999

For the prediction of concrete-steel bond ability in reinforced concrete, many countries establish specifications for the pullout test. But these methods hardly to consider many parameters such as strength, shape, diameter and location of steel, concrete restrict condition by loading plate, strength of concrete and cover depth etc, and it is difficult to solve concentration and disturbance of stress. The purpose of this study is to propose a New Ring Test method which can be rational quantity evaluations of bond splitting mechanism. For this purpose, pullout test was carried out to assess the effect of several variables on bond splitting properties between reinforcing bar and concrete. Key variables are concrete compressive strength, concrete cover, bar diameter and rib spacing. Failure mode was examined and maximum bond stress-slip relationships were presented to show the effect of above variables. As the result, it appropriately expressed general characteristics of bond splitting mechanism, and it proved capability for standard test method.

• Journal of Welding and Joining
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• 제8권3호
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• pp.31-38
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• 1990

The bonding mechanism and bond strength were investigated for the cold pressure welding of Al to Al, Cu to Cu and Al to Cu by upsetting. A phenomenon of bonding betweenthe metallic components has been observed by a scanning electron microscope and metallurgical microscope. A modified equation for bond strength with respect to the reduction of height shows reasonably a good agreement with the experimental data. When the values of the hardening factor and threshold deformation for the given materials could be determined, the theoretical bond strength can be calculated.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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• pp.234-237
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• 2003

Previous researches about headed reinforcement have not been concerned about bond failure which is quite important is some cases. In this paper, failure mechanism including bond failure was presented in order to define the contribution of bond stress at the time failure occurs. Examined with design codes and test results, it is proved to be rational to consider the contribution of bond stress in determining the ultimate pull-out capacity of headed reinforcement. Direct adaptation of design code for anchor bolt without modification for the contribution of bond stress will lead to underestimate the capacity of headed reinforcement.

• 한국환경과학회지
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• 제12권11호
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• pp.1159-1165
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• 2003

The Carbon Bond Mechanism IV has been developed for use in urban- and regional-scale oxidant models. The photochemical mechanism, CBM4, contains extensive improvements to earlier carbon bond mechanisms in the chemical representations of aromatics, biogenic hydrocarbons, peroxyacetyl nitartes, and formaldehyde. Ozone is produced mainly by nitrogen oxides and hydrocarbon. By altering the initial concentrations of the mechanism, an analysis of the sensitivity of ozone concentrations to VOC/NO$\_$x/ ratios and VOC composition is conducted in this one-dimensional mechanism. Note that it is considered a chemical mechanism in order to understand the photochemical reactions within this mechanism. It analyzed the results of these simulations by applying a NO$\_$x/-sensitive and a VOC-sensitive regime. These sensitivity regimes are changed to match the relative contribution of VOC and NO$\_$x/ concentrations to ozone production in simulations of two sets.

• Bulletin of the Korean Chemical Society
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• 제29권10호
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• pp.1920-1926
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• 2008

We investigated the C-H bond activation mechanism of aldimine by the [RhCl$(PPH_3)_3$] model catalyst using DFT B3LYP//SBKJC/6-31G*/6-31G on GAMESS. Due to their potential utility in organic synthesis, C-H bond activation is one of the most active research fields in organic and organometallic chemistry. C-H bond activation by a transition metal catalyst can be classified into two types of mechanisms: direct C-H bond cleavage by the metal catalyst or a multi-step mechanism via a tetrahedral transition state. There are three structural isomers of [RhCl$(PH_3)_2$] coordinated aldimine that differ in the position of chloride with respect to the molecular plane. By comparing activation energies of the overall reaction pathways that the three isomeric structures follow in each mechanism, we found that the C-H bond activation of aldimine by the [RhCl$(PH_3)_3$] catalyst occurs through the tetrahedral intermediate.

• Steel and Composite Structures
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• 제6권5호
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• pp.387-400
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• 2006

This paper discusses the composite mechanism and its effect upon the behavior of a steel reinforced concrete (SRC) member subjected to a flexural load. The relationship between member strength and deformation is established using the bond strength between the steel and reinforced concrete. An analytical model is proposed and used to incorporate the sectional strains and bond strength at the elastic and inelastic stages for moment-curvature relationship derivation. The results from the flexural load tests are used to validate the accuracy of the proposed model. Comparisons between the experimental information and the analytical results demonstrate close moment-curvature relevance, which justifies the applicability of the proposed method.

• 콘크리트학회논문집
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• 제17권4호
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• pp.513-520
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• 2005

현재 유럽 및 일본의 경우 기둥 및 보 부재에 대한 전단 설계에 있어, 전단기구로서 전단보강근과 주철근의 부착작용을 필요로 하지 않는 아치기구와 전단보강근과 주근의 부착 작용을 필요로 하는 트러스기구를 고려하여, 양자의 합으로 전단내력을 평가하는 방식을 취하고 있다. 이러한 설계 방법은 매우 명료하고, 또한 힘의 평형 조건에 기초하여, 단적으로 부착의 좋고 나쁨 및 전단보강근 양의 대소로 정해지는 상한 값으로 전단 내력을 평가하는 것이 특징이다. 본 연구에서는, 역대칭 휨 모멘트를 받는 철근콘크리트 보 부재에서 단부의 텐션쉬프트 영역 사이를 대상으로 한 주철근의 축 방향 응력(압축, 인장) 및 주근의 직경, 부착길이의 상이함에 기인하는 부착거동의 차이와 트러스 기구와의 관계를 명확히 하는 것을 목적으로, 트러스기구만이 재현 가능한 모델 실험법을 제안하고, 전단보강근의 양, 부재의 축압축 응력의 크기 및 부착 영역 양단의 주철근에 가하는 힘의 크기를 실험 변수로 한 부재 실험을 실시하였다. 실험에서 얻은 결과에 기초하여, 양단부 주철근에 가한 힘의 차이로 인해 발생하는 부착응력 분포의 차이를 고려한 일정 트러스 기구와 부채형 트러스기구를 중첩한 복합 트러스 모델을 제안하였다.

• Steel and Composite Structures
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• 제38권5호
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• pp.563-582
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• 2021

The present study experimentally and analytically investigated the push-out behaviour of H-shaped steel section embedded in ultrahigh-performance fibre-reinforced concrete (UHPFRC). The effect of significant parameters such as the concrete types, fibre content, embedded steel length, transverse reinforcement ratio and concrete cover on the bond stress, development of bond stress along the embedded length and failure mechanism has been reported. The test results show that the bond slip behaviour of steel-UHPFRC is different from the bond slip behaviour of steel-normal concrete and steel-high strength concrete. The bond-slip curves of steel-normal concrete and steel-high strength concrete exhibit brittle behaviour, and the bond strength decreases rapidly after reaching the peak load, with a residual bond strength of approximately one-half of the peak bond strength. The bond-slip curves of steel-UHPFRC show an obvious ductility, which exhibits a unique displacement pseudoplastic effect. The residual bond strength can still reach from 80% to 90% of the peak bond strength. Compared to steel-normal concrete, the transverse confinement of stirrups has a limited effect on the bond strength in the steel-UHPFRC substrate, but a higher stirrup ratio can improve cracking resistance. The experimental campaign quantifies the local bond stress development and finds that the strain distribution in steel follows an exponential rule along the steel embedded length. Based on the theory of mean bond and local bond stress, the present study proposes empirical approaches to predict the ultimate and residual bond resistance with satisfactory precision. The research findings serve to explain the interface bond mechanism between UHPFRC and steel, which is significant for the design of steel-UHPFRC composite structures and verify the feasibility of eliminating longitudinal rebars and stirrups by using UHPFRC in composite columns.

• KCI Concrete Journal
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• 제12권2호
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• pp.31-43
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• 2000

The extensive usage of pretensioned prestressed concrete component in modem construe- tion as structural members mandates precise understanding of its mechanism. Especially, an adequate transfer of prestressing force from steel tendons to concrete around the end regions of the member is a critical issue. Due to the importance of the topic, several investigators have formulated equations modeling the transfer bond length based on various bonding mechanism between steel and concrete. However, the existing models are still inadequate in predicting the bond development in pretensioned prestressed concrete members. Therefore, this study presents a model of transfer bond length based on rational theory that can simulate experimental results. The model is developed into solid mechanics based structural analysis computer program. The program is validated by comparing the analysis results with experimental results of bond stress distribution, concrete strain profiles, and transfer length in pretensioned prestressed concrete members. The proposed analytical procedure in this study can be utilized as a useful tool for realistic evaluation of transfer length in pretensioned prestressed concrete members.

• Bulletin of the Korean Chemical Society
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• 제35권9호
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• pp.2717-2722
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• 2014

The reaction mechanism between azacyclopropenylidene and epoxypropane has been systematically investigated employing the second-order M${\o}$ller-Plesset perturbation theory (MP2) method to better understand the reactivity of azacyclopropenylidene with four-membered ring compound epoxypropane. Geometry optimization, vibrational analysis, and energy property for the involved stationary points on the potential energy surface have been calculated. It was found that for the first step of this reaction, azacyclopropenylidene can insert into epoxypropane at its C-O or C-C bond to form spiro intermediate IM. It is easier for the azacyclopropenylidene to insert into the C-O bond than the C-C bond. Through the ring-opened step at the C-C bond of azacyclopropenylidene fragment, IM can transfer to product P1, which is named as pathway (1). On the other hand, through the H-transferred step and subsequent ring-opened step at the C-N bond of azacyclopropenylidene fragment, IM can convert to product P2, which is named as pathway (2). From the thermodynamics viewpoint, the P2 characterized by an allene is the dominating product. From the kinetic viewpoint, the pathway (1) of formation to P1 is primary.