• Title/Summary/Keyword: Blue emissive polymers

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Synthesis and EL Properties of Blue Light-emitting Poly(arylenevinylene)s

  • Hwang, Do-Hoon
    • Journal of Information Display
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    • v.3 no.1
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    • pp.1-5
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    • 2002
  • A series of fully conjugated polymers containing new arylenevinylene units were synthesized and their light-emitting properties were investigated. A bisphosphonate containing tetraphenyl group was made to react with three different dialdehyde monomers to produce fully conjugated alternating copolymers. The photoluminescence (PL) and the electroluminescence (EL) peak wavelengths of the polymers were varied from 500 nm to 460 nm depending on the polymer structure. Single layer EL devices using the polymers as an emissive layer have been fabricated. The single layer EL devices became visible between 12-22 V and emitted blue light.

Synthesis and Characterization of 1,2,4-Oxadiazole-Based Deep-Blue and Blue Color Emitting Polymers

  • Agneeswari, Rajalingam;Tamilavan, Vellaiappillai;Hyun, Myung Ho
    • Bulletin of the Korean Chemical Society
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    • v.35 no.2
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    • pp.513-517
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    • 2014
  • Two donor-acceptor-donor monomers such as 3,5-bis(4-bromophenyl)-1,2,4-oxadiazole (BOB) and 3,5-bis(5-bromothiophen-2-yl)-1,2,4-oxadiazole (TOT) incorporating electron transporting and hole blocking 1,2,4-oxadiazloe moiety were copolymerized with light emitting fluorene derivative via Suzuki polycondensation to afford two new polymers, PFBOB and PFTOT, respectively. The optical studies for polymers PFBOB and PFTOT revealed that the band gaps are 3.10 eV and 2.72 eV, respectively, and polymer PFBOB exhibited a deep-blue emission while polymer PFTOT showed blue emission in chloroform and as thin film. The photoluminescence quantum efficiencies (${\Phi}_f$) of polymers PFBOB and PFTOT in chloroform calculated against highly blue emitting 9,10-diphenylanthracene (DPA, ${\Phi}_f=0.90$) were 1.00 and 0.44, respectively.

White Light-Emitting Diodes Using Conjugated Polymer Blends

  • Hwang, Do-Hoon;Park, Moo-Jin;Kim, Suk-Kyung;Lee, Chang-Hee;Kim, Yong-Bae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.585-587
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    • 2004
  • We report the characterization of white light emitting devices fabricated using conjugated polymer blends. Blue emissive poly[9,9-bis(4'-n-octyloxyphenyl) fluorene-2,7-diyl-co-10-(2'-ethylhexyl)phenothiazine-3,7-diyl] [poly(BOPF-co-PTZ)] and red emissive poly(2-(2'-ethylhexyloxy)-5-methoxy-1,4-phenylenevinylene) (MEH-PPV) were employed in the blends. The inefficient energy transfer between these blue and red light emitting polymers (previously deduced from the PL spectra of the blend films) enables the production of white light emission through control of the blend ratio. The PL and EL emission spectra of the blend systems were found to vary with the blend ratio. The EL devices were fabricated in the ITO/PEDOT/blend/LiF/Al configuration and white light emission was obtained for one of the tested blend ratios.

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Study of White Polymer Light Emitting Diode with Blending Method

  • Shin, Byong-Wook;Lee, Sung-Youp;Lee, Eui-Wan;Lee, Hyeong-Rag
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1461-1463
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    • 2007
  • In this study, we report the luminescent properties of white polymer light emitting diode (WPLED) fabricated by soluble methods with poly-fluorenebased polymers blends which emit blue and yellow light. A device structure of ITO/PEDOT:PSS/Emissive Layer (EML)/Al was employed.

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The Investigation of Photolithographic Patterning Method for Polymer Light Emitting Diodes

  • Kim, Mi-Kyung;Lee, Jeong-Ik;Kim, Duck-Il;Oh, Ji-Young;Hwang, Chi-Sun;KoPark, Sang-He;Yang, Yong-Suk;Chu, Hye-Yong;Kim, Suk-Kyung;Hwang, Do-Hoon;Lee, Hyung-Jong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.592-594
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    • 2004
  • We have investigated the photolithographic patterning method of light emitting polymer film for polymer light emitting diodes (PLEDs). Blue light emitting polymers based on polyfluorene, which can be cured photochemically to yield an insoluble form, have been synthesized using Ni(0) mediated Yamamoto polymerization. The relationship between patterning property and several variables such as the intensity of the exposed UV light, the concentrations of additives, has been studied by using optical microscope analysis, UV/visible spectroscopy, and photoluminescence. We have successfully fabricated PLEDs composed of the patterned emissive layer and their electroluminescence property has been also investigated. In this presentation, the detailed photolithographic patterning method and its application for polymer light emitting display will be discussed.

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The Investigation of Photolithographic Patterning Method for Polymer Light Emitting Diodes (PLEDs) (고분자 전기 발광 다이오드(PLEDs)를 위한 포토리소그라피 패터닝 방법에 관한 연구)

  • Kim, Mi-Kyung;Lee, Jeong-Ik;Kim, Duck-Il;Hwang, Chi-Sun;Yang, Yong-Suk;Oh, Ji-Young;KoPark, Sang-He;Chu, Hye-Yong;Kim, Suk-Kyung;Hwang, Do-Hoon;Lee, Hyung-Jong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05a
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    • pp.106-108
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    • 2004
  • We have investigated the photolithographic patterning method of light emitting polymer film for polymer light emitting diodes (PLED). Blue light emitting polymers based on polyfluorene, which can be cured photochemically to yield an insoluble form, have been synthesized using Ni(0) mediated Yamamoto polymerization. The relationship between patterning property and several variables such as the intensity of the exposed UV light, the concentrations of additives, has been studied by using optical microscope analysis, UV/visible spectroscopy, and photoluminescence. We have successfully fabricated PLEDs composed of the patterned emissive layer and their electroluminescence property has been also investigated. In this presentation, the detailed photolithographic patterning method and its application for polymer light emitting display will be discussed.

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