• Title/Summary/Keyword: Block formation

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Synthesis of Star like Random Copolymers from Resorcinarene-based Alkoxyamine Initiator via Nitroxide Mediated Free Radical Polymerization

  • Abraham, Sinoj;Choi, Jae-Ho;Ha, Chang-Sik;Kim, Il
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.337-337
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    • 2006
  • The synthesis of an octafunctional resorcinarene based initiator for nitroxide mediated polymerization and its ability to yield random star copolymers of styrene and methyl methacrylate is studied. The effect of the initiator conformations towards its activity and the conditions that permit the formation of well-defined star block copolymers is also investigated in detail. The characterization of the initiator and the polymers were carried out by various spectro-analytical techniques. Well-defined random copolymers were obtained with controlled molecular weight and low PDI depending on the monomer feed.

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Self-assembled Micelle-based Fluorescence Sensor for Extremely Acidic pH Range (강산성 용액의 pH를 측정할 수 있는 미셀기반의 형광센서 개발)

  • Lee, Jeongmoo;Lee, Seoung Ho
    • Journal of Environmental Science International
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    • v.29 no.8
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    • pp.801-808
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    • 2020
  • In this study, an effective fluorescence pH sensor based on conjugated polyelectrolyte micelles (CPMs) was devised for detecting extremely acidic conditions. An amphiphilic coumarin derivative (CC12-N), a building block, was prepared, into which an ionizable amino group, aryl amine, was incorporated as a potential hydrophilic moiety. This monomer displays self-assembled micelle formation in extremely acidic pH ranges, giving a hydrophobic π-extended conjugated system at the inner part and hydrophilic functionality at the periphery, resulting in efficient fluorescence intensity enhancement. This new micelle-based fluorescence provides an efficient sensing platform for detecting very low pH values in the presence of competing substances.

Fractographic Analysis Method of Fatigue Fracture Surface under Program and Random Loading for Aluminum Alloy (알루미늄 합금의 랜덤하중 하에서 발생한 피로파면 해석 방법)

  • 김상태;최성종;양현태;이희원
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.12
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    • pp.2055-2060
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    • 2003
  • Striation is a typical pattern observed on the fatigue fracture surface and the spacing is known to correspond to a macroscopic fatigue crack growth rate, and many models for the predict in the formation of such striation have been proposed. However, these theories and methods can't be applied under random loading spectrum. In this study, the fatigue tests were carried out on aluminum alloy under random loading spectrum. The fatigue fracture surfaces were observed in the scanning electron microscope (SEM) and great quantities of SEM micrographs were synthesized and saved in computer system. The space and morphology of several large-scale striations, which are expected to from at the relatively greater load range in loading block, were observed. The crack length for each loading blocks was decided in consideration of regularity and repetition of those striations. It is shown that the applicability of fractographic methods on the fatigue fracture surface under random loading spectrum.

THE MICROSOMAL EPOXIDE HYDROLASE(MEPHXS) POLYMORPHISMS AND THE ASSOCIATION OF MICRONUCLEI(MN) IN THE BENZENE-EXPOSED WORKERS

  • Kim, Tae-Yon;Kwon, Seul-A;Kim, Jin-Sik;Kim, Su-Young;Lee, Young-Jun;Chung, Eun-Jung;Paek, Do-Myung;Park, Jung-Keun;Chung, Hai-Won
    • Proceedings of the Korean Society of Toxicology Conference
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    • 2002.05a
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    • pp.134-134
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    • 2002
  • In order to investigate whether genetic polymorphisms in the mEH exon3 (Tyr139His), exon4 (His113Arg) interact with the formation of MN in benzene exposed workers, the PCR-RFLP based genotyping of 76 exposed and 115 controls were performed and cytokinesis-block micronucleus (CBMN) analysis of 56 exposed and 53 controls was employed.(omitted)

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Synthesis of $\beta$-SiC Whiskers by Decomposition-Carbonization of Mullite (물라이트의 환원분해 및 탄화법에 의한 $\beta$-SiC 휘스커의 합성)

  • 김종엽;남원식;최상욱
    • Journal of the Korean Ceramic Society
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    • v.32 no.10
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    • pp.1139-1146
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    • 1995
  • $\beta$-SiC whiskers could be formed from a system of mullite-carbon-hydrogen by VLS mechanism at elevated temperatures. It was considered that methane gases were generated from the reaction of hydrogen gases with carbon black, and were reacted with mullite to produce two kinds of gases; silicon suboxide (SiO) and carbon monoxide (CO) of precursors of SiC. With increasing the synthesizing temperature up to 146$0^{\circ}C$, the formation of $\beta$-SiC whisker increased from 0.58 mg/$\textrm{cm}^2$ to 3.98 mg/$\textrm{cm}^2$ on the basis of unit area of carbon block, and the diameters of whiskers had their uniformity due to the reduction in stacking faults.

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An Analysis for the Formation and Kinematic Behavior of Potential Tetrahedral Block on the Roof of Underground Excavation (지하공동 천장에 발달된 잠재적 사면체 블록의 판별 및 거동 양상 분석)

  • 조태진;홍관석;김일석
    • Journal of the Korean Geotechnical Society
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    • v.17 no.5
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    • pp.17-27
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    • 2001
  • 지하 굴착공동의 천장면에 형성되는 잠재적 키블록의 존재성과 운동학적 거동 양상 및 안정성을 해석적으로 분석할 수 있는 시스템을 개발하였다. 천장에서 측정된 절리들의 상대적인 위치와 방향성 자료를 이용하여 데이타베이스를 구축하였으며, 굴착설계도와 연계된 전산절리도를 작성하였다. 잠재적 키블록의 존재성과 거동양상은 사면체로 가정된 블록 옆면의 3차원 공간에서의 평면식을 절리의 방향성에 의거하여 구성하며 대수학적으로 분석되었다. 블록의 안정성 분석은 자중에 의해 미끄러짐이 발생되는 블록면의 공간 기하학적 특성을 고려하여 수행하였다. 개발된 분석시스템의 현장활용성을 검증하기 위하여 언양 자수정동굴에서 키블록 형성 및 거동양상을 조사하여 분석결과와 비교하였다.

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Active Flow Control Using the Synthetic Jet Actuator (Synthetic Jet Actuator를 이용한 능동 유동 제어)

  • Noh Jongmin;Kim Chongam
    • 한국전산유체공학회:학술대회논문집
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    • 2005.04a
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    • pp.65-69
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    • 2005
  • Curretly, the development of MEMS(Micro Electronic Mechanical System) technology awakes many research's interest for the aerodynamics. This work presents the development of a compact synthetic jet actuator for flow separation control at the flat plate. The formation and evolution of fluidic actuators based on synthetic jet technology are investigated using Reynolds-Averaged Navier-Stokes equations. Also, 2-Dimensional, unsteady, incompressible Navier-Stokes equation solver with single partitioning method for Multi-Block grid to analyze and a modeled boundary condition in developed fo. the synthetic jet actuator. Both laminar and turbulent jets are investigated. Results show very good agreement with experimental measurements. A jet flow develops, even though no net mass flow is introduced. Pair of counter-rotating vortices are observed near the jet exit as are observed in the experiments.

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