• Journal of the Korean Recycled Construction Resources Institute
• /
• v.3 no.3
• /
• pp.261-267
• /
• 2015

To develop high-strength high-volume ground granulated blast-furnace slag (GGBFS) concrete, this study investigated the characteristics of strength development and durability of concrete with the water-to-binder ratio of 23% and the GGBFS replacement ratio of up to 65%. The results show that the compressive strength of GGBFS blended concrete is lower than that of ordinary Portland cement (OPC) concrete up to 3-day age, but the becomes higher after 7-day age. Together with strength increase, the pore structure becomes tighter, and thus the resistance to chloride ion penetration increases. Therefore, the GGBFS blended concrete has high resistance to freezing and thawing without additional air-entraining, and high resistance to carbonation despite low amount of calcium hydroxide ($Ca(OH)_2$). On the other hand, if silica fume (SF) is blended with GGBFS, the strength becomes lower than that of the concrete blended with GGBFS only, and the resistance to chloride ion penetration deceases. Therefore, it needs further studies on the reaction of SF in high-strength high-volume GGBFS concrete.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2006.05a
• /
• pp.5-21
• /
• 2006

Traditional standards and specifications for concrete have largely been prescriptive, (or prescription-based), and can sometimes hinder innovation and in particular the use of more environmentally friendly concretes by requiring minimum cement contents and SCM replacement levels. In December 2004, the Canadian CSA A23.1-04 standard was issued which made provisions (a) for high-volume SCM concretes, (b) added new performance requirements for concrete, and (c) clearly outlined the requirements and responsibilities for use in performance-based concrete specifications. Also, in December 2003, the CSA A3000 Hydraulic Cement standard was revised. It (a) reclassified the types of cements based on performance requirements, with both Portland and blended cements meeting the same physical requirements, (b) allows the use of performance testing for assessing sulphate resistance of cementitious materials combinations, (c) includes an Annex D, which allows performance testing of new or non-traditional supplementary cementing materials. From a review of international concrete standards, it was found that one of the main concerns with performance specifications has been the lack of tests, or lack of confidence in existing tests, for judging all relevant performance concerns. Of currently used or available test methods for both fresh, hardened physical, and durability properties, it was found that although there may be no ideal testing solutions, there are a number of practical and useful tests available. Some of these were adopted in CSA A23.1-04, and it is likely that new performance tests will be added in future revisions. Other concerns with performance standards are the different perspectives on the point of testing for performance. Some concrete suppliers may prefer processes for both pre-qualifying the plant, and specific mixtures, followed only with testing only 'end-of-chute' fresh properties on-site. However, owners want to know the in-place performance of the concrete, especially with high-volume SCM concretes where placing and curing are important. Also, the contractor must be aware of, and share the responsibility for handling, constructability, curing, and scheduling issues that influence the in-place concrete properties.

• Journal of the Korea Concrete Institute
• /
• v.21 no.1
• /
• pp.21-27
• /
• 2009

In this study, experimental findings on the resistance to magnesium sulfate attack of portland cement mortar and paste specimens incorporating metakaolin (MK) are presented. Specimens with four replacement levels of metakaolin (0, 5, 10 and 15% of cement by mass) were exposed to solutions with concentrations of 0.424% and 4.24% as $MgSO_4$ at ambient temperature. The resistance of mortar specimens was evaluated through visual examination and linear expansion measurements. Additionally, in order to identify the products formed by magnesium sulfate attack, microstructural analyses such as XRD, DSC and SEM/EDS were also performed on the paste samples incorporating metakaolin. Results confirmed that mortar specimens with a high replacement level of metakaolin exhibited lower resistance to a higher concentration of magnesium sulfate solution. It was found that the negative effect of metakaolin on the magnesium sulfate attack is partially attributed to the formation of gypsum and thaumasite. Conclusively, it is necessary to pay a special attention when using metakaolin in concrete structures, particularly under highly concentrated magnesium sulfate environment.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.5 no.4
• /
• pp.488-495
• /
• 2017

In this study, we conducted the kinetic hydration modeling of OPC and the final product according to the substitution ratio of GGBS by using the geochemical code, GEMS, in order to calculate the thermodynamic equilibrium. The thermodynamic data was used by GEMS's 3rd party database, Cemdata18, and the cement hydration model, the Parrot & Killoh model was applied to simulate the hydration process. In OPC modeling, ion concentration of pore solution and hydration products by mass and volume were observed according to time. In the GGBS modeling, as the substitution rate increases, the amount of C-S-H, which contributes the long-term strength, increases, but the amount of Portlandite decreases, which leads to carbonation and steel corrosion. Therefore, it is necessary to establish prevention of some deterioration.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.32 no.6A
• /
• pp.427-435
• /
• 2012

In order to evaluate the effects of exposure conditions on the resistance to sulfate attack of normal and blended cement mortars, several mechanical characteristics of the mortars such as expansion, strength and bulk density were regularly monitored for 52 cycles under sodium sulfate attack. The mortar specimens were exposed to 3 different types of exposure conditions; 1) continuous full immersion(Exposure A), continuous half-immersion(Exposure B) and cyclic wetting-drying(Exposure C). Experimental results indicated that the maximum deterioration was noted in OPC mortar specimens subjected to Exposure B, showing the wide cracks in the portions where attacking solution is adjacent to air. Additionally, the beneficial effect of ground granulated blast-furnace slag and silica fume was clearly observed showing a superior resistance against sodium sulfate attack, because of its lower permeability and densified structure. Thus, it is suggested that when concrete made with normal cement is exposed to sulfate environment, proper considerations on the exposure conditions should be taken.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.8 no.3
• /
• pp.237-247
• /
• 2006

The use of high-performance shotcrete lining is indispensable to improve long-term durability of a tunnel and to apply the single-shell tunnelling method. Among a lot of shotcrete admixtures, pozzolan materials such as silica fume have positive effects on increasing the strength and the durability of shotcrete. It is also well known that a cement-based accelerator is much faster in setting time and more eco-friendly than conventional accelerators. This study aimed to improve the properties of wet-mix shotcrete by incorporating with Metakaolin and the calcium aluminate based accelerator. To compare Metakaolin with silica fume, mixing ratios of each material were varied as 4% and 8% of cement weight. Moreover, Metakaolin was blended with silica fume, and their binder was also set to 4% and 8% of cement weight. At each mixing condition, setting time, compressive strength, flexural strength, permeability and freezing-thawing resistance were measured. From the experiments, it was revealed Metakaolin could be a substituting material for silica fume.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.16 no.4
• /
• pp.122-129
• /
• 2012

In this study, environmental problems(i.e., pH elevation and $Cr^{6+}$ detection) occurred by using the cement grout made from CA(calcium aluminate) were evaluated using viscosity agents(MC, chelate polymer). Ordinary portland cement and blaste-furnace slag cement were used by main materials and ACC(blended mixture of calcium aluminate) were used by accelerator for hardening of grout. In addition, viscosity agents were used for preventing pH elevation and heavy metal detection from grouting materials. From the results, it was noted that when chelate polymer was used, pH elevation and $Cr^{6+}$ detection were minimized. However, other cases showed higher pH elevation and $Cr^{6+}$ detection. At test 1 day, $Cr^{6+}$ detection with age presented over 97% of total value and, after that, additional increase was not distinct. As a result of this study, it was acknowledged that, to control pH elevation and heavy-metal (like $Cr^{6+}$) detection, the usage of BSC and chelate polymer is a very useful fact.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.7 no.4
• /
• pp.302-309
• /
• 2019

This paper shows an experimental study for fundamental characteristics of alkali activated fly ash-slag cement paste exposed to seawater of 5℃. Fly ash and slag were blended in three different ratios; 6:4, 7:3, and 8:2. Activators (NaOH and Na2SiO3) used 5% of the binder weight. It was shown that as the fly ash substitution rate in creased, compressive strength and density decreased, and water absorption rate increased. The results of X-ray diffraction and thermogravimetry showed that hydration reactants formed in samples did not differ significantly, however, C-S-H gel increased as the slag substitution rate increased. It showed that mechanical properties of fly ash-slag cement pastes under 5℃ seawater condition were affected by the slag substitution rate rather than fly ash.

• Geomechanics and Engineering
• /
• v.25 no.2
• /
• pp.143-157
• /
• 2021

Expansive soil is the most predominant geologic hazard which shows a large amount of shrinkage and swelling with changes in their moisture content. This study investigates the macro-mechanical and micro-structural behaviours of dredged natural expansive clay from coal mining treated with ordinary Portland cement or hydrated lime addition. The stabilised expansive soil aims for possible reuse as pavement materials. Mechanical testing determined geotechnical engineering properties, including free swelling potential, California bearing ratio, unconfined compressive strength, resilient modulus, and shear wave velocity. The microstructures of treated soils are observed by scanning electron microscopy, x-ray diffraction, and energy dispersive spectroscopy to understand the behaviour of the expansive clay blended with cement and lime. Test results confirmed that cement and lime are effective agents for improving the swelling behaviour and other engineering properties of natural expansive clay. In general, chemical treatments reduce the swelling and increase the strength and modulus of expansive clay, subjected to chemical content and curing time. Scanning electron microscopy analysis can observe the increase in formation of particle clusters with curing period, and x-ray diffraction patterns display hydration and pozzolanic products from chemical particles. The correlations of mechanical properties and microstructures for chemical stabilised expansive clay are recommended.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.9 no.2
• /
• pp.117-126
• /
• 2021

An experimental study was carried out to investigate the applicability of cement-based materials for green soil which is a soil for promoting plant growth. The results show that the shear strength of the green soil mixed with gypsum cement (No.3) was low, but the hardness (23.6mm) and pH value (7.4) was most suitable for the vegetation environment. In addition, the initial vegetation germination of green soil, which improved performance by adding a moisturizer, was slower than that of general green soil, and the conductivity value tended to be slightly higher. On the other hand, the slope adhesion of advanced green soil was high, and it was found that the plant growth rate and the regeneration capacity were superior after time passed.