• Title/Summary/Keyword: Blend ratio

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Morphology of Membranes Formed from Polysulfone/Polyethersulfone/N-methyl-2-pyrrolidone/Water System by Immersion Precipitation

  • Baik, Ki-Jun;Kim, Je-Young;Lee, Jae-Sung;Kim, Sung-Chul;Lee, Hwan-Kwang
    • Macromolecular Research
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    • v.9 no.5
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    • pp.285-291
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    • 2001
  • The polysulfone(PSf)/polyethersulfone(PES) blend membranes were prepared by an immersion precipitation method. N-methyl-2-pyrrolidone(NMP) was used as a solvent and water as a nonsolvent. The composition of the coagulation bath and the dope polymer concentration as well as the blend ratio of two polymers were varied. The membrane morphologies were interpreted on the basis of the phase diagram of the PSf/PES/NMP/water system. As the solvent content in the coagulation bath increased in the single polymer system, the number of macrovoids decreased and the morphology was changed from finger-like to cellular structure. In the given bath condition phase separation occurs earlier for the solutions of PSf/PES blend than for those of single polymer. A horizontally layered structure and horizontal protuberances inside the macrovoid were observed for the membranes formed from PSf/PES blend solutions. This peculiar structure formation can be interpreted by a PSf-rich/PES-rich phase separation followed by a polymer-rich/polymer-lean phase separation during the exchange of solvent and nonsolvent.

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Effects of Mixed Activators on Enzymatic Activation for Wool.polyester Blend Fabrics (양모.폴리에스터 혼방직물의 효소가공 시 활성제 복합사용의 효과)

  • Song, Hyun-Joo;Song, Wha-Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.32 no.9
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    • pp.1461-1466
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    • 2008
  • This study provides effects of mixed activators on enzymatic activation and determines optimum mixture ratio for enzymatic treatment. Wool 80% and polyester 20% blend fabric and papain from carica papaya are used in this experiment. L-cysteine and sodium sulfite are used as activators for papain treatment process. The treatment condition is pH 7.5, $70^{\circ}$, papain concentration 10%(o.w.f), 60 minutes. L-cysteine and sodium sulfite are added in enzyme solution with various concentrations($0{\sim}50mM$). The optimum treatment condition is determined by measuring weight loss, tensile strength, whiteness, water contact angle(WCA), dyeability and surface micrographs. The results are as follow; The optimum mixture ratio of activators is L-cysteine 2mM and sodium sulfite 10mM. Mixed activators assists in improving the activation of papain. WCA of papain treated fabrics is decreased since papain treatment with activator mixture makes wool polyester blend fabrics more hydrophilic. Dyeing property of papain-treated fabrics more improves by the treatment with mixed activators than with single activator. It means that this method can save time and lower cost. After papain treatment in the presence of mixed activator, the surface of fabrics is modified. The surface of wool fiber shows to be descaled and hydrolyzed, and that of polyester fiber shows to be cracked.

Studies on the Improvement of Quality for Soles and Heels of Shoes (군화창 및 구두창의 품질향상에 관한 연구)

  • Huh, Dong-Sub;Choi, Choon-Chuel;Kim, Chong-Suk
    • Elastomers and Composites
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    • v.8 no.2
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    • pp.148-152
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    • 1973
  • A study of preparing rubber soles and heels was made to improve the quality in their physical properties such as resistance of cut-growth, abrasion resistance and tensile strength. Following results were obtained in the characteristics of rubber compounding: 1. In the reinforcement effect of fillers, it was found that hydrous silcate and carbon black were the best, aluminum and calcium silicate were pretty good, and basic magnesium carbonate was moderate. 2. SBR/BR blend in the ratio of from 85/25 to 100/0 and NBR/BR blend in the ratio of from 60/40 to 20/80 were the most suitable compounding condition.

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Studies on the Physical Properties and Application of EPDM-Polymer Blends. Part 4. Physical Properties for EPDM-NBR Blends (EPDM과 각종(各種)Polymer의 Blend에 의(依)한 성능변화(性能變化) 및 그 응용(應用)에 관(關)한 연구(硏究)(제4보(第4報)) EPDM과 Acrylonitrile-Butadiene Rubber의 Blend에 대(對)하여)

  • Kim, Joon-Soo
    • Elastomers and Composites
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    • v.7 no.1
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    • pp.45-52
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    • 1972
  • As a series of the studies of EPDM-Polymer blends, the experiments are concentracted to the investigation of the physical properties of the EPDM-NBR blends. The results are shown as follows; 1. As EPDM addition ratio is increased, the physical properties such as resistance to ozone and aging have also improved, on the other hand, elongation and abrasion resistance decreased. 2. Tear strength is less influenced by blending and character after aging exhibited the same result. 3. Tensile strength decreased with increase in EPDM contents, especially the ratio of EPDM/NBR are 50/50 and 75/25.

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Studies on the Physical properties and Application of EPDM-Polymer Blends. Part 5. Physical Properties for EPDM-CR Blends (EPDM과 각종(各種) Polymer의 Blend에 의(依)한 성능변화(性能變化) 및 그 응용(應用)에 관(關)한 연구(硏究) (제5보(第5報)) EPDM과 Chloroprene Rubber의 Blend에 대(對)하여)

  • Kim, Joon-Soo
    • Elastomers and Composites
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    • v.7 no.2
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    • pp.175-182
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    • 1972
  • As a series of the studies of EPDM-Polymer blonds, the experiments are concentrated to the investigation of the physical properties of the EPDM-CR blends. The results are shown as follows: 1. In blending, tensile strength decreased with increase in EPDM contents and decreasing value was good results than various EPDM blending. 2. As EPDM Addition ratio is increased physical properties such as elongation have also improved, on the other hand, hardness and abrasion resistance decreased. 3. Aging resistance is less influenced by blending. 4. Tear strength is less influenced by blending and character after aging exhibited the same result. 5. Ozone resistance was much improved after blending. It was effective more than the ratio of EPDM/CR is 25/75.

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Studies on the Physical Properties and Application of EPDM-Polymer Blends. Part 1. Physical Properties for EPDM-NR Blends (EPDM과 각종(各種) Polymer의 Blend에 의(依)한 성능변화(性能變化) 및 그 응용(應用)에 관(關)한 연구(硏究)(제1보(第1報)) EPDM과 Natural Rubber의 Blend에 대(對)하여)

  • Kim, Joon-Soo
    • Elastomers and Composites
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    • v.6 no.2
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    • pp.65-72
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    • 1971
  • The purpose of this study is to establish an effective way to utilize the application of EPDM-Polymer blends. First of all, the physical properties for EPDM/NR blends and compounding agents were studied. The results are shown as follows: 1. In blending, tensile strength and tear strength decreased with increase in EPDM contents. It was not effective more than the ratio of EPDM/NR is 50/50. 2. Elongation is influenced by blending, especially the ratio of EPDM/NR is 50/50. 3. It was found that both the resistance for ozone and aging were much improved after blending.

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Studies on it's practical Application to Auto Pneumatic tyre and Manufacture of CBR (Part 1.) On the Blend of CBR and SBR (CBR의 제조(製造) 및 이를 자동차(自動車) tyre에 활용(活用)하는데 관(關)한 연구(硏究)(제1보(第一報)) CBR와 SBR의 Blend에 관(關)하여)

  • Lee, Hyan-O;Lee, Young-Kil
    • Elastomers and Composites
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    • v.6 no.1
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    • pp.53-70
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    • 1971
  • We have studied the blending effects of cis-1,4-polybutadiene (CBR) and styrene-tutadiene rubber at various blending ratios of 100 : 0, 70 30, 50 : 50, 30 : 70, 0 : 100, and of carbon black ISAF and HAP at various compounding ratios of 45 PHR, 55 PHR, 65 PHR, for tyre tread rubber. The results obtained are summerized as follows; 1. For tyre tread rubber, it was found to increased efficiency to use SBR polymer only than to use the blending ratio CB/SBR=30/70 below. But it was observed that the latter was adapted for the bus or truck tyre and the former for the passenger tyre. 2. Excellent efficiency was obtained in case of carbon black compounding ratio of 55%, and also the compounding of ISAF made better efficiency than that of HAF. 3. Carbon black was more efficient to SBR than to CB. 4. For the aging ratio, the compounding rubber of NR was the highest, and the ratio was decreased in order of the compounding rubber of oil-extended SBR or CB polymer only, the compounding rubber of non oil-extended SBR or CB polymer only, and the blending rubber.

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Silk fibroin/hyaluronic acid blend sponge accelerates the wound healing in full-thickness skin injury model of rat (전층피부창상에서 실크피브로인과 하이알론산 혼합 스폰지의 창상치유효과)

  • Kang, Seuk-Yun;Roh, Dae-Hyun;Kim, Hyun-Woo;Yoon, Seo-Yeon;Kwon, Young-Bae;Kweon, HaeYong;Lee, Kwang-Gill;Park, Young-Hwan;Lee, Jang-Hern
    • Korean Journal of Veterinary Research
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    • v.46 no.4
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    • pp.305-313
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    • 2006
  • The primary goal of the wound healing is rapid wound closure. Recent advances in cellular and molecular biology have greatly expanded our understanding of the biologic processes involved in wound repair and tissue regeneration. This study was conducted to develop a new sponge type of biomaterial to be used for either wound dressing or scaffold for tissue engineering. We designed to make a comparative study of the wound healing effect of silk fibroin/hyaluronic acid (SF/HA) blend sponge in full-thickness dermal injury model of rat. Two full-thickness excisions were made on the back of the experimental animals. The excised wound was covered with either the silk fibroin (SF), hyaluronic acid (HA) or SF/HA (7 : 3 or 5 : 5 ratio) blend sponge. On the postoperative days of 3, 7, 10 and 14, the wound area was calculated by image analysis software. Simultaneously, the tissues were stained with Hematoxylin-Eosin and Masson's trichrome methods to measure the area of regenerated epithelium and collagen deposition. In addition, we evaluated the degree of the epithelial cell proliferation using immunohistochemistry for proliferating cell nuclear antigen (PCNA). We found that the half healing time ($HT_{50}$) of SF/HA blend sponge treated groups were significantly decreased as compared with either those of SF or HA treatment group. Furthermore, SF/HA blend sponges significantly increased the size of epithelialization and collagen deposition as well as the number of PCNA positive cells on epidermal basement membrane as compared with those of control treatment. Especially, the 5 : 5 ratio group of SF/HA among all treatment groups was most effective on wound healing rate and histological studies. These results suggest that SF/HA blend sponges could accelerate the wound healing process through the increase of epithelialization, collagen deposition and basal cell proliferation in full thickness skin injury.