• Title/Summary/Keyword: Bleached

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Improvement of Physical Properties of Paper by Esterification of Cellulose (셀룰로오스 에스테르화에 의한 종이의 강도변화)

  • 이명구;유재국
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.2
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    • pp.55-61
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    • 1998
  • This treatment was applied to bleached softwood kraft pulp handsheets in an effort to improve physical strength of paper. Paper strength was improved by esterification of cellulose and polycarboxylic acid. Because hydrogen bond of carboxyl group is stronger than that of hydroxyl group, polycarboxylic acid forms stronger hydrogen bond than cellulose does. 1,2,3,4,-cyclopentanetetracarboxylic acid (CPTA) and sodium dihydrogen phosphate ($NaH_2O_4$) were used as polycarboxylic acid and catalyst, respectively This reaction was confirmed by the weight gain of the handsheets, by FTIR spectrum and by changes in mechanical properties of sheets. Wet tensile strength was improved when handsheets were treated with polycarboxylic acid. However, tear strength and burst strength decreased.

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Influence of Conductivity and Anionic Trashes on Adsorption Behavior of Cationic Starches (전기전도도와 음이온성 트래쉬에 따른 양상전분의 흡착 거동변화)

  • 허동명;이학래
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.3
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    • pp.10-18
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    • 1999
  • The influence of simple electrolyte or anionic trashes on cationic starch adsorption was examined using deinked pulp and bleached thermomechniical pulp. Adsorbed amounts of cationic starches increased slightly , then decreased abruptly as the concentration of simple electrolyte increased. This phenomenon was discussed based on the compression of electrical double layer and conformation change of starch molecules. Also, the effect of the type of simple electrolytes on starch adsorption was examined and discussed. Addition of sodium slilicate increased starch adsorption since it increased surface charge density of fibers. On the other hand, addition of kraft lignin decreased cationic demand of the pulp slurries and adsorbed amounts of cationic starches. Nonionic surfactant did not show any significant effect on the cationic demand of pulp slurries. When simple electrolytes were added to the stock , grater adsorption or cationic starches was obtained with starches of lower degree of substitution . On t도 other hand, amount of adsorbed starches decreased for lower DS starches when the concentration of anionic trashes increased.

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Paper Properties Improvement by adding Microfibrillated Cellulose-Mineral Composites (Microfibrillated Cellulose (MFC)와 중질탄산칼슘 (GCC)로 구성된 복합충전제를 이용한 종이 물성 향상)

  • Lee, Jung Myoung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.2
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    • pp.83-90
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    • 2016
  • Increasing the amount of filler in paper is of high interest for paper industry while maintaining its key sheet quality properties. In this study, a MFC-GCC composite, made through a co-grinding NBSK (Northern bleached softwood kraft) pulp with a ground calcium carbonate (Intracarb 60), was used as a strength aid in paper in order to evaluate a potential cost reduction through filler increase without sacrificing paper quality. Hand-sheets were made of NBSK and/or eucalyptus pulp by using white water recirculation in a Tappi sheet former and was compared its properties without or with MFC additions at different filler levels. It was found that the MFC-GCC composite has a large surface area compared to the fiber, allowing the formation of more hydrogen bonds in the web, thus giving natural strength to the paper. Overall results are encouraging that the MFC-GCC composite allows papermaker to reduce basis weight and maintain critical sheet properties.

Sugar Extraction by Pretreatment and Soda Pulping from Cattail (Typhaceae) (2) Pulping Characteristics (부들의 전처리를 통한 당의 추출과 소다펄프화에 관한 연구 (2) 펄프화 특성)

  • Kim, Wan-Jung;Lee, Sung-Eun;Seo, Yung-Bum
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.3
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    • pp.14-21
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    • 2010
  • Three different species of cattails (Typha orientalis, Typha angustata, Typha latifolia) cultivated in South Korea were examined as raw materials for the production of pulp and paper. Soda pulping with anthraquinone was used for the stems and the leaves of cattail, separately. Addition of anthraquinone in soda pulping improved the yield greatly. Chemical components between three cattail species and within each species (leaves and stem) gave little differences. Average fiber length of the bleached cattail fibers was a little shorter than that of the HwBKP of Eucalyptus. Average fiber width of the cattail fibers was a half of that of the HwBKP. Compared to the HwBKP, cattail pulp gave higher breaking length, higher opacity, and better smoothness at equivalent freeness.

A Study on the Photofade of Graft Copolymer (Part I) -for variance of whiteness- (Graft 공중합물의 광퇴색에 관한 연구(제1보) -백색도 변화에 대하여-)

  • Cho Kyung Rae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.7 no.1
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    • pp.11-16
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    • 1983
  • Variance of whiteness after graft copolymerization of acrylonitrile, methylmethacrylate and acrylamide onto bleached cellulose using Ce(IV) salt as initiators and the effect of homopolymer on the grafted fibers by photo-irradiation were studied. Also, the development of Yellowing were determined after carbon-arc radiation in a Fade-o-meter. The results were as follows: (1) Variation of whiteness of grafted cellulose fibers were influenced by graft-ratio, Inorganic-Organic Balance (IOB) of functional group in used monomers and adhering homopolymers on the grafed fibers. (2) Yellowing was not affected by the concentration of Ceric Ammonium Nitrate directly during reaction (eg. 0.008>0.006>0.014 M).

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Characteristics of Paper making fiber with Synergism and Combined effect of Purified two major Cellulase Components Treatment (I. The effects of Cx components contents) (정제된 Cellulase 구성요소간 상승작용이 펄프섬유의 특성에 미치는 영향 (제1부 Cx 구성요소비에 의한 변화))

  • 김병현;신종순
    • Journal of the Korean Graphic Arts Communication Society
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    • v.16 no.3
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    • pp.157-170
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    • 1998
  • To investigate the most effective way of cellulase utilization on paper making process and the systematic way of how to combine its components for better use, purified two major cellulase were applied to bleached kraft pulp at various dosage in the refining process and estimated the synergism effect of each components in the characteristics of papermaking fiber. freeness was not changed by $C_1$ Component dosage but strongly increased by Cx Component dosage. Drop in fiber viscosity, increase in WQV, fiber shortening and fine generation was strongly influenced by Cx Component, it seems to be that Cx Component works a hydrogenate that breaks hydrogen bonding in fiber and enhances pooling effect of fiber. $C_1$ Component was little influenced these characteristics of fiber but considered to help to make fiber surface smooth.

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Growth and Maturation Period of Silvetia siliquosa in the Natural Population in Jindo, South Korea (한국 진도의 자연군락 뜸부기(Silvetia siliquosa)의 생장과 성숙 주기)

  • Hwang, Eun Kyoung;Yoo, Ho Chang;Ha, Dong Soo;Park, Chan Sun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.48 no.5
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    • pp.745-751
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    • 2015
  • The ecological characteristics of Silvetia siliquosa, an endangered brown alga, were investigated from January to December 2013 in Jindo, South Korea. The S. siliquosa population formed widespread patches on natural rock. Receptacles were observed from March to August when seawater temperatures ranged from 8-26℃. A maturation peak was detected in June, when seawater temperatures were 23.4℃. After embryo release, the alga bleached and only the discoidal holdfast remained after August. Developmental initiation of the thallus occurred at temperatures above 8℃, and receptacle formation required approximately 196 degree-days. This is the first study to examine a S. siliquosa population throughout the entire year in a natural habitat.

Ultraviolet Microscopic Study on Lignin Distribution in the Fiber Cell Wall of BCTMP

  • Yoon, Seung-Lak;Yasuo Kojina
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.1
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    • pp.61-66
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    • 2004
  • Bleached chemithermomechanical pulp (BCTMP) was produced from CTMP of Betula maximowicziana Regel by two staged ozone-hydrogen peroxide bleaching in order to improve the optical properties of high yield pulp. This pulp was used for the evaluation of optical properties improvement, chemical characteristics of lignin in fiber and the relationship between lignin and optical properties in fiber cell wall. Hydrogen peroxide treatment improved the brightness, but the post color number (PC No.). There was little improvement on optical properties by ozone treatment, but this could be improved more by using two staged ozone-hydrogen peroxide bleaching. The hydrogen peroxide treatment did not make any change on chemical characteristics of lignin in cell wall, but by ozone treatment, it was found that the non-aromatic conjugated structure was existed in the surface of cell wall, but this could be removed by hydrogen peroxide treatment in two staged ozone-hydrogen peroxide treatment. Therefore, the optical properties was significantly improved, due to the removal of non-aromatic conjugated structure.

Optical implementation of two-stage free-space interconnection network using hologram arrays (홀로그램 어레이를 이용한 2단 자유공간 광연결 구현)

  • 지창환;박진상;장주성;정신일
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.33A no.7
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    • pp.253-260
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    • 1996
  • In this paper, a simple scheme of two-stage free-space photonic swiching system for nonblocking optical interconnections has been investigated using holgorams. The multistage system requires a smaller number of interconnections for a given number of inpuut-output nonblocking ports than the single stage system does. Here hologram elements were used to change interconnection beam paths. In order to increase the idffraction efficiency of the hologram elements in photographic plates, a bleaching technique was used, which converts the amplitude hologram to the phase hologram. To show sthe feasibility of our optical interconnection system, it was implemented using the bleached hologram arrays and an LCTV spatial light modulator, and the sytem as a photonic switching system was demonstrated.

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Diffraction Efficiency Properties of Holographic Gratings by the Reversal Bleached on the Effect of Superadditivity (초부가성 효과에 의한 반전표백 홀로그래피 회절격자의 회절효율 특성)

  • Lim, Chun-Woo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.5
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    • pp.403-407
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    • 2010
  • This paper shows that the diffraction efficiency is influenced by superadditivity for the combination of the different developing agent and concentrations in the reversal bleach applied to the Slavich PFG-01 plate to be used for recording transmission holograms. The four developers based on ascorbic acid in combination with metol, phenidone, hydroquinone respectively, were studied. In diffraction efficiency aspect, the superadditivity effect of mixture of two developing agents is lower than one developing agent developer, AAC in the reversal bleach.