• Advances in concrete construction
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• v.16 no.3
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• pp.155-167
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• 2023

The penetrated chloride in concrete has different behavior with mix proportions and local exposure conditions, even in the same environments, so that it is very important to quantify surface chloride contents for durability design. As well known, the surface chloride content which is a key parameter like external loading in structural safety design increases with exposure period. In this study, concrete samples containing OPC (Ordinary Portland Cement), GGBFS (Ground Granulated Blast Furnace Slag), and FA (Fly Ash) had been exposed to submerged, tidal, and splash area for 5 years, then the surface chloride contents changing with exposure period were evaluated. The surface chloride contents were obtained from the chloride profile based on the Fick's 2nd Law, and the regression analysis for them was performed with exponential and square root function. After exposure period of 5 years in submerged and tidal area conditions, the surface chloride content of OPC concrete increased to 6.4 kg/m³ - 7.3 kg/m³, and the surface chloride content of GGBFS concrete was evaluated as 7.3 kg/m³ - 11.5 kg/m³. In the higher replacement ratio of GGBFS, the higher surface chloride contents were evaluated. The surface chloride content in FA concrete showed a range of 6.7 kg/m³ to 9.9 kg/m³, which was the intermediate level of OPC and GGBFS concrete. In the case of splash area, the surface chloride contents in all specimens were from 0.59 kg/m³ to 0.75 kg/m³, which was the lowest of all exposure conditions. Experimental constants available for durability design of chloride ingress were derived through regression analysis over exposure period. In the concrete with GGBFS replacement ratio of 50%, the increase rate of surface chloride contents decreased rapidly as the water to binder ratio increased.

• Advances in concrete construction
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• v.16 no.6
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• pp.303-316
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• 2023

Using industrial wastes and construction and demolition (C&D) wastes is potentially advantageous for concrete production in terms of sustainability improvement. In this paper, a sustainable Self-Compacting Concrete (SCC) made with industrial wastes and C&D wastes was proposed by considerably replacing natural counterparts with recycled coarse aggregates (RCAs) and supplementary cementitious materials (SCMs) (i.e., Fly ash (FA), ground granulated blast furnace slag (GGBS) and silica fume (SF)). A total of 12 SCC mixes with various RCAs and different combination SCMs were prepared, which comprise binary, ternary and quaternary mixes. The mechanical properties in terms of compressive strength and static elasticity modulus of recycled aggregates (RA-SCC) mixes were determined and analyzed. Microstructural study was implemented to analyze the reason of improvement on mechanical properties. By means of life cycle assessment (LCA) method, the environmental impacts of RA-SCC with various RCAs and SCMs were quantified, analyzed and compared in the system boundary of "cradle-to-gate". In addition, the comparison of LCA results with respect to mechanical properties was conducted. The results demonstrate that the addition of proposed combination SCMs leads to significant improvement in mechanical properties of quaternary RA-SCC mixes with FA, GGBS and SF. Furthermore, quaternary RA-SCC mixes emit lowest environmental burdens without compromising mechanical properties. Thus, using the combination of FA, GGBS and SF as cement substitution to manufacture RA-SCC significantly improves the sustainability of SCC by minimizing the depletion of cement and non-renewable natural resources.

• Journal of the Korea institute for structural maintenance and inspection
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• v.10 no.3
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• pp.97-105
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• 2006

The autogenous shrinkage of high-performance concrete is important in that it can lead the early cracks in concrete structures. The purpose of the present study is to explore the autogenous shrinkage of high-performance concrete with admixture and to derive a realistic equation to estimate the autogenous shrinkage model of that. For this purpose, comprehensive experimental program has been set up to observe the autogenous shrinkage for various test series. Major test variables were the type and contents of admixture and water-cement ratio is fixed with 30%. The autogenous shrinkage of HPC with fly ash slightly decreased than that of OPC concrete, but the use of blast furnace slag increased the autogenous shrinkage. Also, the autogenous shrinkage of HPC is found to decrease with increasing shrinkage reduction agent and expansive additive. A prediction equation to estimate the autogenous shrinkage of HPC with admixture was derived and proposed in this study. The proposed equation show reasonably good correlation with test data on autogenous shrinkage of HPC with mineral and chemical admixture.

• Computers and Concrete
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• v.34 no.2
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• pp.213-230
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• 2024

The use of waste tires and industrial wastes such as fly ash (FA) and ground granulated blast furnace slag (GGBS) in concrete is an important issue in terms of sustainability. In this study, the effect of parameters affecting the physical, mechanical and microstructural properties of FA/GGBS-based geopolymer concretes with waste rubber fiber was investigated. For this purpose, the effects of rubber fiber percentage (0.6%, 0.9%, 1.2%), binder (75FA25GGBS, 50FA50GGBS, 25FA75GGBS) and curing temperature (75 ℃, 90 ℃ and 105 ℃) were investigated. The Taguchi-Grey Relational Analysis (TGRA) method was used to obtain optimum parameter levels of rubber fiber geopolymer concrete (RFGC). The slump, fresh and hardened density, compressive strength, flexural strength, static and dynamic modulus of elasticity, ultrasonic pulse velocity (UPV) tests and scanning electron microscopy (SEM) analysis were performed on the produced concretes. The analysis of variance (ANOVA) method was used to statistically determine the effects of the parameters on the experimental results. A confirmation test was performed to test the accuracy of the optimum values found by the TGRA method. With the increase of GGBS percentage, the compressive strength of RFGC increased up to 196%. The increase in rubber fiber percentage and curing temperature adversely affected the mechanical properties of RFGC. As a result of TGRA, the optimum value was found to be A1B3C1. ANOVA results showed that the most effective parameter on the experimental results was the binder with 99% contribution percentage. It is understood from the SEM images that the optimum concrete had a denser microstructure and less capillary cracks and voids. For this study, the use of the TGRA method in multiple optimization has proven to provide very useful and reliable results. In cases where many factors are effective on its strength and durability, such as geopolymer concrete, using the TGRA method allows for finding the optimum value of the parameters by saving both time and cost.

• Journal of the Korea Concrete Institute
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• v.29 no.4
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• pp.415-424
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• 2017

The purpose of this study is to investigate the effect of sulfate (${SO_4}^{2-}$) and magnesium ($Mg^{2+}$) ions on sulfate resistance of Alkali-activated materials using Fly ash and Ground granulated blast furnace slag (GGBFS). In this research, 30%, 50% and 100% of GGBFS was replaced by sodium silicate modules ($Ms(SiO_2/Na_2O)$, molar ratio, 1.0, 1.5 and 2.0). In order to investigate the effects of $Mg^{2+}$ and ${SO_4}^{2-}$, compression strength, weight change, lengh expansion of the samples were measured in 10% sodium sulfate ($Na_2SO_4$), 10%, 5% and 2.5% magnesium sulfate ($MgSO_4$), 10% magnesium nitrate ($Mg(NO_3)_2$), 10% [magnesium chloride ($MgCl_2$) + sodium sulfate ($Na_2SO_4$)] and 10% [magnesium nitrate $(Mg(NO_3)_2$ + sodium sulfate ($Na_2SO_4$)] solution, respectively and X-ray diffraction analysis was conducted after each experiment. As a result, when $Mg^{2+}$ and ${SO_4}^{2-}$ coexist, degradation of compressive strength and expansion of the sample were caused by sulfate erosion. It was found that the reaction of $Mg^{2+}$ with Calcium Silicate Hydrate (C-S-H) occurred and $Ca^{2+}$ was produced. Then the Gypsum ($CaSO_4{\cdot}2H_2O$) was formed due to reaction between $Ca^{2+}$ and ${SO_4}^{2-}$, and also Magnesium hydroxide ($Mg(OH)_2$, Brucite) was produced by the reaction between $Mg^{2+}$ and $OH^-$.

• Journal of the Korea Concrete Institute
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• v.17 no.1 s.85
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• pp.129-137
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• 2005

In Korea, due to the insufficiency of natural aggregates and increasing needs of crushed stones, it is necessary to examine the alkali-silica reaction of the crushed stones. The reaction produces an alkali-silica reaction gel which can imbibe pore solution and swell to generate cracks that are visible In affected concrete. In general, crushed stones are tested by petrograptuc examination, chemical method and mortar-bar method, but the most reliable method Is mortar-bar test. This study tested alkali-silica reactivity of crushed stones of various rock types using ASTM C 227 and C 1260, and compared the results of two test methods. This study also analyzed effects of particle size and grading of reactive aggregate on alkali-silica reaction expansion of mortar-bar. The effectiveness of mineral admixtures to reduce detrimental expansion caused by alkali-silica reaction was investigated through the ASTM C 1260 method. The mineral admixtures used were nv ash, silica fume, metakaolin and ground granulated blast furnace slag. The replacement ratios of 0, 5, 10, 15, 25 and $35\%$ were commonly applied for all the mineral admixtures and the replacement ratios of 45 and $55\%$ were additional applied for the admixtures that could maintain workability. The results indicate that replacement ratios of $25\%$ for ay ash, $10\%$ for silica fume, $25\%$ for metakaolin or $35\%$ for ground granulated blast furnace slag were most effective to reduce alkali-silica reaction expansion under the experimental conditions.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.1
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• pp.109-116
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• 2017

This paper describes the investigation into the durability alkali-activated materials(AAM) mortar and paste samples manufactured using fly-ash(FA) and ground granulated blast furnace slag(GGBFS) exposed to a sulfate environment with different GGBFS replace ratios(30, 50 and 100%), sodium silicate modules($Ms[SiO_2/Na_2O]$ 1.0, 1.5 and 2.0). The tests involved immersions into 10% sodium sulfate solution($Na_2SO_4$), 10% magnesium sulfate solution($MgSO_4$), 10% magnesium nitrate solution($Mg(NO_3)_2$) and 5% magnesium nitrate($Mg(NO_3)_2$+5% sodium sulfate solution+$Na_2SO_4$). The evolution of compressive strength, weight, length expansion and microstructural observation such as x-ray diffraction were studied. As a results, in case of immersed in $Na_2SO_4$, $Mg(NO_3)_2$ and $Mg(NO_3)_2+Na_2SO_4$ shows increase in long-term strength. However, for samples immersed in $MgSO_4$, the general observation was that the compressive strength decreased after immersion. The most drastic reduction of compressive strength and expansion of weight and length occurred when GGBFS or Ms ratios were higher. Also, the XRD analysis of samples immersed in magnesium sulfate indicated that expansion of AAM caused by gypsum($CaSO_4{\cdot}2H_2O$) and brucite(MgOH). The results showed that, an additional condition $Mg^{2+}$ in which ${SO_4}^{2-}$ is the presence of a certain concentration, sulfate erosion has to be accelerated.

• Journal of the Korea Concrete Institute
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• v.27 no.2
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• pp.127-136
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• 2015

To evaluate the effects of limestone powder and silica fume on the properties of high-strength high-volume ground granulated blast-furnace slag (GGBFS) blended cement concrete, this study investigated the rheology, strength development, hydration and pozzolanic reaction characteristics, porosity and pore size distribution of high-strength mortars with the water-to-binder ratio of 20, 50 to 80% GGBFS, up to 20% limestone powder, and up to 10% silica fume. According to test results, compared with the Portland cement mixture, the high-volume GGBFS mixture had much higher flow due to the low surface friction of GGBFS particles and higher strength in the early age due to the accelerated cement hydration by increase of free water; however, because of too low water-to-binder ratio and cement content, and lack of calcium hydroxide content, the pozzolanic reactio cannot be activated and the long-term strength development was limited. Limestone powder did not affect the flowability, and also accelerate the early cement hydration. However, because its effect on the acceleration of cement hydration is not greater than that of GGBFS, and it does not have hydraulic reactivity unlikely to GGBFS, compressive strength was reduced proportional to the replacement ratio of limestone powder. Also, silica fume and very fine GGBFS lowered flow and strength by absorbing more free water required for cement hydration. Capillary porosities of GGBFS blended mortars were smaller than that of OPC mortar, but the effect of limestone powder on porosity was not noticeable, and silica fume increased porosity due to low degree of hydration. Nevertheless, it is confirmed that the addition of GGBFS and silica fume increases fine pores.

• Korean Journal of Mineralogy and Petrology
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• v.35 no.1
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• pp.25-39
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• 2022

This study was conducted to evaluate the manufacturing process of non-sintered cement for the safe containment of radioactive waste using low level or ultra-low level radioactive waste soil generated from nuclear-decommissioning facilities, clay minerals, and blast furnace slag (BFS) as an industrial by-product recycling and to characterize the products using mineralogical and morphological analyses. A stepwise approach was used: (1) measuring properties of source materials (reactants), such as waste soil, clay minerals, and BFS, (2) manufacturing the non-sintered cement for the containment of radioactive waste using source materials and deducing the optimal mixing ratio of solidifying and adjusting agents, and (3) conducting mineralogical and morphological analyses of products from the hydration reactions of manufactured non-sintered cement solidifier (NSCS) containing waste concrete generated from nuclear-decommissioning facilities. The analytical results of NSCS using waste soil and clay minerals confirmed none of the hydration products, but calcium silicate (CSH) and ettringite were examined as hydration products in the case of using BFS. The compressive strength of NSCS manufactured with the optimum mixing ratio and using waste soil and clay minerals was 3 MPa after the 28-day curing period, and it was not satisfied with the acceptance criteria (3.44 MPa) for being brought in disposal sites. However, the compressive strength of NSCS using BFS was estimated to be satisfied with the acceptance criteria, despite manufacturing conditions, and it was maximized to 27 MPa at the optimal mixing ratio. The results indicate that the most relevant NSCS for the safe containment of radioactive waste can be manufactured using BFS as solidifying agent and using waste soil and clay minerals as adsorbents for radioactive nuclides.

• Journal of the Korea Concrete Institute
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• v.21 no.1
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• pp.55-64
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• 2009

This study is aimed to derive the optimum mix proportion of the combined self compacting concrete according to cement types (blast-furnace slag cement and belite cement) and to propose the basic data to field construction work after evaluating the quality properties. Specially, lime stone powder (LSP) as binder and viscosity agent are used in the combined self compacting concrete because slurry wall of an underground LNG storage tank should be kept stability of quality during concrete working. Replacement ratio of LSP is determined by confined water ratio test and main design factors including fine aggregate ratio ($S_r$), coarse aggregate ratio ($G_v$) and water-cement ratio (W/C) are selected. Also, quality properties including setting time, bleeding content, shortening depth and hydration heat on the optimum mix proportion of the combined self compacting concrete according to cement type are compared and analyzed. As test results, the optimum mix proportion of the combined self compacting concrete according to cement type is as followings. 1) Slag cement type-replacement ratio of LSP 13.5%, $S_r$ 47% and W/C 41%. 2) Belite cement type-replacement ratio of LSP 42.7%, Sr 43% and W/C 51%. But optimum coarse aggregate ratio is 53% regardless of cement types. Also, as test results regarding setting time, bleeding content, shortening depth and hydration heat of the combined self compacting concrete by cement type, belite cement type is most stable in the quality properties and is to apply the actual construction work.