• Applied Chemistry for Engineering
• /
• v.9 no.6
• /
• pp.835-841
• /
• 1998

This study was devoted to the manufacturing process of activated carbon(AC) using and anthracite and bituminous coals which were regarded as appropriate for AC manufacturing, and the physcial properties a AC prepared with coal blends were characterized by the ultimate and proximate analysis. Generally, as the fraction of antheracite in AC from anthracite and bituminous coal blends was increased, AC yield was increased whereas iodine value($I_2$) was decreased. Being not related to mixing ratio of coal blends, the apparent density of AC remained constant. Pore development and iodine value of AC based on coal blends(Fushun and Dandong, 75:25 wt. %) were examined, varing carbonization and steam activation conditions. These results showed that the average pore diameter of AC was below $20{\AA}$ in the activation temperature range of 850 to $900^{\circ}C$ and the iodine value was above $1000m^2/g$. When the adsorption capacity of manufactured AC was compared with commercial AC, it is found that the AC from coal blends was comparable to the commercial AC. Therefore, it was confirmed that the characteristics of manufactured AC were changed with manufacturing conditions and the ratios and types of coal blends.

• KSBB Journal
• /
• v.11 no.2
• /
• pp.238-245
• /
• 1996

Microbial desulfurization characterlstics of a bituminous coal have been determined by using Thiobacillus ferrooxidans. The effects of process variables (such as coal pulp density, particle size and addition of surfactants) on pyrite removal have been investigated in both shake and airlift-bioreactor culture experiments. In shake experiments, pyrite could be removed over 78% for pulp densifies below 20% (w/v) and removed below 40% for pulp densities over 30% (w/v) in 8 days. Pyrite removal decreased with increasing pulp densities, and it also decreased sharply with increasing particle sizes. In airlift bioreactor experiments, pyrite at 50% (w/v) pulp density could be removed about 50%. Its value is much higher than 15% at the same pulp density in a shake experiment. With addition of surfactants, pyrite removal was enhanced in shake experiments significantly, whereas it was slightly decreased in an airlift bioreactor experiment.

• Journal of Energy Engineering
• /
• v.18 no.3
• /
• pp.191-202
• /
• 2009

South Korea, ranks 10th largest emitter of carbon dioxide in the world, will probably be under the obligation to reduce GHG emission from 2013. It is very important to reduce the electrical energy consumption since 30% of GHG emission in South Korea is made during electricity generation. In this study, based on "the 1st national energy master plan", the GHG emission reduction potential and the feasibility of the scenario in the electricity generation have been analyzed using LEAP(Long-range Energy Alternative Planning system). The scenario of the mater plan contains the 41% expansion of nuclear power plant facilities and the 11% diffusion of renewable energy until 2030. In result, total $CO_2$ emission reduction rate is 28.8% in 2030. Also $CO_2$ emission of unit electricity generation of bituminous coal power plant is $0.85kgCO_2/kWh$ and its LNG power plant is $0.51kgCO_2/kWh$ in BAU scenario. Therefore when existing facilities is exchanged for nuclear or renewable energy power plant, substitute of bituminous power plant is more effective than LNG power.

• Journal of Energy Engineering
• /
• v.6 no.2
• /
• pp.176-187
• /
• 1997

As a way to evaluate the performance of IGCC (Integrated Gasification Combined Cycle) processes, heating values of coal gas as well as plant efficiency were compared for different rank coals and coal feeding methods by employing the static process simulation technique. Performance of the process was compared with coal rank that was varied by three assorted bituminous coals and also by three subbituminous coals, in addition to the two types of feeding techniques, i.e., dry-feeding and slurry-feeding, that are utilized in entrained-bed coal gasifiers. For the verification of the simulation technique, simulated results were compared first with the actual pilot plant data published from Shell and Texaco. The simulation technique was, then, applied to other coals. Result from tests varying coal rank exhibits the trend of improving both heating content of the product gas and plant efficiency with increasing carbon content in coal. The effect of coal rank is more sensitive in slurry-feeding cases compared to the dry-feeding cases. In particular, considering notably lower values in gas heating value and plant efficiency calculated in the slurry-feeding case that uses a subbituminous coal, limited utilization of the slurry-feeding method for subbituminous coals can be expected. From the plant efficiency point of view, dry-feeding method resulted in higher simulated efficiency values by maximum 3% for subbituminous coals and ca. l% for bituminous coals.

• Journal of Energy Engineering
• /
• v.22 no.2
• /
• pp.96-104
• /
• 2013

Coal gasification is considered as one of the best alternatives among clean coal technology and new concept next generation technologies are under being developed to achieve low cost as well as high efficiency. In this study we have developed double swirl multi-burner as part of the development of low cost compact gasifier. We installed new concept multi-burner with pulverized coal distributor to the body of existing gasifier for burner test. Gasification test was performed under the condition of $6.4{\sim}7.2kg/cm^2$ and $1170{\sim}1300^{\circ}C$ by using Indonesian ABK (sub-bituminous) coal to get operation condition of new concept multi-burner. Our interest was focused to ensure a stable operating condition rather than the gasifier performance evaluation. As a result, we were able to achieve the carbon conversion of 84% and the cold gas efficiency of 52.1% at the stable operating conditions.

• Journal of Korean Society of Environmental Engineers
• /
• v.27 no.4
• /
• pp.445-449
• /
• 2005

Present study was designed to evaluate the practical application of triethyl amine(TEA) injection for improving the collection efficiency of electrostatic precipitator(ESP) connected to a real operating plant. The major fuels used at the domestic power stations were bituminous coals imported from Australia, China, South Africa, and USA. Although the values of the electric resistance would be more or less different according to the type of the coals used, the unique electric resistance values of fly ash from the coals were mostly higher than $1{\times}10^{12}\;{\Omega}-cm$ and therefore, back corona problems were always expected to occur in the electrostatic precipitator. The particulates concentrations, smoke concentrations and their electric resistivity measured at the outlet of ESP, and the inspection of collection indicated that the injection of TEA improved the collection efficiency of particulate at collection plates of ESP. The electric resistance for, fly ash with the injection concentration of TEA 15 ppm(Purity 99.7%) was lowered to $2.1{\times}10^{11}\;{\Omega}-cm$ after injection from $1.9{\times}10^{12}\;{\Omega}-cm$ before injection. Under this condition, the dust emission content at the stack was reduced to approximately 80%, lowering the average outlet concentrations of particulates from $70\;mg/Sm^3$ to $14\;mg/Sm^3$.

• Korean Chemical Engineering Research
• /
• v.48 no.1
• /
• pp.80-87
• /
• 2010

Lignite of low rank coal and petroleum coke of high sulfur content can be high potential energy sources for coal gasification process because of their plentiful supply. The kinetic study of steam gasification has been performed in an atmospheric thermobalance with wood chip, lignite, bituminous, anthracite, pet-coke. The effects of gasification temperature($600{\sim}850^{\circ}C$) and partial pressure of steam(30~90 kPa) on the gasification rate have been investigated. The modified volumetric reaction model was applied to the experimental data to describe the behavior of carbon conversion and to evaluate the needed kinetic parameters. Lignite and wood chip with high volatile content showed high average gasification rates comparing to other fuel and thus they might be proper fuel for gasification processes. The activation energies for wood chip, lignite, bituminous, anthracite, and pet-coke through Arrhenius plot were found to be 260.3, 167.9, 134.6, 82.2, 168.9 kJ/mol, respectively. The expression of apparent reaction rates for steam gasification of various chars have been proposed as basic information for the design of coal gasification processes.

• Korean Chemical Engineering Research
• /
• v.51 no.1
• /
• pp.121-126
• /
• 2013

The objective of this research is to predict the TG curve of blends of bituminous coal and sub-bituminous coal during devolatilization. TSL (Thermal Shock Large) TGA was used for Experiments, and Coats-redfern method was used for reaction order calculation. Based on reaction order, sum method was verified to be suitable for a single coal, then, prediction and comparison of TG curve of coal blends was conducted using both of WSM (Weight Sum Method) and MWSM (Modified Weight Sum Method), where the latter was developed in this research. The presented experiment results and WSM & MWSM were showed to be reasonable using linear least square method. MWSM performed more accurately than WSM for the case that TG curve had different slopes and the case that sharp weight loss happened due to release of volatile matter. The results showed that it's possible to predict the thermal behavior of coal blends during devolatilization based on the thermal behavior of single coals.

• Journal of the Korean GEO-environmental Society
• /
• v.11 no.5
• /
• pp.25-34
• /
• 2010

In this study characteristics for reclaimed ash was studied to enlarge the usage of reclaimed ash which is reaching to 72 million ton producted from whole thermal power plants in South Korea. Fly ash and bottom ash are reclaimed separately at some of thermal power plants. However, typically bottom ash and fly ash are mixed when they are buried at most of the thermal power plant, as a result the engineering characteristics of ponded ash are not investigated properly. In order to investigate the engineering characteristics of the ponded ash, laboratory tests were performed with ponded ash and fly ash from youngheung and samcheonpo thermal power plants. Specific gravity, unit weight, and grain size analysis test were fulfilled to evaluate the physical characteristics and triaxial permeability test, direct shear test, unconfined compressive strength test, compaction test were performed to evaluate the mechanical characteristics. And also engineering characteristics of coal ash from anthracite and Bituminous thermal power plants were compared and studied respectively. As a result of the study, it was confirmed that using coal ash from Bituminous thermal power plants can be effective in the place where lightweight materials are required and using coal ash from anthracite thermal power plants can be effective as backfill material which require higher permeability. Finally, it was confirmed that fly ash from youngheung thermal power plants which has the lowest permeability among the tested material is suitable for a field requiring impermeable material.

• Clean Technology
• /
• v.21 no.1
• /
• pp.53-61
• /
• 2015

In this study, we have investigated the kinetics on the char-CO₂ catalytic gasification reaction. Thermogravimetric analysis (TGA) experiments were carried out for char-CO₂ catalytic gasification of an Indonesian Kideco sub-bituminous. Na₂CO₃ and K₂CO₃ were selected as catalysts which were physically mixed with coal. The char-CO₂ catalytic gasification reaction showed a rapid increase of carbon conversion rate at 850 ℃, 60 vol% CO₂, and 7 wt% Na₂CO₃. At the isothermal conditions ranging from 750 ℃ to 900 ℃, the carbon conversion rates increased as the temperature increased. Four kinetic models for gas-solid reaction including the shrinking core model (SCM), random pore model (RPM), volumetric reaction model (VRM), and modified volumetric reaction model (MVRM) were applied to the experimental data against the measured kinetic data. The gasification kinetics were suitably described by the MVRM for the Kideco sub-bituminous. The activation energies for each char mixed with Na₂CO₃ and K₂CO₃ were found 55-71 kJ/mol and 69-87 kJ/mol.