• 제목/요약/키워드: Bipolar Electrode

검색결과 96건 처리시간 0.028초

실리콘으로 제작된 소형 연료 전지에서 가습 조건의 최적화 (Humidification Optimization in Silicon-based Miniaturized Fuel Cell)

  • 권오중;원호연;김재정
    • 전기화학회지
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    • 제10권2호
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    • pp.104-109
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    • 2007
  • 연료 전지의 소형화를 위하여 흑연(graphite)를 기본으로 하는 분리판을 실리콘분리판으로 대체하였으며, 실리콘 분리판과 active area가 $4cm^2$인 MEA (membrane electrode assembly)와 결합하여 단위 전지를 제작하였다. 단위 전지에 공급되는 수소와 산소의 공급량은 고정하고 가습기의 구동 온도만을 변화시키면서 단위 전지의 성능을 확인하고 최적의 가습 조건을 결정하였다. 또한 가습 조건이 실리콘으로 제작된 연료 전지 스택에 미치는 영향을 알아보기 위하여 실리콘 분리판과 2개의 MEA로 이루어진 스택을 제작하여 가습 조건의 영향을 알아보고 실리콘 분리판으로 제작된 연료전지 스택의 문제점 및 특징을 알아보았다.

착용형 심장활동 모니터링 시스템을 활용한 정신적 스트레스 평가 (The Assessment of Dynamic Mental Stress with Wearable Heart Activity Monitoring System)

  • 김경섭;신승원;이정환;최희정
    • 전기학회논문지
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    • 제57권6호
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    • pp.1109-1115
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    • 2008
  • In the ubiquitous health monitoring environments, it is quite important not only to evaluate the physiological health condition but also mental stress condition. In order to achieve this goal, a heart activity monitoring system utilizing a wearable bipolar electrode is devised and the heart rate variability(HRV) is extracted and interpreted in both frequency and time feature domains. Consequently, to evaluate the emotional stress condition of the subjects, a stress-induced experimental protocol was applied to healthy subjects and the time and frequency features of heart activity were analyzed in terms of the ratio of low frequency components v.s., high frequency components and the relevant the moving average distributions compromising the successive RR peaks intervals in the ambulatory ECG measurement system.

고분자 전해질 막 연료전지에서의 아이오딘이 코팅된 분리판의 성능 효과 (Effect of Iodine-coated Bipolar Plates on the Performance of a Polymer Exchange Membrane (PEM) Fuel Cell)

  • 김태언;전소미;조광연;설용건
    • 한국수소및신에너지학회논문집
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    • 제24권1호
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    • pp.61-69
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    • 2013
  • Polymer exchange membrane (PEM) fuel cells have multifunctional properties, and bipolar plates are one of the key components in these fuel cells. Generally, a bipolar plate has a gas flow path for hydrogen and oxygen liberated at the anode and cathode, respectively. In this study, the influence of iodine applied to a bipolar plate was investigated. Accordingly, we compared bipolar plates with and without iodine coating, and the performances of these plates were evaluated under operating conditions of $75^{\circ}C$ and 100% relative humidity. The membrane and platinum-carbon layer were affected by the iodine-coated bipolar plate. Bipolar plates coated with iodine and a membrane-electrode assembly (MEA) were investigated by electron probe microanalyzer (EPMA) and energy-dispersive x-ray spectroscopy (EDS) analysis. Polarization curves showed that the performance of a coated bipolar plate is approximately 19% higher than that of a plate without coating. Moreover, electrochemical impedance spectroscopy (EIS) analysis revealed that charge transfer resistance and membrane resistance decreased with the influence of the iodine charge transfer complex for fuel cells on the performance.

PEMFC용 금속분리판 코팅 기술 개발 : II. 코팅 금속분리판 연료전지 성능 특성 연구 (Development of Surface Coating Technology for Metallic Bipolar Hate in PEMFC : II. Study on the PEMEC Performance of Coated Metallic Bipolar Plate)

  • 윤용식;정경우;양유창;안승균;전유택;나상묵
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 추계학술대회
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    • pp.352-355
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    • 2006
  • As the stainless steel has good corrosion resistance, mechanical property and ease of manufacture, it has been studied as the candidate material of metallic bipolar plate for automotive PIMFC. But, metal is dissolved under fuel cell operating conditions Dissolved ions contaminate a membrane electrode assembly (MEA) and, decrease the fuel cell performance. In addition, metal oxide formation on the surface of stainless steel increases the contact resistance in the fuel cell. These problems have been acted as an obstacle in the application of stainless steel to bipolar plate. Therefore, many kinds of coating technologies have been examined in order to solve these problems. In this study, stainless steel was coated in order to achieve high conductivity and corrosion resistance by several methods. Contact resistance was measured by using a tensile tester and impedance analyzer Corrosion characteristics of coated stainless steel were examined by Tafel-extrapolation method from the polarization curves in a solution simulating the anodic and cathodic environment of PEMFC. Fuel cell performance was also evaluated by single cell test. We tested various coated metal bipolar plate and conventional and graphite were also tested as comparative samples. In the result, coated stainless steel bipolar plate exhibited better cell performance than graphite to bipolar plate.

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양극고주파전극과 냉동프로브를 이용한 지속성 심방세동의 수술 결과 - 절개/봉합술식과 비교 - (Result of Cox Maze Procedure with Bipolar Radiofrequency Electrode and Cryoablator for Persistent Atrial Fibrillation - Compared with Cut-sew Technique -)

  • 이미경;최종범;이정문;김경화;김민호
    • Journal of Chest Surgery
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    • 제42권6호
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    • pp.710-718
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    • 2009
  • 배경: Cox maze 수술은 거의 20년 가까이 심방세동의 표준적인 외과적 치료방법으로 이용되었다. 최근 저자들은 Cox maze 수술에서 대부분의 절개선을 양극고주파전극(Cox maze IV procedure)으로 대치하였다. 저자들은 지속성 심방세동의 수술적 치료에 양극고주파전극을 이용한 Cox maze 수술의 결과를 조사하고 절개-봉합법을 이용한 Cox maze III 수술의 결과와 비교하였다. 대상 및 방법: 2005년 4월부터 2007년 7월까지 40명의 환자가 양극고주파전극으로 Cox maze 수술을 받았다. 그 결과를 절개-봉합법으로 수술 받은 35예의 결과와 비교하였다. 모두 다른 심장수술과 함께 심방세동 수술을 받았으며, 수술 후 1내지 2개월마다 추적 조사하였다. 결과: 수술 후 6개월에 정규리듬의 전환율은 양극고주파전극방법과 절개-봉합방법 사이에 차이가 없었고(95.0%/97.1%, p=1.0), 마지막 추적시간까지 정규리듬 전환율도 차이가 없었다(92.5%/91.6%, p=1.0). 다변량 분석(Cox-regression)으로 양극고주파군에서 심방세동의 지속 및 재발의 위험인자는 수술 후 좌심방의 내경이었고(hazard ratio 31, p=0.005), 양군 전체의 환자에서 수술 후 심방세동의 지속 및 재발의 위험인자(Cox-regression)는 수술 6개월에 심방세동의 출현(hazard ratio 92.24, p=0.003)과 수술 후 좌심방의 내경(hazard ratio 16.05, p=0.019)이었다. 대동맥차단시간과 체외순환시간은 양극고주파전극군에서 더 짧았다. 결론: Cox maze 수술 시 양극고주파전극의 사용은 절개-봉합법과 같이 우수한 정규리듬 전판율을 보이며, 수술 후 좌심방의 크기가 심방세동의 지속 및 재발에 영향을 주는 독립인자였다.

전해응집공정을 이용한 염색폐수의 처리 (The Treatment of Textile Wastewater by Electrocoagulation Process)

  • 이용택;한승우;조영개;이현문;김태근;손인식;양병수
    • 한국환경과학회지
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    • 제9권4호
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    • pp.359-363
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    • 2000
  • This research studied the characteristics and applicability of electrocoagulation using aluminium electrode for the color and COD removal in textile wastewater. Electrocoagulation reactor used two different electrode, Fe and Al, since in the general chemical wastewater treatment, aluminium and ferrous salts were used as coagulants. Aluminium electrode showed higher removal efficiency of color and COD than ferrous electrode did. The COD and color removal efficiency improved at the 0.192A/$dm^2$ current density. Thus, the electrocoagulation process with bipolar aluminium electrode showed better efficiency in the decolorization and COD removal rate of textile wastewater effluent than custom coagulants did.

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ECR-MOCVD를 이용하여 연료 전지 분리판에 코팅된 FTO막의 특성 연구 (Characteristics of Fluorine-Doped Tin Oxide Film Coated on SUS 316 Bipolar Plates for PEMFCs)

  • 박지훈;;전법주;변동진;이중기
    • 한국수소및신에너지학회논문집
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    • 제22권3호
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    • pp.283-291
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    • 2011
  • Polymer electrolyte membrane fuel cells (PEMFCs) use the bipolar plate of various materials between electrolyte and contact electrode for the stable hydrogen ion exchange activation. The bipolar plate of various materials has representatively graphite and stainless steel. Specially, stainless steels have advantage for low cost and high product rate. In this study, SUS 316 was effectively coated with 600 nm thick F-doped tin oxide (SnOx:F) by electron cyclotron resonance-metal organic chemical vapor deposition and investigated in simulated fuel cell bipolar plates. The results showed that an F-doped tin oxide (SnOx:F) coating enhanced the corrosion resistance of the alloys in fuel cell bipolar plates, though the substrate steel has a significant influence on the behavior of the coating. Coating SUS 316 for fuel cell bipolar plates steel further improved the already excellent corrosion resistance of this material. After coating, the increased ICR values of the coated steels compared to those of the fresh steels. The SnOx:F coating seems to add an additional resistance to the native air-formed film on these stainless steels.

열전달 및 열하중을 고려한 자동차 연료전지(PEMFC) 분리판의 두께 최적설계 (Optimization of Automotive PEMFC Bipolar Plates considering Heat Transfer and Thermal Loads)

  • 김영성;김철
    • 한국자동차공학회논문집
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    • 제23권1호
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    • pp.34-40
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    • 2015
  • A stack in the proton exchange membrane fuel cell (PEMFC) consists of bipolar plates, a membrane electrode assembly, a gas diffusion layer, a collector and end plates. High current density is usually obtainable partially from uniform temperature distribution in the fuel cell. A size optimization method considering the thermal expansion effect of stacked plates was developed on the basis of finite element analyses. The thermal stresses in end, bipolar, and cooling plates were calculated based on temperature distribution obtained from thermal analyses. Finally, the optimization method was applied and optimum thicknesses of the three plates were calculated considering both fastening bolt tension and thermal expansion of each unit cell (72 cells, 5kW). The optimum design considering both thermal and mechanical loads increases the thickness of an end plate by 0.64-0.83% the case considering only mechanical load. The effect can be enlarged if the number of stack increases as in an automotive application to 200-300 stacks.

Utilization of Waste Aluminium Foil as a Sacrificial Electrode for the Treatment of Wastewater

  • Perumalsamy, Rajagopal;Kumaran, Chithra;Rajamanickam, Vaishali
    • Journal of Electrochemical Science and Technology
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    • 제12권1호
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    • pp.92-100
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    • 2021
  • In this study, the use of waste food grade aluminium foil and mild steel as a sacrificial electrode in an electrocoagulation system was developed to remove reactive red 111 from wastewater. The effect of different parameters like pH, current density, electrode material, and different electrode configurations was investigated. Optimum operating conditions for maximum COD removal were determined as, 6 mA/㎠ current density and 30 min at 5 pH for aluminium foil and 7 pH for mild steel. Maximum COD reduction obtained at optimum conditions using monopolar 4 electrodes, monopolar 2 electrodes and bipolar electrode configuration were 96.5%, 89.3%, and 90.2% for Mild steel as a sacrificial electrode and 92.1%, 84.2%, and 88.6% for aluminium foil as a sacrificial electrode. The consumption of electrode and energy for both the electrodes of different configurations were calculated and compared. Using batch experimental data, a continuous-flow reactor was developed. Sludge analysis using Fourier Transform Infra-Red Spectroscopy (FTIR) analysis was done. Different adsorption kinetic models and isotherms were developed and it was found that pseudo second-order model and Langmuir isotherm fit best with the experimental data obtained.

플로우팅 전극과 보조 게이트를 이용하여 스냅백을 없앤 애노드 단락 SOI LIGBT의 수치 해석 (Numerical Analyses on Snapback-Free Shorted-Anode SOI LIGBT by using a Floating Electrode and an Auxiliary Gate)

  • 오재근;김두영;한민구;최연익
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제49권2호
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    • pp.73-77
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    • 2000
  • A dual-gate SOI SA-LIGBT (shorted-anode lateral insulated gate bipolar transistor) which eliminates the snapback effectively is proposed and verified by numerical simulation. The elimination of the snapback in I-V characteristics is obtained by initiating the hole injection at low anode voltage by employing a dual gate and a floating electrode in the proposed device. For the proposed device, the snapback phenomenon is completely eliminate, while snapback of conventional SA-LIGBT occurs at anode voltage of 11 V. Also, the drive signals of two gates have same polarity by employing the floating electrode, thereby requiring no additional power supply.

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