• Title/Summary/Keyword: Biomass Combustion

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Conversion of organic residue from solid-state anaerobic digestion of livestock waste to produce the solid fuel through hydrothermal carbonization

  • Yang, Seung Kyu;Kim, Daegi;Han, Seong Kuk;Kim, Ho;Park, Seyong
    • Environmental Engineering Research
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    • v.23 no.4
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    • pp.456-461
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    • 2018
  • The solid-state anaerobic digestion (SS-AD) has promoted the development and application for biogas production from biomass which operate a high solid content feedstock, as higher than 15% of total solids. However, the digested byproduct of SS-AD can be used as a fertilizer or as solid fuel, but it has serious problems: high moisture content and poor dewaterability. The organic residue from SS-AD has to be improved to address these problems and to make it a useful alternative energy source. Hydrothermal carbonization was investigated for conversion of the organic residue from the SS-AD of livestock waste to solid fuels. The effects of hydrothermal carbonization were evaluated by varying the reaction temperatures within the range of $180-240^{\circ}C$. Hydrothermal carbonization increased the calorific value through the reduction of the hydrogen and oxygen contents of the solid fuel, in addition to its drying performance. Therefore, after the hydrothermal carbonization, the H/C and O/C atomic ratios decreased through the chemical conversion. Thermogravimatric analysis provided the changed combustion characteristics due to the improvement of the fuel properties. As a result, the hydrothermal carbonization process can be said to be an advantageous technology in terms of improving the properties of organic waste as a solid-recovered fuel product.

Recent developments in liquid-phase synthesis and applications of nanomagnesia

  • Hanie Abdollahzade;Asghar Zamani
    • Advances in nano research
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    • v.14 no.1
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    • pp.103-115
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    • 2023
  • Recent developments in the synthesis of nanomagnesia of controlled sizes and shapes that are suitable for various applications are reviewed. Two main methods, based on liquid-phase synthesis, i.e., chemical methods and bio-based methods, are used to synthesize nanomagnesia. Conventionally, nanomagnesia was synthesized by chemical methods such as coprecipitation, sol-gel, combustion method, and so on using different chemical agents and stabilizers which later on become responsible for several biological risks because of the toxicity of used chemicals. Bio-based protocols are growing as another environmental friend method for the synthesis of various nanostructures especially nanomagnesia using biomass, plant extracts, alga, and fungi as a source of precursor material. The ideal method should offer better control of textural properties of nanostructures and decrease the necessity for purification of the synthesized nanoproducts, which sequentially removes the use of large amounts of chemicals and organic solvents and manipulation of products that are unsafe to the environment. Finally, the broad applicability of nanomagnesia in diverse areas is presented. Employment of nanomagnesia reported in several laboratory and industrial fields are valued from the standpoint of the significance of these issues for technological requests, as described in the literature. Nanomagnesia has various applications such as antimicrobial performance, removing pollutants, batteries application, and catalysis.

Effects of Biogas Composition Variations on Engine Performance (바이오가스의 성분 변화가 엔진 성능에 주는 영향)

  • Park, Seung-Hyun;Park, Cheol-Woong;Kim, Young-Min;Lee, Sun-Youp;Kim, Chang-Gi
    • Journal of the Korean Institute of Gas
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    • v.15 no.5
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    • pp.25-30
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    • 2011
  • Biogas obtained from the biodegradable organic wastes in an anaerobic digester consists of $CH_4$ and inert gases such as $CO_2$ and $N_2$. Since the composition of biogas varies by anaerobic digester conditions and the origin of wastes, it is necessary to respond to these variations so as to make stable combustion and accomplish high efficiency when it is used as a fuel for power generating SI engines. In this study, efforts have been made to investigate the effect of changes in the calorific values of biogas on the engine performance and exhaust characteristics. The biogas was simulated by supplying of $CH_4$ with $N_2$ dilution of various ratios, and ECM was developed to achieve accurate control of ignition and combustion. The results show that as the $CH_4$ concentration of the biogas decreases, the optimal spark timing is advanced due to the elevated thermal capacity and lowered $O_2$ concentration of the in-cylinder charge. Furthermore, since combustion temperature was reduced by increased inert gas, $NO_x$ emissions decreased, whereas THC emissions increased.

Size Distributions of Trace Elements in Airborn Particulates Collected using Drum impactor at Gosan, Jeju Island : Measurements in Springtime 2002 (DRUM impactor를 이용한 대기 입자상 물질 중 원소성분의 입경분포 특성 : 제주도 고산지역의 2002년 봄철 (3.29-5.30) 측정 연구)

  • 한진석;문광주;류성윤;안준영;공부주;홍유덕;김영준
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.4
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    • pp.555-569
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    • 2004
  • Size -segregated measurements of aerosol composition using 8-stage DRUM impactor are used to determine the transport of natural and anthropogenic aerosols at Gosan site from 29 March to 30 May in 2002. Separation of ambient aerosols by DRUM impactor offers many Advantages over other standard filtration techniques. Some of the most important advantages are the ability to segregate into details by particle tire, to better preserve chemical integrity since the air stream doesn't pars through the deposit, to collect samples as a function of time, and to have a wide variety of impaction surfaces available to match analytical needs. Although the transport of Yellow sand is a well-known phenomenon in springtime, the result of measurement shows that not only soil dust but also anthropogenic aerosols, including sulfur, enriched trace metals such as Pb, Ni, Zn. Cu, Cr, As, Se, Br, are transported to Gosan in springtime. This study combines the size- and time-resolved aerosol composition measurements with isentropic, backward air-mass trajectories in order to identify some potential source regions of anthropogenic aerosols. As a result, during the NYS period, the average concentration of PM$_{10}$ was 46$\mu\textrm{g}$/㎥, Si, Al. S, Fe, Cl, K, Ca were higher than 1,000 ng/㎥ and Ti was about 100 ng/㎥. The concentrations of Zn, Mn, Cu. Pb, Br, Rb, V, Cr, Ni. At, Se ranged between 1 and 70 ng/㎥. More than 50% typical soil elements, tuck as Al, Si, Fe, Cd. Ti, Cr, Cu, Br. were distributed in a coarse particle range(5.0-12${\mu}{\textrm}{m}$). In other hand, anthropogenic pollutants, luck as S, N, Vi, were mainly distributed in a fine particle range (0.09-0.56${\mu}{\textrm}{m}$). During the YS period, PM$_{10}$ increased about 8 times than NYS period, and main soil elements, such as Al, Si, S, K, V, Mn, Fe also doubled in coarse particle range (1.15-12${\mu}{\textrm}{m}$). But Zn, As, Pb, Cu and Se, which distributed in the time aerosols (0.09-0.56${\mu}{\textrm}{m}$), were on the same level with or decreased than NYS period. Finally. except the YS Period, coarse particles (2.5-12${\mu}{\textrm}{m}$) are inferred to be influenced by soil, coal combustion, waste incineration, ferrous and nonferrous sources through similar pathways with Yellow Sand. But fine particles have different sources, such as coal combustion, gasoline vehicle, biomass burning, oil or coal combustion, nonferrous and ferrous metal sources, which are transported from China, Korea peninsula and local sources.ces.

Ultrafine Particle Events in the Ambient Atmosphere in Korea

  • Maskey, Shila;Kim, Jae-Seok;Cho, Hee-Joo;Park, Kihong
    • Asian Journal of Atmospheric Environment
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    • v.6 no.4
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    • pp.288-303
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    • 2012
  • In this study, real time measurements of particle number size distribution in urban Gwangju, coastal Taean, and industrial Yeosu in Korea were conducted in 2008 to understand the occurrence of ultrafine particle (UFP) (<100 nm) events, the variation of its concentration among different sampling sites, and UFP formation pathways. Also, to investigate seasonal and long-term variation of the UFP number concentration, data were collected for the period of 5 years (2007, 2008, 2010, 2011, and 2012) in urban Gwangju. Photochemical and combustion events were found to be responsible for the formation of UFP in the urban Gwangju site, whereas only photochemical event led to the formation of UFP in the coastal Taean site. The highest UFP concentration was found in industrial Yeosu (the average UFP number fractions were 79, 59 and 58% in Yeosu, Gwangju, and Taean, respectively), suggesting that high amount of gas pollutants (e.g., $NO_2$, $SO_2$, and volatile organic carbon (VOC)) emitted from industries and their photochemical reaction contributed for the elevated UFP concentration in the industrial Yeosu site. The UFP fraction also showed a seasonal variation with the peak value in spring (61.5, 54.5, 50.5, and 40.7% in spring, fall, summer, and winter, respectively) at urban Gwangju. Annual average UFP number concentrations in urban Gwangju were $5.53{\times}10^3\;cm^{-3}$, $4.68{\times}10^3\;cm^{-3}$, $5.32{\times}10^3\;cm^{-3}$, $3.99{\times}10^3\;cm^{-3}$, and $2.16{\times}10^3\;cm^{-3}$ in the year 2007, 2008, 2010, 2011, and 2012, respectively. Comparison of the annual average UFP number concentration with urban sites in other countries showed that the UFP concentrations of the Korean sites were lower than those in other urban cities, probably due to lower source strength in the current site. TEM/EDS analysis for the size-selected UFPs showed that the UFPs were classified into various types having different chemical species. Carbonaceous particles were observed in both combustion (soot and organics) and photochemical events (sulfate and organics). In the photochemical event, an internal mixture of organic species and ammonium sulfate/bisulfate was identified. Also, internal mixtures of aged Na-rich and organic species, aged Ca-rich particles, and doughnut shaped K-containing particles with elemental composition of a strong C with minor O, S, and K-likely to be originated from biomass burning nearby agricultural area, were observed. In addition, fly ash particles were also observed in the combustion event, not in the photochemical event.

Estimation on Greenhouse Gases(GHGs) Emission of Large Forest Fire Area in 2013 (RapidEye 영상을 활용한 대형산불피해지의 온실가스 배출량 추정)

  • Won, Myoung-Soo;Kim, You-Seung;Kim, Kyong-Ha
    • Journal of the Korean Association of Geographic Information Studies
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    • v.17 no.3
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    • pp.54-67
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    • 2014
  • This study was performed to estimate Greenhouse gases(GHGs) emissions from biomass burning at large forest fire(Ulju, Pohang and Bonghwa) in 2013. The extended methodology to estimate GHGs adopted the IPCC(Intergovermental Panel on Climate Change) Guidelines(2006) equation. For classifying fire damaged area and analyzing burn severity of total three large-fire area damaged, this study used post-fire imagery from Rapideye imagery to compute the Maximum Likelihood Classifiction (MLC). The result of accuracy assessment on burn severity from imagery showed that average overall accuracy was 75.93% and Kapp coefficient was 0.67 Finally, GHGs emissions from biomass burning in the three large-fire area 2013 were estimated as follows: Ulju $CO_2$ 63,260, CO 5.207, $CH_4$ 360, $N_2O$ 28.0 and $NO_x$ $4.4g/kg^{-1}{\cdot}ha^{-1}$, Pohang $CO_2$ 28,675, CO 2.359, $CH_4$ 163, $N_2O$ 12.7 and $NO_x$ $1.9g/kg^{-1}{\cdot}ha^{-1}$ and Bonghwa $CO_2$ 53,086, CO 1,655, $CH_4$ 114, $N_2O$ 23.5 and $NO_x$ $3.6g/kg^{-1}{\cdot}ha^{-1}$.

Development of Direct DME Synthesis Process (DME 직접 합성공정 기술개발)

  • Mo, Yong-Gi;Cho, Won-Jun;Baek, Young-Soon
    • Journal of the Korean Institute of Gas
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    • v.14 no.3
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    • pp.41-45
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    • 2010
  • The physical properties of DME(Dimethyl Ether) are very similar to LPG and well-mixed. As cetane number of DME is similar to diesel fuel that can replace diesel fuel and alternative energy. DME is a clean energy source that can be manufactured from various raw materials such as natural gas, CBM(Coal Bed Methane) and biomass. DME has no carbon-carbon bond in its molecular structure and its combustion essentially generates no soot as well as no SOx. The development of DME process in KOGAS have 4 section. First, syngas section can be manufactured various syngas ratio. This completes the tri-reforming process for the synthesis gas ratio of approximately 4.0 to 1.0 range can be adjusted. Second, $CO_2$ is removed from the $CO_2$ removal section of about 92~99%, so the maximum concentration of $CO_2$ entering the DME synthesis reactor should not exceed 8%. Third, in the DME synthesis section, if the temperature of DME reactor increases, the activity of DME catalyst increased. but for the long-term activity is desirable to maintain the proper temperature. Finally, the purity of DME in the DME purification section is over 99.6%.

Conversion Characteristics of Liquid Fuels from Sawdust by Acetone-Solvolysis (아세톤-용매분해반응에 의한 톱밥으로부터 액체 연료물질의 전환 특성 연구)

  • Yoon, Sung Wook;Lee, Jong-Jib
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.4
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    • pp.231-236
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    • 2014
  • Sawdust, produced as an wood by-product, is usable biomass as liquid fuels if decomposed to monomer unit, because the chemical structure are similar to high octane materials found in gasoline. In this study, parameters of thermochemical degradation by acetone-solvolysis reaction of sawdust such as the effect of reaction temperature, reaction time and type of solvent on conversion yield and degradation products were investigated. The liquid products by acetone-solvolysis from sawdust produced various kind of ketone, phenol and furan compounds. The optimum sawdust conversion was observed to be 88.7% at $350^{\circ}C$, 40min. Combustion heating value of liquid products from thermochemical conversion processes was as high as 7,824 cal/g. The energy yield and mass yield in acetone-solvolysis of sawdust was 60.8% and 36.4 g-oil/100g-sawdust after 40 min of reaction at $350^{\circ}C$, respectively. The major components of the acetone-solvolysis products, that could be used as liquid fuel, were 4-methyl-3-pentene-2-one, 1,3,5-trimethylbezene, 2,6-dimethyl-2,5-heptadiene-4-one, 3-methyl-2-cyclopenten-1-one as ketone compounds.

Estimation of the major sources for organic aerosols at the Anmyeon Island GAW station (안면도에서의 초미세먼지 유기성분 주요 영향원 평가)

  • Han, Sanghee;Lee, Ji Yi;Lee, Jongsik;Heo, Jongbae;Jung, Chang Hoon;Kim, Eun-Sill;Kim, Yong Pyo
    • Particle and aerosol research
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    • v.14 no.4
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    • pp.135-144
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    • 2018
  • Based on a two-year measurement data, major sources for the ambient carbonaceous aerosols at the Anmyeon Global Atmosphere Watch (GAW) station were identified by using the Positive Matrix Factorization (PMF) model. The particulate matter less than or equal to $2.5{\mu}m$ in aerodynamic diameter (PM2.5) aerosols were sampled between June 2015 to May 2017 and carbonaceous species including ~80 organic compounds were analyzed. When the number of factors was 5 or 6, the performance evaluation parameters showed the best results, With 6 factor case, the characteristics of transported factors were clearer. The 6 factors were identified with various analyses including chemical characteristics and air parcel movement analysis. The 6 factors with their relative contributions were (1) anthropogenic Secondary Organic Aerosols (SOA) (10.3%), (2) biogenic sources (24.8%), (3) local biomass burning (26.4%), (4) transported biomass burning (7.3%), (5) combustion related sources (12.0%), and (6) transported sources (19.2%). The air parcel movement analysis result and seasonal variation of the contribution of these factors also supported the identification of these factors. Thus, the Anmyeon Island GAW station has been affected by both regional and local sources for the carbonaceous aerosols.

Effects of Inert Gas Composition Variations in Biogas on the Performance of a SI Engine (바이오가스 내의 불활성 가스 성분 변화가 SI 엔진 성능에 주는 영향)

  • Lee, Sunyoup;Park, Seunghyun;Park, Cheolwoong;Kim, Changgi;Lee, Janghee;Woo, Sejong
    • Journal of the Korean Institute of Gas
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    • v.16 no.5
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    • pp.14-20
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    • 2012
  • Biogas can be obtained from biogenic materials through an anaerobic digestion process. Since biogas has low calorific value and its composition significantly varies, appropriate combustion strategies need to be established to obtain stable combustion in engine applications. In this study, efforts have been made to investigate the effects of inert gas composition variations on engine performance and emissions. Results show that the MBT spark timing was advanced and $NO_x$ was reduced as the inert gas in the biogas rose. Moreover, $NO_x$ emission drop in $CO_2$ diluted biogas was more significant than that of $N_2$ due to higher heat capacity of $CO_2$, while THC emissions showed the opposite tendency. Thermal efficiency was increased in $N_2$ case with elevation of $N_2$ due to the decreased heat loss and PMEP. However, there is no difference in $CO_2$ case because of deteriorated flame propagation speed.