• Title/Summary/Keyword: Bio absorbing

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The synthesis and light absorbing properties of heptamethine cyanine chromophores based on benzoxazole derivatives

  • Youn, Hye-Soo;Park, Soo-Youl;Shin, Seung-Rim;Shin, Joung-Il;Oh, Seong-Geun;Jun, Kun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.10a
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    • pp.133-134
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    • 2008
  • A novel near infrared(NIR) absorbing dyes were synthesized by using bis-aldehyde formyl aromatic compounds and heteroaryl derivatives with the reactive methylene group. These dyes provided a range of the NIR wavelength region about 720 nm value. Also, the light absorbing properties of these dyes were investigated in our experiment results. In generally, these NIR colorants may be potential used for optical recording media, DNA sequencing probe and laser beam printings.

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Newly Developed BioDegradable Mg Alloys and Its Biomedical Applications

  • Seok, Hyeon-Gwang;Kim, Yu-Chan;Yang, Gui Fu;Cha, Pil-Ryeong;Jo, Seong-Yun;Yang, Seok-Jo
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.55.2-55.2
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    • 2012
  • Intensive theoretical and experimental studies have been carried out at Korean Institute of Science and Technology (KIST) on controlling the bio absorbing rate of the Mg alloys with high mechanical strength through tailoring of electrochemical potential. Key technology for retarding the corrosion of the Mg alloys is to equalize the corrosion potentials of the constituent phases in the alloys, which prevented the formation of Galvanic circuit between the constituent phases resulting in remarkable reduction of corrosion rate. By thermodynamic consideration, the possible phases of a given alloy system were identified and their work functions, which are related to their corrosion potentials, were calculated by the first principle calculation. The designed alloys, of which the constituent phases have similar work function, were fabricated by clean melting and extrusion system. The newly developed Mg alloys named as KISTUI-MG showed much lower corrosion rate as well as higher strength than previously developed Mg alloys. Biocompatibility and feasibility of the Mg alloys as orthopedic implant materials were evaluated by in vitro cell viability test, in vitro degradation test of mechanical strength during bio-corrosion, in vivo implantation and continuous observation of the implant during in vivo absorbing procedures. Moreover, the cells attached on the Mg alloys was observed using cryo-FIB (focused ion beam) system without the distortion of cell morphology and its organ through the removal of drying steps essential for the preparation of normal SEM/TEM samples. Our Mg alloys showed excellent biocompatibility satisfying the regulations required for biomedical application without evident hydrogen evolution when it implanted into the muscle, inter spine disk, as well as condyle bone of rat and well contact interface with bone tissue when it was implanted into rat condyle.

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COMPARISON OF RED TIDE DETECTION BY A NEW RED TIDE INDEX METHOD AND STANDARD BIO-OPTICAL ALGORITHM APPLIED TO SEA WIFS IMAGERY IN OPTICALLY COMPLEX CASE-II WATERS

  • Shanmugam Palanisamy;Ahn Yu-Hwan
    • Proceedings of the KSRS Conference
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    • 2005.10a
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    • pp.445-449
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    • 2005
  • Various methods to detect the phytoplankton/red tide blooms in the oceanic waters have been developed and tested on satellite ocean color imagery since the last two and half decades, but accurate detection of blooms with these methods remains challenging in optically complex turbid waters, mainly because of the eventual interference of absorbing and scattering properties of dissolved organic and particulate inorganic matters with these methods. The present study introduces a new method called Red tide Index (Rl), providing indices which behave as a good measure of detecting red tide algal blooms in high scattering and absorbing waters of the Korean South Sea and Yellow Sea. The effectiveness of this method in identifying and locating red tides is compared with the standard Ocean Chlorophyll 4 (OC4) bio-optical algorithm applied to SeaWiFS ocean imagery, acquired during two bloom episodes on 27 March 2002 and 28 September 2003. The result revealed that OC4 bio-optical algorithm falsely identifies red tide blooms in areas abundance in colored dissolved organic and particulate inorganic matter constituents associated with coastal areas, estuaries and river mouths, whereas red tide index provides improved capability of detecting, predicting and monitoring of these blooms in both clear and turbid waters.

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The Synthesis and Evaluation of Squarylium Dyes Based On the NIR Spectra Region

  • Park, Soo-Youl;Shin, Seung-Rim;Shin, Joung-Il;An, Kyoung-Lyong;Jun, Kun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.10a
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    • pp.131-132
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    • 2008
  • Several squarylium dyes, derived from benzothiazole and indoles, were synthesized as a potential NIR dyes with absorption in the 700-900 nm region. These chromophores were induced much more bathochromic shift in the absorption maximum of the compound relative to the neutral parent squarylium dyes which we were described before. The squaryliums offer a convenient way of linking the dye to functional substrates and may be an advantage to be potential chromophores for NIR-absorbing, NIR-Cut-off filter, PDT(Photo Dynamic Therapy) materials.

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Utilization of Wastepaper Fibers for Development of Environment-friendly Shock-Absorbing Materials (환경친화적 완충재의 개발을 위한 폐지 섬유의 이용)

  • Kim, Gyeong-Yun;Kim, Chul-Hwan;Lee, Young-Min;Song, Dae-Bin;Shin, Tae-Gi;Kim, Jae-Ok;Park, Chong-Yawl
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.2 s.115
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    • pp.52-60
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    • 2006
  • Environment-friendly shock-absorbing materials were made of wastepaper such as Korean old corrugated containers(KOCC) and Korean old newsprint (KONP) with a vacuum forming method. The plate-like cushioning materials made of KOCC and KONP respectively by vacuum forming showed superior shock-absorbing properties with lower elastic moduli compared to expanded polystyrene (EPS) and pulp mold. Even though the plate-like materials had many free voids in their fiber structure, their apparent densities (${\approx}0.1g/cm^3$) were a little higher than that of EPS (${\approx}0.03g/cm^3$) and much lower than that of pulp mold(${\approx}0.3g/cm^3$). However, the elastic moduli of the cushioning materials made of wastepaper were much lower than that of EPS or pulp mold. This finding implies that the cushioning materials made of KOCC fibers containing more lignin than KONP show better shock-absorbing properties than KONP. Moreover, the cushioning materials made of KOCC and KONP respectively showed greater porosity than pulp mold. The addition of cationic starch to the cushioning materials contributed to the increase in the elastic modulus to the same level as that of EPS. Furthermore, the deterioration in fiber quality by repeated use of wastepaper played a positive role in improving shock-absorbing ability.

Use of Wastepaper for Developing Environment-friendly Shock-absorbing Materials

  • Kim, Chul-Hwan;Song, Dae-Bin;Lee, Young-Min;Kim, Jae-Ok;Kim, Gyeong-Yun;Shin, Tae-Gi;Park, Chong-Yawl
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.471-474
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    • 2006
  • Environment-friendly shock-absorbing materials were made of wastepaper such as old corrugated containers (OCC) and old newspapers (ONP) with a vacuum forming method. The plate-like cushioning materials made of OCC and ONP respectively by vacuum forming showed superior shock-absorbing properties with lower elastic moduli compared to expanded polystyrene (EPS) and pulp mold. Even though the plate-like materials had many free voids in their fiber structure, their apparent densities (${\approx}0.1g/cm^{3}$) were a little higher than that of EPS (${\approx}0.03g/cm^{3}$) and much lower than that of pulp mold (${\approx}0.3g/cm^{3}$). However, the elastic moduli of the cushioning materials made of wastepaper were much lower than that of EPS or pulp mold. This finding implies that the cushioning materials made of OCC fibers containing more lignin than ONP show better shock-absorbing properties than ONP Moreover, the cushioning materials made of OCC and ONP respectively showed greater porosity than pulp mold. The addition of cationic starch to the cushioning materials contributed to an increase in the elastic modulus to the same level as that of EPS. Furthermore, the deterioration in fiber quality by repeated use of wastepaper played a great role in improving shock-absorbing ability.

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Use of Waste Woods for Developing Environment-friendly Shock-absorbing Materials

  • Kim, Chul-Hwan;Song, Dae-Bin;Lee, Young-Min;Kim, Jae-Ok;Kim, Gyeong-Yun;Shin, Tae-Gi;Park, Chong-Yawl
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.475-478
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    • 2006
  • Environment-friendly shock-absorbing materials were made using a vacuum forming method from waste wood collected from local mountains in Korea. The waste wood was pulped by thermomechanical pulping. The TMP cushions showed superior shock-absorbing properties with lower elastic moduli compared to EPS and pulp mold. Even though the TMP cushions made using different suction times had many free voids in their inner fiber structure, their apparent densities were a little higher than EPS and much lower than pulp mold. The addition of cationic starch improved the elastic modulus of the TMP cushions without increasing the apparent density, which was different from surface sizing with starch. The porosity of the TMP cushions was a little greater than EPS and much less than pulp mold. Finally, the TMP cushions have great potential to endure external impacts occurring during goods distribution.

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Investigation of a series of near-infrared absorbing heptamethine cyanine dyes

  • Yun, Hye-Su;Park, Su-Yeol;Sin, Seung-Rim;Sin, Jong-Il;An, Gyeong-Ryong;Lee, Sang-O;O, Seong-Geun;Jeon, Geun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2009.11a
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    • pp.115-116
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    • 2009
  • In this study, near-infrared absorbing dyes, namely, new rigidified heptamethine cyanine dyes were synthesized and investigated their properties. The cyanine dyes have been synthesized by a condensation reaction between a quanternary salt containing as activated methyl group and an unsaturated bisaldehyde or its equivalent. We were investigated the synthesis of new rigidified heptamethine cyanine and related the compounds with near infrared absorption. The full spectroscopic characterization of all cyanine were described. Absorption properties in the near-infrared region may cause these dyes to the potential used in bio-probe, optical recording media materials.

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The Use of Special Washers in Bone Plates for Improved Impact-Absorbing Characteristics (충격흡수 특성의 향상을 위하 내고정용 특수 와셔에 관한 연구)

  • 김윤영;김장수
    • Journal of Biomedical Engineering Research
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    • v.16 no.4
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    • pp.457-462
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    • 1995
  • Unlike the usual bone plate and screw fracture fixation, an improved plate fixation method, which can transfer gradually physiological load to bones, is described. The key feature of the present method is to use washers between the plate and the screw. Bio-absorbable materials or non-ferrous materials with good damping characteristics are used to manufacture the washers. The purpose of this paper is to discuss potential advantages of the proposed method, and to show experimentally its improved impact-absorbing characteristics. Vibration experiments are carried out for pig femurs and cow tibias with and without the proposed washers. This experiments show that the washers can drop the first peak value suite substantially in the FRF plots. Although in-vivo experiments have not been conducted, the present fixation method appears to be a simple and effective alternative to the presently used method.

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Development of Environment-friendly Cushioning Materials by Pulping of Waste Residual Woods (폐잔재의 펄프화를 통한 환경친화적 완충소재의 개발)

  • Lee, Young-Min;Kim, Chul-Hwan;Kim, Jae-Ok;Kim, Gyeong-Yun;Shin, Tae-Gi;Song, Dae-Bin;Park, Chong-Yawl
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.2 s.115
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    • pp.61-71
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    • 2006
  • Environment-friendly shock-absorbing (cushioning) materials were made using a vacuum forming method from waste wood collected from local mountains in Korea. The waste wood was pulped by thermomechanical pulping. The TMP cushions showed superior shock-absorbing properties with lower elastic moduli compared to EPS(Expanded Polystyrene) and pulp mold. Even though the TMP cushions made using at different suction times had many free voids in their inner fiber structures, their apparent densities were a little higher than EPS and much lower than pulp mold. The addition of cationic starch improved elastic modulus of the TMP cushions without increasing the apparent density, which was different from surface sizing with starch. The porosity of the TMP cushions was a little greater than EPS and much less than pulp mold. Finally, the TMP cushions have great potential to endure external impacts occurring during goods distribution.