• Title/Summary/Keyword: Binder-free

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Tension Stiffening Behavior of High Strength Concrete Utilizing Silica Fume Free Binder (실리카 흄 대체재로 SFFB를 사용한 고강도 콘크리트의 인장강성)

  • Yun, Hyun-Do;Park, Whan-Shin;Lee, Young-Oh;Kim, Sun-Woo;Lee, Sang-Soo;Yun, Gil-Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.107-108
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    • 2010
  • This paper provides test results on the tension stiffening behavior of high strength concrete (HSC) members used silica fume free binder (SFFB) instead of silica fume. The objective of this study is to evaluate the capability of replacing expensive silica fume to SFFB in HSCs with compressive strength of 60 and 80MPa. Test results indicated that for two mixes of 60 and 80 MPa HSC, cracking and strength behavior of tension members, which are replaced silica fume to SFFB, showed equivalent performance to those of tension members used silica fume.

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Binder-Free Synthesis of NiCo2S4 Nanowires Grown on Ni Foam as an Efficient Electrocatalyst for Oxygen Evolution Reaction

  • Patil, Komal;Babar, Pravin;Kim, Jin Hyeok
    • Korean Journal of Materials Research
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    • v.30 no.5
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    • pp.217-222
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    • 2020
  • The design and fabrication of catalysts with low-cost and high electrocatalytic activity for the oxygen evolution reaction (OER) have remained challenging because of the sluggish kinetics of this reaction. The key to the pursuit of efficient electrocatalysts is to design them with high surface area and more active sites. In this work, we have successfully synthesized a highly stable and active NiCo2S4 nanowire array on a Ni-foam substrate (NiCo2S4 NW/NF) via a two-step hydrothermal synthesis approach. This NiCo2S4 NW/NF exhibits overpotential as low as 275 mV, delivering a current density of 20 mA cm-2 (versus reversible hydrogen electrode) with a low Tafel slope of 89 mV dec-1 and superior long-term stability for 20 h in 1 M KOH electrolyte. The outstanding performance is ascribed to the inherent activity of the binder-free deposited, vertically aligned nanowire structure, which provides a large number of electrochemically active surface sites, accelerating electron transfer, and simultaneously enhancing the diffusion of electrolyte.

Physical and Chemical characteristics of Cokes Using Ash-Free Coal as binder (무회분 석탄(AFC)을 바인더로 이용한 코크스의 물리적 및 화학적 특성)

  • Kim, Gyeong Min;Kim, Jin Ho;Lisandy, Kevin Yohanes;Kim, Gyu Bo;Choi, Ho Kyung;Jeon, Chung Hwan
    • Korean Chemical Engineering Research
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    • v.55 no.3
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    • pp.395-400
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    • 2017
  • Coke strength was increased by adding ash-free coal (AFC) binder. In this study, the effect of the AFC binder on the physical and chemical properties of coke was experimentally investigated to understand the molecular mechanism for the improved coke strength. For reduced $CO_2$ emission in steelmaking industry, torrefied biomass fuel mixed with coal binder is also considered. The interface between the base coal and AFC was thus examined using Scanning Electron Microscope (SEM). The coke strength was commonly measured by performing the indirect tensile test and Nuclear Magnetic Resonance (NMR) spectroscopy in $^1H$ and $^{13}C$ modes. For comprehensive mechanism study of the enhanced coke strength thus obtained, ordinary coal for thermal power plant use was carbonized with AFC for subsequent SEM examination. The NMR spectroscopy results of coke samples positively revealed that the tensile strength was proportional to the average number of aromatic rings.

기술연구 - Clinker free 콘크리트의 기초성상에 관한 연구

  • Lee, Jong-Yeol
    • Cement
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    • s.192
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    • pp.39-47
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    • 2011
  • 최근 온실가스 감축과 기후변화 그리고 녹색성장에 대한 관심증대와 더불어 시멘트 분야의 연구 생산분야는 천연자원 사용량을 줄이고, 소성공정을 도입하지 않은 새로운 개념의 무기바인더가 다시 고개를 들고 있다. 다른 용어로는 비소성, 무시멘트 등으로 표현되기도 하는데, 광의의 개념으로 보면 알칼리 활성화제를 사용한 비소성 무기결합재인 지오폴리머가 바로 그것이다. 지오폴리머 결합재는 1957년 우크라이나의 토목공학회에서 개발한 알칼리 활성 슬래그시멘트에 기원을 두고 있고, 1970년대 말 프랑스의 다비도비치에 의해 지오폴리머라는 용어가 처음 사용되기 시작했다. 알칼리 활성 무기결합재(Alkali-activated inorganic binder)의 정의이다. Alkali-activated inorganic binder는 원래는 결합능력이 없던 재료에 대해서 Alkali-activating 용액을 첨가했을 때, 시멘트처럼 결합능력을 가지게 되는 모든 종류의 결합시스템을 말한다. 국내에도 이미 2000년 초부터 지오폴리머의 개념을 도입한 제품이 상업화되어 오랫동안 품질검증을 거쳐 안정성이 확인되고 있다. 최근에 다시 전남대가 그 동안의 연구성과를 발 빠르게 중소기업에 기술 이전하여 소위 무시멘트 시대에 진입하는 분위기이다. 지난 9월 동아에스텍(주)과 조인트벤처 설립을 위해 손을 잡았고, 사업화가 곧 진행될 것으로 보인다. 이를 계기로 국내에도 무시멘트회사가 본격적으로 등장하게 된 것이다. 따라서 본 고는 무시멘트의 개념을 잘 표현한 문헌으로 일본콘크리트공학 연차논문집, 2010년 1월호를 번역 요약 발췌한 것이다.

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Shattering Grain Loss in Relation to the Impulse During Harvest and Year-Variation of Grain Tensile Strength in Rice (벼 수확시 충격에 의한 탈립 손실과 탈립성의 년차간 변이)

  • Yong Woong, Kwon;Jin Chul, Shin
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.28 no.4
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    • pp.419-424
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    • 1983
  • Tensile strength and shattering losses of rice grains in a binder harvest and in a free falling test were examined. Indica$\times$Japonica varieties, Milyang 23, Hangangchal, and Taebaek, and a Japonica variety, Jinheung were used for this study. The average tensile strength varied with varieties, showing 0.743N (Newton) in Milyang 23, 1.078N in Hangangchal, 1.573 N in Taebaek, and 1.775 N in Jinheung. Extrapolation of the average tensile strength for the zero field loss of grain indicated about 1.7 N. Moisture content of straw at the cutting position in a binder harvest was 76.0 to 86.7% in culm and 76.7 to 77.8% in leaf sheath. The percent loss of grains occurring in binder barvest in the field was equivalent to the degree of shattering in the panicle-falling test onto the concrete floor at the height of about 40cm. The grain shattering (Y) was closely related to the impulse (X), the change in momentum: Y=-25.73+4958.4X, ($r^2$=0.987) for Milyang 23, Y=-12.97+2258.3X, ($r^2$=0.979) for Hanagangchal, Y=-5.24+840.4X, ($r^2$ =0.976) for Taebaek. The tensile strengths of grains and their variance varied singnificantly yearly even in the same variety. The magnitude of year-variance was somewhat smaller for the easily shattering variety.

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Optimising Ink Setting Properties on Double Coated Wood-free Papers

  • Bluvol, Guillermo;Carlsson, Roger
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.215-225
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    • 2006
  • Today's requirements for print-press runnability and print quality demand an optimised absorption and adhesion of printing ink on the paper surface. Modern coating concepts for high glossing offset grades use ultra fine pigments, whereas binder level has continuously been decreased to a minimum in recent years to achieve the highest possible sheet gloss development and for economical reasons. Both the ultra fine pigments and the reduced binder levels lead in many cases to a faster ink setting rate. On the other hand, matt paper grades use relatively coarse pigments leading to a slow ink setting compared to the high glossing papers. Both too fast and too slow ink setting properties implicate drawbacks in print quality and print press runnability. The mechanisms behind the interactions between ink and coating have been presented in many previous publications. The purpose of this study was to determine and quantify how the ink setting rate is influenced by pigment system (GCC and GCC/clay blends), latex level and latex properties in the topcoat of double coated sheet fed offset paper. The roles of binder level and type in the precoat were also assessed. The effect of calendering (temperature and pressure) was studied with one formulation. The resulting ink setting characteristics were tested using three different laboratory testing instruments. The correlation amongst the different laboratory testing methods is discussed. The results show that by varying the latex properties, the pigment system and/or latex addition level, the ink tack development of ink applied to a topcoat pigment system can be significantly influenced. It can be slowed down as often desired with ultra fine pigments or speeded up in the case of coarse pigments. There was no visible effect on the ink setting rate by using different binder systems in the precoat..

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A study on the Powder Injection Molding of Translucent Alumina via Flowability Simulation of Powder/Binder Mixture (분말사출성형 시 분말 혼합체의 유동성 시뮬레이션을 통한 투광성 알루미나 소결체의 특성 연구)

  • Kim, Hyung Soo;Byun, Jong Min;Kim, Se Hoon;Kim, Young Do
    • Journal of Powder Materials
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    • v.21 no.3
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    • pp.215-221
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    • 2014
  • Translucent alumina is a potential candidate for high temperature application as a replacement of the glass or polymer. Recently, due to the increasing demand of high power light emitting diode (LED), there is a growing interest in the translucent alumina. Since the translucent property is very sensitive to the internal defect, such as voids inside or abnormal grain growth of sintered alumina, it is important to fabricate the defect-free product through the fabrication process. Powder injection molding (PIM) has been commonly applied for the fabrication of complex shaped products. Among the many parameters of PIM, the flowability of powder/binder mixture becomes more significant especially for the shape of the cavity with thin thickness. Two different positions of the gate were applied during PIM using the disc type of die. The binder was removed by solvent extraction method and the brown compact was sintered at $1750^{\circ}C$ for 3 hours in a vacuum. The flowability was also simulated using moldflow (MPI 6.0) with two different types of gate. The effect of the flowability of powder/binder mixture on the microstructure of the sintered specimen was studied with the analysis of the simulation result.

Study on the characteristic of liner and cover material by accelerating agent type (급결제 종류에 따른 광산 차수재의 특성 연구)

  • Cho, Yong-Kwang;Nam, Seong-Young;Lee, Yong-Mu;Kim, Chun-Sik;Seo, Shin-Seok;Jo, Sung-Hyun;Lee, Hyoung-Woo;Ahn, Ji-Whan
    • Journal of Environmental Science International
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    • v.27 no.2
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    • pp.75-81
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    • 2018
  • At present research on mining backfill materials is being carried out to prevent ground subsidence and breaking by underground cavern of exhausted mines. However, backfill materials can cause secondary environmental issues such as ground pollution. To solve these issues, liner and cover materials are constructed before backfill materials constructed, to inhibit toxic substances form moving to the surroundings. Liner and cover materials, however, should have an accelerating performance after construction and when the accelerating performance is degraded, the work efficiency can be lowered, and the construction cost can be increased, by many rebound content. Therefore, this study develops mining liner and cover materials, and evaluates their accelerating performance and physical properties of liner and cover materials by types and content of accelerating agent. In case of aluminate accelerating agent, it is mixed with more than 5% of liner and cover materials(binder/ratio); thus an accelerating performance satisfying Korean Industrial Standards(KS) occurs, and in case of alkali-free accelerating agent, when it is mixed with more than 7%(binder/ratio), accelerating performance satisfying KS occurs. The more the accelerating agent capacity increases, the more compressive strength decreases. In addition, it is confirmed that compressive strength of aluminate accelerating agent is more degraded than compressive strength of the alkali-free accelerating agent. It is also confirmed that drying shrinkage stability of the alkali-free accelerating agent is better than the drying shrinkage stability of the aluminate accelerating agent.

Fabrication and Piezoelectric Strain Characteristics of PLZT Functionally Gradient Piezoelectric Actuator by Doctor Blade Process (닥터블레이드법에 의한 PLZT계 경사기능 압전 엑튜에이터의 제조와 압전 변위 특성)

  • 김한수;최승철;이전국;정형진
    • Journal of the Korean Ceramic Society
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    • v.29 no.9
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    • pp.695-704
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    • 1992
  • In (Pb, La)(Zr, Ti)O3 ceramic system, the functionally gradient material (FGM) was developed, and its processing and properties were investigated. The FGMs were successfully prepared through doctor blade method with acrylic binder system as well as mold stacking press method. The ultrasonic treatment was very effective for particle dispersion in slurry, and it lead to form clack-free green films. The strain-voltage characteristics of the FGM system was significantly improved which fabricated between a high piezoelectric-low dielectric and a low piezoelectric-high dielectric composition layer.

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