• Title/Summary/Keyword: Binder treatment

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Fabrication of Low Temperature Cofired Ceramic (LTCC) Chip Couplers for High Frequencies : I, Effects of Binder Burnout Process on the Formation of Electrode Line (고주파용 저온 동시소성 세라믹(LTCC)칩 커플러 제조: I. 전극형성에 대한 결합제 분해공정의 영향)

  • 조남태;심광보;이선우;구기덕
    • Journal of the Korean Ceramic Society
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    • v.36 no.6
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    • pp.583-589
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    • 1999
  • In the fabrication of ceramic chip couples for high frequency application such as the mobile communication equipment the formation of electrode lines and Ag diffusion were investigated with heat treatment conditions for removing organic binders. The deformation and densification of the electrode line greatly depended on the binder burnout process due to the overlapped temperature zone near 400$^{\circ}C$ of the binder dissociation and the solid phase sintering of the silver electrode. Ag ions were diffused into the glass ceramic substrate. The Ag diffusion was led by the glassy phase containing Pb ions rather than by the crystalline phase containing Ca ions. The fact suggests that the Ag diffusion could be controlled by managing the composition of the glass ceramic substrate.

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Effect of Binder's Concentration and Fiber Type on Mechanical Properties of Fragrant Fabrics (마이크로캡슐을 이용한 방향가공시 바인더 농도 및 섬유 종류에 따른 물성)

  • 김혜림;송화순
    • Journal of the Korean Society of Clothing and Textiles
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    • v.28 no.7
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    • pp.1029-1036
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    • 2004
  • The fragrant fabrics were prepared by treatment with eucalyptus microcapsules. 100% cotton fabric, 100% polyester fabric and 100% wool fabric were used as test specimens. Using pad-dry-cure method, microcapsules were attached on each specimen by acrylic binder under conditions of varying concentration. Surface property, stiffness, and air permeability of fragrant fabrics were evaluated. As increasing concentration of binder, add-on yield was increased. Add-on yield was decreased with increasing laundering cycle, especially in polyester fabric. As the concentration of binder was increased, the properties of stiffness and air permeability were decreased. Also it fumed out that pad-dry-cure method was not suitable to polyester fabric.

Effects of binder type and heat treatment temperature on physical properties of a carbon composite bipolar plate for PEMFCs

  • Kang, Dong-Su;Roh, Jea-Seung
    • Carbon letters
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    • v.14 no.2
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    • pp.110-116
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    • 2013
  • This study investigated a developed process for producing a composite bipolar plate having excellent conductivity by using coal tar pitch and phenol resin as binders. We used a pressing method to prepare a compact of graphite powder mixed with binders. Resistivity of the impregnated compact was observed as heat treatment temperature was increased. It was observed that pore sizes of the GCTP samples increased as the heat treatment temperature increased. There was not a great difference between the flexural strengths of GCTP-IM and CPR-IM as the heat treatment temperature was increased. The resistivity of GPR700-IM, heat treated at $700^{\circ}C$ using phenolic resin as a binder, was $4829{\mu}{\Omega}{\cdot}cm$ which was best value in this study. In addition, it is expected that with the appropriate selection of carbon powder and further optimization of process we can produce a composite bipolar plate which has excellent properties.

Effects of Li2O Addition and Heat-Treatment on Formability of FeS2 Powder for Cathode of Thermal Battery (열전지 양극용 FeS2 분말의 성형성에 미치는 Li2O 첨가 및 열처리의 효과)

  • Ryu, Sung-Soo;Lee, Won-Jin;Kim, Seongwon;Cheong, Hae-Won;Cho, Sung-Baek;Kang, Seung-Ho;Lee, Sung-Min
    • Journal of Powder Materials
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    • v.21 no.3
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    • pp.185-190
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    • 2014
  • $FeS_2$ has been widely used for cathode materials in thermal battery because of its high stability and current capability at high operation temperature. Salts such as a LiCl-KCl were added as a binder for improving electrical performance and formability of $FeS_2$ cathode powder. In this study, the effects of the addition of $Li_2O$ in LiCl-KCl binder on the formability of $FeS_2$ powder compact were investigated. With the increasing amount of $Li_2O$ addition to LiCl-KCl binder salts, the strength of the pressed compacts increased considerably when the powder mixture were pre-heat-treated above $350^{\circ}C$. The heat-treatment resulted in promoting the coating coverage of $FeS_2$ particles by the salts as $Li_2O$ was added. The observed coating as $Li_2O$ addition might be attributed to the enhanced wettability of the salt rather than its reduced melting temperature. The high strength of compacts by the $Li_2O$ addition and pre-heat-treatment could improve the formability of $FeS_2$ raw materials.

Synthesis and Effect of Plasma Treatment of Acrylic Composite Particle Binder (아크릴계 복합입자 바인더의 제조와 플라즈마 처리영향)

  • Sim, Dong-Hyun;Seul, Soo-Duk
    • Polymer(Korea)
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    • v.32 no.3
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    • pp.276-283
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    • 2008
  • Kind of monomer(MMA, EA, BA, St)and the monomer ratio(80/20 to 20/80) where changed in the preparation of the core shell binder, and property was improved the plasma processing. Each material changed by plasma treatment time($1{\sim}10\;s$) to change to measure the tensile strength, contact angle and adhesion peel strength for the core shell binder optimal conditions for handling the output of the surface treatment. The type of polymerization and composition of the binder is a regardless initiator of APS, the reaction temperature of $85^{\circ}C$ to 0.3 wt% of the surfactant used to indicate when the conversion rate was the highest, core shell composite particle binder got two glass temperature curves. Core shell binder after the plasma processing contact angle change is the PEA/PSt 38 percent of cases within five seconds to indicate slight decrease was a decline rapidly if not handled $0^{\circ}$ to reach. Tensile strength PSt/PMMA varies $46.71{\sim}46.27\;kg_f$/2.5 cm and adhesion strength PEA/PMMA varies $7.89{\sim}14.44\;kg_f$/2.5 cm increases. Overall, adhesion strength of core shell composite particle is in the order of order PEA>PBA>PSt for shell monomer MMA.

Comparison Study of Polymer and Ti Sol-Gel Carbon Coating on Ti for PEMFC Bipolar Plates (고분자전해질 연료전지용 Ti 분리판을 위한 고분자와 Ti Sol-Gel 탄소코팅의 비교 연구)

  • Won-Seog Yang;Jae-Ho Lee;Hee-Suk Roh;Ju-Hyun Yoo;Chul-Min Park;Su-Yeon Lee;Sung-Mo Moon
    • Corrosion Science and Technology
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    • v.22 no.6
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    • pp.447-456
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    • 2023
  • In this work, we performed a comparative study examining two coatings on Ti Gr.1 for use in fuel cell bipolar plates. The coatings consisted of carbon black as the conductor along with acrylic polymer and Ti Sol-Gel binder as the binder. Ti Sol-Gel that had precipitated as TiO2 in areas impregnated between carbon black gaps, thereby acting as a binder for carbon black and serving as a polymer coating. Neither of the coatings peeled off during the 90° bend test to check formability. The contact resistance of the TiO2 coating was found to be lower than that of the polymer binder coating. Moreover, due to coating shrinkage (denser) that occurred during the heat treatment process, the TiO2 binder coating showed almost the same level of corrosion resistance, as measured by potentiostatic and EIS tests, despite being thinner than the polymer coating. However, both the polymer binder coating and the TiO2 binder coating had many pores and irregularities internally (around 10 ~ 100 nm) and on the surface (0.1 ~ 2 ㎛). We considered that these pores and irregularities contributed to the lower corrosion resistance.

19F NMR investigation on the ratio of amorphous to crystal for the binder PVdF in Li ion battery

  • Im, Jong-san;Park, Junghwan;Kim, Kyoung Soo;Jung, Hyunok
    • Journal of the Korean Magnetic Resonance Society
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    • v.23 no.1
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    • pp.1-5
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    • 2019
  • $^{19}F$ NMR experiments were carried out to observe the change of the characteristics of the PVdF binder which is an auxiliary material of the lithium ion battery. PVdF has various crystalline or amorphous phases by thermal treatment. A mixture of cathode and auxiliary materials including PVdF was coated on aluminum foil as an electron collector and then subjected to thermal treatment at various temperatures. The overlapped $^{19}F$ NMR signals obtained from the various phases were separately convoluted into the respective phases, and it was found that there was a relative ratio change of these phases. In addition, the crystal and amorphous phase of PVdF was changed during the vacuum drying, which is the last step of the actual electrode manufacturing. It was observed that the relative amount of amorphous phase, which may affect the flexibility of the electrode or the wettability of the electrolyte, abruptly changes after a certain temperature.

Selection of Binder and Solid Materials for Pelleting Welsh Onion(Allium fistulosum L.) Seeds (파 펠렛종자 생산을 위한 접착제 및 피복재료 선발)

  • 강점순
    • Journal of Life Science
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    • v.12 no.6
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    • pp.721-730
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    • 2002
  • This study was carried out to select new pelleting binder and material for Welsh onion seeds. The optimum treatments of the various plant growth regulators to improve seed germination of the Welsh onion was also estimated. There were no significant effects of growth regulators on the germination percentage, but germination was faster according to the number of days to 50% of the final germination ($T_{50}$) and the mean number of days to germination (MDG) than those of the control. Germinability was increased when the seeds were soaked in gibberellic acid ($GA_3$) solution for 24hrs, even though there was no synergy effect on the germinability when $GA_3$ was mixed with 6-benzylaminopurine (BAP). The optimum treatment for improving germination of Welsh onion was observed when the tested seeds was soaked in 500 $\mu$M of $GA_3$ at $20^{\circ}C$ for 24hrs. Also, when the seeds soaked in the aforementioned treatment, the rate of germination was increased at lower temperature than at $20^{\circ}C$, the optimal temperature. The percentage and the speed of seed germination depended on the kinds of pelleting binder and their concentration. It showed that the higher the concentration of the binder for seeds pelleting, the lower the percentage of seed germination. Among the pelleting binder, polyvinyl alcohol (PVA) and polyvinyl pyrrolidone (PVP) were the best binders for seed pelleting, because seed germination using those binder did not affect on the concentration of binder. On the other hand, Carboxymethy cellulose (CMC) and methyl cellulose (MC) severely inhibited the seed germination The germinability was also different arcording to the pelleting materials. Among the different 58 pelleting materials, kaoline alone, the mixture of bentonite and kaoline, the mixture of bentonite, calcium carbonate and diatomaceous earth #300 were found as the best pelleting materials for welsh onion seeds.

The Preparation of Ceramic YBaCuO System Superconducting wire (세라믹 YBaCuO계 초전도 선재의 제조)

  • 박성진;한태희;한병성;김양수
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.40 no.9
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    • pp.908-912
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    • 1991
  • YBaCuO oxide superconductor-shows superconductive at Liquid Nitrogen temperature-must be preparate wire or thin film form for utility. The wiring is possible with heat treatment after appropriate mixture of polymeric binder and YBaCuO oxide superconductor has fabricated. This study, analyzed the characteristics of fabricated superconductor and extruded wire after application to each of a mixed at different rate in the superconductor and compared with an original pure sample. From the result, we knew that the binder component influences superconducting characteristics. The best condition for superconductivity occurred at a criticla temperature of 86.4K (8:2 rate) and at a critical current density of 100.27A/cmy with a binder packing ratio of about 20~25 percent.

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Control of Contaminants Elution by Solidification of Contaminated Soil (오염토양의 고형화에 따른 오염물질 용출제어)

  • Chung, Ha-Ik;Cho, Jin-Woo;Yu, Jun;Lee, Yong-Su
    • Proceedings of the Korean Geotechical Society Conference
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    • 2002.03a
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    • pp.739-742
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    • 2002
  • Immobilization of contaminants in contaminated soils by solidification processes is an attractive potential remediation process. In this study, the treatability of lead, copper, toluene, and COD was investigated by leaching test. Industrial sand was adopted as the test material and was contaminated with lead copper, and toluene to 100mg/kg, 500mg/kg, 200mg/kg respectively. P solidifying agent was used as the binder(20% by weight of contaminated soil) in the solidification treatment. The leachability of contaminants leached from the solidified soil was evaluated using column test. The percentage of contaminants leached from the solidified soil was significantly reduced by reaction of waste species with cement components and encapsulation reaction of binder. Based on the tests, it is ascertained solidification process can be a very effective method to control the elution of contaminants from the contaminated soil.

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