• Title/Summary/Keyword: Binder level

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Development of High Viscous Modified Asphalt Binder for Porous Asphalt Pavement (배수성 포장용 고점도 개질 아스팔트 바인더 개발)

  • Kim, Hyeong-Seok;Lee, Hyun-Jong;Lee, Kwang-Ho;Kim, Hyung-Bae
    • International Journal of Highway Engineering
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    • v.12 no.2
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    • pp.81-90
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    • 2010
  • This paper describes the results of laboratory and field performance tests on the polymer modified asphalt binder and mixtures developed in this study for porous asphalt pavements. Various physical and mechanical laboratory tests including DSR and BBR tests are performed for two types of modified binders, and one type of binder is selected based on the binder testing results. Mix designs are conducted for the selected asphalt binder and a Japanese modified binder, respectively. Various performance tests including fatigue tests, wheel tracking tests, and moisture susceptibility tests are conducted for the domestic and Japanese porous asphalt mixtures. Test results indicate that the overall performance characteristics of the domestic mixture are similar to or better than those of the Japanese mixture. Based on the laboratory testing results, the domestic porous mixture is applied to a field test section. Periodic field investigations are conducted to evaluate the changes in noise level and air voids with time. The road noise analysis shows that the noise levels of the porous pavement keep increasing and, after two years, are similar to those of SMA pavements.

Properties of the high strength and self-compacting concrete according to the replacement ratio of fly ash (플라이애쉬의 치환율에 따른 고강도 자기충전 콘크리트의 특성)

  • Kwon, Yeong-Ho;Lee, Hyun-Ho;Lee, Hwa-Jin;Ha, Jae-Dam
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.85-88
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    • 2006
  • This study describes the optimum mix proportion of the high strength and self-compacting concrete placed in main structures of LNG above tank. This concrete requires high strength level about $60{\sim}80MPa$, low hydration heat, balance between workability and consistency without vibrating in the actual work. For this purpose, low heat portland cement and fly ash are selected and design factors including water-binder ratio, replacement ratio of fly ash are tested. As experimental results, low heat portland cement shows lower the confined water ratio than another cement type and the optimum replacement ratio of fly ash in order to improve properties of the binder-paste shows 10% by cement weight considering test results of the confined water ratio$({\beta}p)$. Also, flowability of the high strength and self-compacting concrete by using fly ash about $10{\sim}20%$ is improved. The replacement ratio of fly ash 10% and water-binder ratio $25{\sim}27%$ are suitable to the design strength 80MPa and cost, In case of the design strength 60MPa, the replacement ratio of fly ash and water-binder ratio show 20% and $25{\sim}30%$ separately. Based on the results of this study, the optimum mix proportions of the high strength and self-compacting concrete will be applied to the construction of LNG above tank as a new type.

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The Flowing Properties of the Super Flowing Concrete using Limestone (석쇠석분을 사용한 초유동 콘크리트의 유동특성에 관한 연구)

  • 이상수;권영호;안재현;김무한;박칠림
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.369-374
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    • 1997
  • This study is the experimental results on the flowing properties of the super flowing concrete (SFC) using limestone (LS), which is to develop the SFC in level of ordinary strength. And this study is described with respect to basic concept, confined water ratio ($\beta_p$) of binder (cement+limestone) in paste, relationship between volume ratio of water-binder (w/b) and addition ratio of superplasticizer in mortar, flowing velocity and funneling time and compressive strength in concrete to replacement ratio of LS. The results of this study is improved to flowing properties in fleshly concrete with increasing replacement ratio of LS. The optimal mixing condition of the SFC using LS in level of ordinary strength is proved W/C 55%, LS 40% and W/C 60%, LS 50%.

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Thick Positive Electrode using Polytetrafluorethylene (PTFE) Binder for High-Energy-Density Lithium-ion Batteries (높은 에너지 밀도의 리튬이온 이차전지를 위한 PTFE 바인더를 적용한 고로딩 양극)

  • Kang, Jeong Min;Kim, Hyoung Woo;Jang, Young Seok;Kim, Haebeen;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
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    • v.24 no.2
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    • pp.28-33
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    • 2021
  • Many researchers have increased the loading level of electrodes to improve the energy density of secondary batteries. In this study, high-loading NCM523 (LiNi0.5Co0.2Mn0.3O2) positive electrode is manufactured using a polytetrafluoroethylene (PTFE) binder, not the conventional polyvinylidene fluoride (PVdF) binder, which has been commonly used in lithium-ion batteries. Through the kneading process using PTFE suspension, not the conventional slurry process using PVdF solution in N-methyl-2-pyrrolidinone (NMP), thick electrodes with high loading are easily manufactured. When the PTFE and PVdF-based electrodes are prepared at a loading level of 5.0 mAh/cm2, respectively, the PTFE-based electrode shows better cycle performance and rate capability than those of PVdF-based electrodes. The electrode manufactured by the kneading process using a PTFE binder has high electrode porosity due to insufficient roll-press, but the porosity can be lowered by high temperature roll-press over 120℃. However, there is no significant difference in cycle performance according to the roll press temperature. In addition, the cycle performance of the high loading electrode is slightly improved by increasing the content of the conductive material. Overall, the PTFE binder can improve the performance of the high loading electrode, but additional solutions will be needed.

Surface Photovoltage Spectroscopy on Dyed Zinc Oxide (색소흡착산화아연에 대한 표면광기전력의 분광학적 연구)

  • Kim, Young-Soon;Sung, Yong-Kiel
    • Journal of the Korean Chemical Society
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    • v.28 no.4
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    • pp.251-258
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    • 1984
  • The mechanism of photosensitization and the affect of binder on dye-sensitized ZnO have been studied by surface photovoltage spectroscopy. It has been found that the value of energy trapping level $E_{t1}$ on ZnO is 1.12eV (${\lambda$ = 1,100nm) and that of energy trapping level $E_{t2}$ on dye-sensitized ZnO is 0.99eV (${\lambda$ = 1,250nm) which is shifted towards a longer wavelength. The effect of binder on ZnO has been increased the efficiency of surface photovoltage, but it does not effect the values of energy trapping level. The acid-type dyes agree well with the prediction based on an electron transfer mechanism. The desensitization of the Na salt-type dyes for the intrinsic photoresponse of zinc oxide can be explained by energy transfer mechanism. It has been obtained that the dye-sensitized ZnO indicates the possibility of electrophotographic photosensitizer for the infrared range of light.

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Adhesive Strength and Electrochemical Properties of Li(Ni0.5Co0.2Mn0.3)O2Electrodes with Lean Binder Composition (바인더 함량에 따른 Li(Ni0.5Co0.2Mn0.3)O2 전극의 접착력 및 전기화학 성능에 관한 연구)

  • Roh, Youngjoon;Byun, Seoungwoo;Ryou, Myung-Hyun;Lee, Yong Min
    • Journal of the Korean Electrochemical Society
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    • v.21 no.3
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    • pp.47-54
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    • 2018
  • To maximize the areal capacity($mAh\;cm^{-2}$) of $LiNi_{0.5}Co_{0.2}Mn_{0.3}O_2$(NCM523) electrode with the same loading level of $15mg\;cm^{-2}$, three NCM523 electrodes with 4, 2, and 1 wt% poly(vinylidene fluoride)(PVdF) binder content are fabricated. Due to the delamination issue of electrode composite at the edge during punching process, the 1 wt% electrode is excluded for further evaluation. When the PVdF binder content decreases from 4 to 2 wt%, both adhesion strength and shear stress decrease from 0.4846 to $0.2627kN\;m^{-1}$ by -46% and from 3.847 to 2.013 MPa by -48%, respectively. Regardless of these substantial decline of mechanical properties, their initial electrochemical properties such as initial coulombic efficiency and voltage profile are almost the same. However, owing to high loading level, the 2 wt% electrode not only exhibits worse cycle performance than the 4 wt% electrode, but also cannot maintain its mechanical integrity only after 80 cycles. Therefore, if the binder content is reduced to increase the area capacity, the mechanical properties as well as the cycle performance must be carefully evaluated.

A Comparative Study on Strength Development, Chloride Diffusivity and Adiabatic Temperature Rise of Marine Concrete Depending on Binder Type (결합재 종류에 따른 해양 콘크리트의 강도 발현, 염화물 확산 및 단열온도 상승 특성에 대한 비교 연구)

  • Bae, Jun-Young;Cho, Sung-Hyun;Shin, Kyung-Joon;Kim, Yun-Yong
    • Journal of the Korea Concrete Institute
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    • v.25 no.4
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    • pp.411-418
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    • 2013
  • Recently, in order to reduce a damage of chloride attack and hydration heat in marine concrete structures, blended cement in mixing the marine concrete is widely used. Long term strength development is distinct in concrete with blended cement and it also has excellent resistance to chloride attack and reduction of hydration heat. However, blended cement has a characteristic of relatively low compressive strength in early age of 28 days. On the other hand, a high level of compressive strength is required in the Standard Specification for marine concrete mix design. Such concrete mix design satisfying Standard Specification is effective to chloride attack but disadvantageous for hydration heat reduction due to large quantity of binder. In this study, the material properties of marine concrete considering water-binder ratio and binder type are experimentally investigated. Through the research results, compressive strength in blended cement at the age of 56 days is similar although it has smaller compressive strength at the age of 28 days compared with result of OPC (ordinary portland cement). Even though blended cement has a large water-binder ratio and small unit of binder content, chloride ion diffusion coefficient is still small and hydration heat is also found to be reduced. For meeting the required compressive strength in Standard Specification for marine concrete at 28 days, the increased unit content of binder is needed but the increased hydration heat is also expected.

Studies on the Correlation between Coated Paper and Physical Properties of Latices (라덱스의 물성이 도공지 품질에 미치는 상관성에 대한 연구)

  • 박동국;조교동;고문찬;윤재한;이용규
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.1
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    • pp.22-29
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    • 2002
  • The coated paper was greatly affected by the basic physical properties of the binder as well as the amount of the coating formula. High glass transition temperature (Tg) of the styrene-butadiene (SB) latex, selected as the binder in our study, gave the high stiffness to the coated paper, but lowered the binding force and print gloss. The average particle size of the SB latex also greatly affected to the coated paper so that the smaller particle size improved the rheological property of the coating formula and increased the binding force and print gloss. Another property of the SBR latex, gel content, was important because when its value was small, the latex was easily deformed at the high temperature and increased air permeability to the coated paper. Therefore, the lower gel content consequently resulted in the higher blistering resistance, especially in the web paper. The larger portion of the SB latex in the coated formula improved the binding force and print gloss, but decreased the ink set-off and ink-trapping to the coated paper. The heavier coating improved optical properties such as opacity, paper gloss and paper smoothness, to the coated paper.

Corrosion of Steel in Blended Concretes Containing OPC, PFA, GGBS and SF

  • Song, Ha-Won;Lee, Chang-Hong;Lee, Kewn Chu
    • Corrosion Science and Technology
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    • v.8 no.5
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    • pp.171-176
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    • 2009
  • The chloride threshold level (CTL) in mixed concrete containing, ordinary Portland cement (OPC), pulverized fuel ash (PFA) ground granulated blast furnace slag (GGBS), and silica fume (SF) is important for study on corrosion of reinforced concrete structures. The CTL is defined as a critical content of chloride at the steel depth of the steel which causes the breakdown of the passive film. The criterion of the CTL represented by total chloride content has been used due to convenience and practicality. In order to demonstrate a relationship between the CTL by total chloride content and the CTL by free chloride content, corrosion test and chloride binding capacity test were carried out. In corrosion test, Mortar specimens were cast using OPC, PFA, GGBS and SF, chlorides were admixed ranging 0.0, 0.2, 0.4, 0.8, 1.0, 1.5, 2.0, 2.5 and 3.0% by weight of binder. All specimens were cured 28 days, and then the corrosion rate was measured by the Tafel's extrapolation method. In chloride binding capacity, paste specimens were casting using OPC, PFA, GGBS and SF, chlorides were admixed ranging 0.1, 0.2, 0.3, 0.5, 1.0, 1.5, 2.0, 2.5 and 3.0% by weight of binders. At 28days, solution mixed with the powder of ground specimens was used to measure binding capacity. All specimens of both experiments were wrapped in polythene film to avoid leaching out of chloride and hydroxyl ions. As a result, the CTL by total chloride content ranged from 0.36-1.44% by weight of binders and the CTL by free chloride content ranged from 0.14-0.96%. Accordingly, the difference was ranging, from 0.22 to 0.48% by weight of binder. The order of difference for binder is OPC > 10% SF > 30% PFA > 60% GGBS.

A Study on the Physical Characteristics of Concrete using Multi-Component Blended Binder According to Warter Reduction Efficiency of Warter Reduction Agent (감수제의 감수 효율에 따른 다성분계 결합재를 사용한 콘크리트의 물리적 특성에 관한 기초적 연구)

  • Kim, Kyung-Hwan;Oh, Sung-Rok;Choi, Byung-Keol;Choi, Yun-Wang
    • Journal of the Korea Concrete Institute
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    • v.27 no.5
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    • pp.559-568
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    • 2015
  • In this study, multi-component blended concrete mix with fly ash and ground granulated blast furnace slag according to 3 level of type of warter reduction agent (type of 0%, 8% and 16%) and 3 level of water-binder ratio (40%, 45% and 50%) was prepared for evaluation of effect of physical characteristics of concrete using multi-component blended binder according to warter reduction efficiency of warter reduction agent. In addition, concrete mix was carried out repetition test of three times in order to secure the reliability. As a result, compressive strength according to type of warter reduction agent was found that difference of strength was about 20% occurred, warter reduction efficiency of warter reduction agent was showed that a great influence on qualities of concrete. Therefore, reflected the effect of warter reduction efficiency of warter reduction agent, prediction model equations of compressive strength for multi-component blended concrete was proposed, it was found that more than 90% of the high correlation.