• 한국진공학회:학술대회논문집
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• 한국진공학회 1995년도 제9회 학술발표회 논문개요집
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• pp.158-158
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• 1995

• 한국산학기술학회논문지
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• 제13권1호
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• pp.456-461
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• 2012

본 연구에서는 글리세롤과 우레아를 이용하여 글리세롤카보네이트를 합성하는 반응을 진행하였다. ZnO와 Zn-Al 이원계 금속 산화물 촉매를 제조하고, 제조되어진 촉매를 사용하여 글리세롤의 전환율과 글리세롤카보네이트의 수율을 확인하였고, Al의 첨가에 따른 촉매 특성의 분석과 글리세롤카보네이트 합성반응에서의 역할에 대해 확인하였다. 글리세롤카보네이트 합성 반응에서 ZnO를 단독으로 촉매를 사용한 경우보다 Zn-Al 혼합 산화물을 촉매로 사용하여 반응하였을 때, 부반응이 억제되어 전환율 및 수율이 증가함을 확인하였다.

• 한국분말재료학회지
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• 제10권1호
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• pp.6-14
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• 2003

The purpose of the present study is to investigate the method decreasing debinding time as well as lowering operation condition than pure supercritical $CO_2$ debinding by using cosolvent or binary mixture of propane + $CO_2$. First method is to add cosolvent, such as n-hexane, DCM, methanol, 1-butanol, in supercritical $CO_2$. In case of adding cosolvent, we were found the addition of non-polar cosolvent (n-hexane) improves dramatically the binder removal rate (more than 2 times) compared with pure supercritical $CO_2$ debinding, second method is to use mixture of supercritical propane + $CO_2$, as solvent. In case of using mixture of supercritical propane + $CO_2$, the rate of debinding speeded up with increasing of pressure and concentration of propane at 348.15 K. It was found that addition of cosolvent (e.g., n-hexane, DCM) and binary mixture propane + $CO_2$ for supercritical solvent remarkably improved binder removal rate for the paraffin wax-based binder system, in comparison with using pure supercritical $CO_2$.

• 한국지하수토양환경학회지:지하수토양환경
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• 제18권4호
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• pp.32-39
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• 2013

This research focused on the effects of heavy metals on the biomonitoring activity of genetically engineered bioluminescent bacteria, Pseudomonas putida mt-2 KG1206. KG1206 was exposed to single or binary mixtures of different heavy metals as well as soils contaminated with heavy metals. In case of single exposure with different inducer pollutant, the toxicity order was as followings : As(III) > Cd, As(V) >> Cu, Cr(VI). The toxic effects of the binary mixtures was compared to the expected effect based on a simple theory of probabilities. The interactive effects were mostly additive, while in few cases antgonistic and synergistic mode of action was observed for some concentration combinations. No considerable correlation was found between the total metal contents in soils and the bioluminescence activity of each sample. However, statistically significant differences (p = 0.0102) were observed between two groups, classified based on arsenite contamination. These results demonstrate the usage of recombinant bioluminescent microorganism in biomonitoring and the complex interactive effects of metals.

• 한국진공학회지
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• 제4권S2호
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• pp.148-155
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• 1995

(1) The metastable crystalline(MX) phases formed by ion mixing are classified into 5 types, i.e. the super-saturated solid solutions and the enlarged HCP-I phases reported earlier, and the newly observed FCC-I phases in hcp-based alloys, The FCC-ll and HCP-ll phases in bcc-based alloys. The growth kinetics of the MX phases is discussed. (2) The interfacial free energy in the multilayered films was found to play an important role in ion beam mixing(IM) induced amorphization. By adding sufficient interfaces, amorphous alloys were obtained even in the systems with rather positive heat of formation. (3) Gibbs free energy diagrams of some representative systems were constructed, by calculating the free energy curves of all the competing phases. Steady-state thermal annealing was conducted and the results confirmed the relevance of the constructed diagrams, which were inturn employed to interpret the MX phase formation as well as the glass forming ability upon IM in the binary metal systems.

• Journal of Welding and Joining
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• 제23권6호
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• pp.43-48
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• 2005

This work was carried out to obtain sound welds and to select a most suitable binary metal joint among three different dissimilar binary metal combinations such as Zr-4/Ta, Mo/Ta and Ti/Ta(seal tube/sensor sheath) joints fur the instrumented nuclear fuel irradiation test. To do this, Taguchi experimental method was employed to optimize the experimental data. In addition, metallography, micro-focus x-ray radiography and hardness test were conducted to examine the welds. From the weld bead appearance, penetration depth and bead width as well as weld defects standpoint, Zr-4/Ta joint is suggested for the circumferential joining between a seal tube and a sensor sheath. The optimized welding parameters based on Zr-4/Ta joint are suggested as well.

• 대한전자공학회논문지SD
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• 제40권9호
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• pp.685-691
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• 2003

본 논문에서는 고속 통신 시스템 응용을 위한 12b 100 MS/s CMOS D/A 변환기(DAC) 회로를 제안한다. 제안하는 DAC는 전력소모, 면적, 선형성 및 글리치 에너지 등을 고려하여, 상위 8b는 단위 전류셀 매트릭스 (unit current-cell matrix)로 나머지 하위 4b는 이진 전류열 (binary-weighted array)로 구성하였다. 제안하는 DAC는 동적 성능을 향상시키기 위해 새로운 구조의 스위치 구동 회로를 사용하였다. 시제품 DAC회로 레이아웃을 위해서는 캐스코드 전류원을 단위 전류셀 스위치 매트릭스와 분리하였으며, 제안하는 칩은 0.35 um single-poly quad-metal CMOS 공정을 사용하여 제작되었다. 측정된 시제품의 DNL 및 INL은 12b 해상도에서 각각 ±0.75 LSB와 ±1.73 LSB이내의 수준이며, 100 MS/s 동작 주파수와 10 MHz 입력 주파수에서 64 dB의 SFDR을 보여준다. 전력 소모는 3 V의 전원 전압에서 91 mW이며, 칩 전체 크기는 2.2 mm × 2.0 mm 이다.

• Journal of Welding and Joining
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• 제17권4호
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• pp.60-68
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• 1999

The previously developed two dimensional model was modified in order to predict more accurately the degree of microsegregation and eutectic fraction on in weld metal whose solidification rate is very fast. The model employed the same assumptions with previous model but considered of a tip undercooling. The previously predicted microsegregation and eutectic fraction has the discrepancies between simulated and examined results in the weld metal solidification. The experiments for the weld metal solidification of 2024 A1 and Fe-Ni alloy were carried out in order to examine the reasonability and feasibility of this modified model. The concentration profile of the solute and eutectic fraction predicted by the simulation agreed well with those found from experimental works. According to the results, it was believed that the dendrite tip undercooling considered in the modified model be reasonable for predicting the degree of microsegregation more accurately in weld metla solidification. In the GTA welds, degree of dendrite-tip undercooling increases with increasing solidification rage(welding speed). This serves to increase the concentration of dendrite core and thus result in reducing the degree of segregation. And solid state diffusion(back diffusion) during solidification is very low in the weld metal solidification so that little additional homogenization of solute occurs during solidification. With consideration of tip undercooling this modified model can predict exactly degree of microsegregation and eutectic fraction from slow solidification(casting) to fast solidification(welding).

• 한국지하수토양환경학회지:지하수토양환경
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• 제13권1호
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• pp.101-109
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• 2008

국내 화학회사에서 발생되는 연마분진 폐기물에 대한 흡착제로서의 재이용성을 평가하기 위하여 연마분진을 $550^{\circ}C$에서 하소시켜 얻어진 무정형 알루미늄 산화물(AMA-L)을 이용하여 양이온 중금속인 구리, 카드뮴, 납 등에 대한 흡착특성을 파악하였으며 MINEQL + 프로그램을 적용하여 AMA-L과 양이온 중금속 이온간의 표면흡착결합 반응을 모사하여 흡착실험결과와 비교하였다. 구리와 카드뮴, 납의 단일성분에 대한 AMA-L의 흡착실험결과, 납 > 구리 > 카드뮴의 순서로 친화력의 차이가 발생하는 것을 확인하였다. 구리와 카드뮴의 농도변화에 따른 AMA-L 흡착실험 결과 구리와 카드뮴의 농도를 증가시킴에 따라 두 성분의 흡착효율은 모두 감소되는 것으로 나타났으며 구리와 카드뮴이 동시에 존재하는 이성분계 흡착의 경우에는 단일성분으로 존재하는 경우와 유사한 흡착율을 나타내었으며 경쟁이온의 영향을 거의 받지 않는 것으로 확인이 되었다. 또한, AMA-L에 대한 흡착특성에 대한 MINEQL+를 이용한 모사결과 단일성분과 이성분계 흡착에 대한 흡착특성은 비교적 잘 일치하는 것으로 나타났다.

• 설비공학논문집
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• 제9권4호
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• pp.552-560
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• 1997

Analysis is performed to determine the optimal lengths or cross-sectional areas of refrigerator-cooled current leads that can be applied to the conduction-cooled superconducting systems. The binary current lead is composed of the series combination of a normal metal at the upper(warm) part and a high $T_c$ superconductor(HTS) at the lower(cold) part. The heat conduction toward the cold end of HTS part constitutes a major refrigeration load. In addition, the joint between the parts should be cooled by a refrigerator in order to reduce the load at the low end and maintain the HTS part in a superconducting state. The sum of the work inputs required for the two refrigeration loads needs to be minimized for an optimal operation. In this design, three simple models that depict the refrigeration performance as functions of cooling temperature are developed based on some of the existing refrigerators. By solving one-dimensional conduction equation that take into account the temperature-dependent properties of the materials, the refrigeration works are numerically calculated for various values of the joint temperature and the sizes of two parts. The results show that for given size of HTS, there exist the optimal values for the joint temperature and the size of the normal metal. It is also found that the refrigeration work decreases as the length of HTS increases and that the optimal size of normal metal is quite independent of the size of HTS. For a given length of HTS, there is an optimal cross-sectional area and it increases as the length increases. The dependence of the optimal sizes on the refrigerator models employed are presented for 1kA leads.