• 제목/요약/키워드: Binary Mixture

검색결과 366건 처리시간 0.025초

이성분계 단백질 혼합물의 미세막 분리공정에서 막오염에 관한 연구 (Fouling Study with Binary Protein Mixtures in Microfilration)

  • 안병훈;문동주;유계상
    • Korean Chemical Engineering Research
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    • 제43권2호
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    • pp.236-242
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    • 2005
  • 대표적인 단백질 물질인 bovine serum albumin(BSA), lysozyme, pepsin, casein 그리고 ovalbumin의 이성분계 단백질 혼합물의 미세 분리 막에서 보이는 막 오염 현상에 관한 실험을 고찰하였다. 트랙 에치법에 의해 제조된 $0.2{\mu}m$ 폴리카보네이트 미세 막을 이용하여 단백질 혼합물 용액의 조성과 종류가 여과유량감속에 미치는 영향에 대한 실험을 일정한 압력(14 kPa)과 수소이온농도(pH=11) 하에서 수행하였다. 각각의 이성분 단백질 혼합물에 대한 막오염 현상을 확인하였으며, 유량 감속 데이터는 최근에 개발된 pore blockage-cake formation 모델을 이용하여 분석한 결과, 실험 결과와 일치하였다. 이성분계 단백질 혼합물의 조성과 단백질 종류가 막오염 및 유속변화에 미치는 영향은 공극막힘속도(${\alpha}$), 단백질 침적층의 초기 저항($R_{po}$) 및 단백질 저항의 증가속도(${\beta}$)에 의해 설명 할 수 있었다. 대체로 공극막힘속도의 변화는 유속감소현상과 일치함을 알 수 있으며, 특히 casein이 존재하는 단백질 혼합물에서의 급격한 유량감속은 casein에 의한 단백질 침적층의 초기저항에 크게 기인된 것으로 판단된다.

물-에탄올 기반 이성분 산화탄소나노유체의 특성 비교 연구 (A Comparative Study on the Characteristics of Binary Oxidized Carbon Nanofluids Based DI Water and Ethanol)

  • 박성식;김남진
    • 한국태양에너지학회 논문집
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    • 제32권6호
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    • pp.85-92
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    • 2012
  • A nanofluid is a fluid containing suspended solid particles, with sizes on the order of nanometers. Normally, nanofluids have higher thermal conductivitiest han their base fluids. Therefore, we measured the thermal conductivity and viscosity of oxidized carbon nanofluids based the mixture of distilled water and ethanol (ethanol concentration is 0.2) oxidized carbon nanofluids were made by ultrasonic dispersing oxidized multi-walled carbon nanotubes in the mixture of distilled water and ethanol at the rates of 0.001~ 0.1 vol%. The thermal conductivity and viscosity of oxidized carbon nanofluids were measured by using transient hot-wire method and rotational digital viscometer, respectively. And all of experiments were carried out at the same temperature conditions($10^{\circ}C$, $25^{\circ}C$ and $70^{\circ}C$). As a result, when volume fraction of nanofluids is 0.1 vol%, thermal conductivity was improved 13.6% ($10^{\circ}C$), 15.1% ($25^{\circ}C$), and 17.0% ($70^{\circ}C$), and its viscosity was increased by 36.0% ($10^{\circ}C$), 32.9% ($25^{\circ}C$) and 19.5% ($70^{\circ}C$) than the base fluids.

원추형 분립유동층에서 미세 분체의 수력학적 특성 (Hydrodynamic Characteristics of Fine Powders in the Conical Powder-Particle Fluidized Beds)

  • 이동현;신문권;김은미;손승용;박병섭;한귀영;윤기준
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2005년도 춘계학술대회
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    • pp.310-313
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    • 2005
  • The conical fluidizing system of a binary mixture of Geldart C powders and Geldart A particles was defined as the conical powder-particle fluidized bed. We used a cold conical powder-particle fluidized bed model having a 0.104m-I.D. and 0.6m-high with an apex angle of $10^{\circ}$ for fluidization of a binary powder-particle mixture of 50 $vol\%$ fine carbon black powders (HI-900L, Korea Carbon Black Co.) and coarse alumina particles $(90{\mu}m)$ under different superficial gas velocities (0-0.1 m/s). The differential bed pressure drop increases with increasing gas velocity, and it goes from zero to a maximum value with increasing or decreasing gas velocity. In the conical fluidized beds of fine powders, demarcation velocities of the partial fluidization, full fluidization, partial defluidization was not observed.

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Seta-flash 밀폐식 방법에 의한 n-hexanol+n-butyric acid 계와 n-butanol+propionic acid 계의 인화점 측정 (Measurement of Flash Points for n-hexanol+n-butyric acid and n-butanol+propionic acid by Seta-flash Closed Cup Method)

  • 하동명;이성진
    • 한국안전학회지
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    • 제29권6호
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    • pp.76-80
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    • 2014
  • The flash point is one of the most important physical properties used to determine the fire hazard of flammable liquid mixture and defined as the lowest temperature at which a liquid produces sufficient vapor to form a combustible mixture with air. The main purpose of this paper is to measure and predict the flash point of binary flammable miscible mixtures. The flash points for n-hexanol+n-butyric acid and n-butanol+propionic acid, were measured by using Seta-flash closed cup method. The experimentally derived data were correlated with the binary interaction parameters of the van Laar and NRTL equations through the optimization method. The flash points estimated by these correlations were compared with those calculated by the method based on Raoult's law. The optimization method were found to be better than the method based on the Raoult's law.

저온연소조건에서 n-heptane/alcohol 혼합연료의 냉염과 열염에 대한 착화지연 관찰 (Observation on the Ignition Delay Time of Cool and Thermal Flame of n-heptane/alcohol Blended Fuel at Low Temperature Combustion Regime)

  • 송재혁;강기중;류승협;최경민;김덕줄
    • 한국연소학회지
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    • 제18권4호
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    • pp.12-20
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    • 2013
  • The ignition delay time is an important factor to understand the combustion characteristics of internal combustion engine. In this study, ignition delay times of cool and thermal flame were observed separately in homogeneous charge compression ignition(HCCI) engine. This study presents numerical investigation of ignition delay time of n-heptane and alcohol(ethanol and n-butanol) binary fuel. The $O_2$ concentration in the mixture was set 9-10% to simulate high exhaust gas recirculation(EGR) rate condition. The numerical study on the ignition delay time was performed using CHEMKIN codes with various blending ratios and EGR rates. The results revealed that the ignition delay time increased with increasing the alcohol fraction in the mixture due to a decrease of oxidation of n-heptane at the low temperature. From the numerical analysis, ethanol needed more radical and higher temperature than n-butanol for oxidation. In addition, thermal ignition delay time is sharply increasing with decreasing $O_2$ fraction, but cool flame ignition delay time changes negligibly for both binary fuels. Also, in high temperature regime, the ignition delay time showed similar tendency with both blends regardless of blending ratio and EGR rate.

인삼 사포닌에서 Ginsenoside-$Rg_2$와 -$Rg_3$의 이성질체인 20(R&S) Prosapogenin들의 역상 고속 액체 크로마토그래피에 의한 분리 (Separation of 20(R&S) Prosapogenin Isomers of Ginsenoside-$Rg_2$ and -$Rg_3$ from Ginseng Saponins by Reversed-Phase High Performance Liquid Chromatography)

  • 정승일;김천석;이용구;이호섭;김일광
    • 분석과학
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    • 제11권5호
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    • pp.404-408
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    • 1998
  • Using a reversed-phase high performance liquid chromatography, the separation of 20(S)-, 20(R)-prosapogenin stereo-isomers of ginsenoside-$Rg_2$ and of ginsenoside-$Rg_3$ in ginseng saponins has been carried out with binary solvent system. The optimum conditions for the isomer separation are as following: Nova-$Pak^{(R)}C_{18}$ (Waters, $3.9{\times}150mm$) column, $CH_3CN/CH_3CN$ (100:8, v/v) binary solvent system and the flow rate was 1.7 mL/min. The stereoisomers were separated with change of the mixture ratio of the solvent system, the solvent elution by gradient program, and then detected at 203 nm of UV detector. The simultaneous separation of mixture that were the $Rg_2$, $Rg_3$ isomers was easily performed in nonpolar solvent for $Rg_2$, polar solvent for $Rg_3$ at the same optimum conditions.

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나노-마이크로 알루미늄 혼합 입자의 공기와의 연소 모델링 (Combustion Modeling of Nano/Micro Aluminum Particle Mixture)

  • 윤시경;신준수;성홍계
    • 한국추진공학회지
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    • 제15권6호
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    • pp.15-25
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    • 2011
  • 금속 연료 중 널리 사용되는 알루미늄의 연소 특성에 관하여 1차원 연소모델링을 제안하였다. 연소 모델링은 예열영역, 반응영역, 반응 후 영역, 세 영역으로 나누어 수행하였다. 또한 희박연소로 가정하여 단일 입자의 경우 입자크기와 당량비에 따른 화염속도, 나노와 마이크로 입자의 혼합물의 경우 혼합 비율에 따른 화염속도를 압력이 1기압 조건에서 계산하여 실험결과와 비교하였다. 단일입자의 경우, 입자의 크기가 작아질수록 화염속도가 빨라지고, 당량비가 낮아질수록 화염속도가 느려지는 현상이 관찰되었다. 나노와 마이크로 입자의 혼합물의 경우, 나노 입자의 함유량에 따라 화염속도는 빨라지며, 화염구조는 분리화염과 중첩화염이 나타남이 관찰되었다.

루프형태의 밀폐형 Thermosyphon의 작동특성과 시스템 모델링에 관한 연구 (A Study on the Operating Characteristics and System Modelling of Closed Loop Type Thermosyphon)

  • 강명철;강용혁;이동규
    • 한국태양에너지학회 논문집
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    • 제22권2호
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    • pp.39-47
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    • 2002
  • The thermosyphon SDHWS and the loop type thermosyphon systems are widely used for domestic hot water system. The loop type thermosyphon is a circulation device for transferring the heat produced at the evaporator to the condenser area in the loop. In this study, the operating characteristics of various working fluids being used have been identified. The working fluids employed in the study were ethanol. water, and a binary mixture of ethanol and water. The volume of working fluid used in this study were 30%, 40%, 50%, 60% and 70% of evaporator volume. It is observed that, in the thermosyphon with low volume of working fluid, such as 30% or 40%, the fluid was dried out. The flow pattern and mechanism of the heat transfer were identified through this study. Flow patterns of the binary mixture working fluid were also investigated, and the patterns were recorded in the camera. The system parameters were calculated using the thermal performance data. Modelling of the system was carried out using PSTAR method and TRNSYS program.

열전달 촉진관에서 2원 혼합냉매의 외부 응축열전달계수 (Condensation Heat Transfer Coefficients of Binary Refrigerant Mixtures on Enhanced Tubes)

  • 김경기;서강태;채순남;정동수
    • 설비공학논문집
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    • 제14권2호
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    • pp.161-167
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    • 2002
  • In this study, external condensation heat transfer coefficients (HTCs) of two non-azeotropic refrigerant mixtures of HFC32/HFC134a and HF0134a/HCF0123 at various compositions were measured on both low fin and Turbo-C enhanced tubes of 19.0 mm outside diameter All data were taken at the vapor temperature of 39$^{\circ}C$ with a wall subcooling of 3- 8 K. Test results showed that HTCs of the tested mixtures on the enhanced tubes were much lower than the ideal values calculated by the mass fraction weighting of the pure compo- nents'HTCs. Also the reduction of HTCs due to the diffusion vapor film was much larger than that of a plain tube. Unlike HTCs of pure fluids, HTCs of the mixtures measured on enhanced tubes increased as the wall subcooling increased, which was due to the sudden break up of the vapor diffusion film with an increase in wall subcooling. Finally, heat transfer enhancement ratios for mixtures were found to be much lower than those of pure fluids.

신경망을 이용한 차량 객체의 그림자 제거 (Cast-Shadow Elimination of Vehicle Objects Using Backpropagation Neural Network)

  • 정성환;이준환
    • 한국ITS학회 논문지
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    • 제7권1호
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    • pp.32-41
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    • 2008
  • 비디오를 이용한 비전기반 감시에서 움직이는 객체의 추적은 GMM (Gaussian Mixture Model)을 사용한 배경영상과 현재영상의 차이법을 이용한다. 문턱치를 통해 생성된 이진영상을 이용하여 객체 추적을 할 경우 객체 정보가 아닌 그림자에 의하여 객체가 병합되는 현상이 나타난다. 본 논문에서는 신경망(Backpropagation Neural Network)을 이용하여 그림자를 제거하는 방법을 제안하였다. 10개의 동영상에서 객체영역과 캐스트그림자(Cast-Shadow)영역의 훈련용 이미지에서 특징 값을 추출하여 신경망을 훈련시켰다. 캐스트그림자를 제거하는 방법은 이진영상의 객체로 추정되는 영역에서 그림자를 분리하는 방법을 기초로 하며 기존의 그림자 제거 알고리즘 (SNP, SP, DNM1, DNM2, CNCC)보다 그림자 제거 성능이 (16.2%, 38.2%, 28.1%, 22.3%, 44.4%)로 높게 나타났다.

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