• Title/Summary/Keyword: Binary Mixture

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Performance Characteristics Analysis of Evaporator in Ammonia-Water Rankine Cycle Based on Exergy and Entransy (암모니아-물 랭킨사이클의 증발기에서의 엑서지 및 엔트랜시 성능 특성 해석)

  • KIM, KYOUNG HOON;JUNG, YOUNG GUAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.6
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    • pp.621-628
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    • 2019
  • The use of the ammonia-water zeotropic mixture as a working fluid in the power generating system has been considered as a proven technology for efficient recovery of low-grade heat sources. This paper presents a thermodynamic performance analysis for ammonia-water evaporator using low-grade heat source, based on the exergy and entransy which has been recently introduced as a physical quantity to describe the heat transfer ability of an object. In the analysis, effects of the ammonia mass fraction and source temperature of the binary mixture are investigated on the system performance such as heat transfer, effectiveness, exergy destruction, entransy dissipation, and entransy dissipation based thermal resistance. The results show that the ammonia mass concentration and the source temperature have significant effects on the thermodynamic system performance of the ammonia-water evaporator.

Surface Properties and Betergency of the Binary Surfactant Mixture (계면활성제 혼합용액의 계면특성 및 세척성에 관한 연구)

  • 심소희;박정희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.21 no.3
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    • pp.632-640
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    • 1997
  • Changes in surface properties and detergency of sunactant mixtures were investigated in order to study the optimum mixing ratio of anionic and nonionic surfactants by measuring surface tension, interfacial tension, suspendability, and emulsification as a Amction of mixing ratio. Also, surface tension and detergency of the surfactant mixtures were determined with the increase of water-hardness or temperature. The results were as follows: the addition of NPE to anionic surfactant solutions (LAS or SDS) by 0.1 mole fraction remarkably decreased surface tension. NPE (n=15)/anionic surfactant mixtures showed a synergistic effect in lowering interfacial tension and emulsification, but NPE (n=7.5)/anionic surfactant mixtures did not. In suspension stability, however, synergism appeared when LAS or 505 was mixed with both of NPE's. With respect to the hydrophile of NPE, NPE (n=15) was more effective than NPE (n=i.5) in improving suspension stability. Detergency of LAS/NPE mixture changed almost linearly with mixing ratio, but that of SDS/NPE mixture increased remarkably by the addition of 0.1 or 0.2 mole fraction of NPE at all temperatures. As the temperature increased, surface tension of surfactant mixtures decreased and detergency was improved, but their synergistic effect decreased. In hard water, the mixtures showed better detergency than single surfactuant solutions.

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Pool Boiling Heat Transfer Coefficient of HFC32/HFC152a on a Plain Surface (평판 표면에서 HFC32/HFC152a 혼합냉매의 풀 비등 열전달계수)

  • Kang, Dong-Gyu;Lee, Yohan;Jung, Dongsoo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.25 no.9
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    • pp.484-492
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    • 2013
  • Nucleate pool boiling heat transfer coefficients (HTCs) are measured with HFC32/HFC152a mixture at several compositions. All data are taken at the liquid pool temperature of $7^{\circ}C$, on a horizontal plain square surface of $9.53{\times}9.53$ mm, with heat fluxes of 10 $kW/m^2$ to 100 $kW/m^2$ with an interval of 10 $kW/m^2$, in the increasing order of heat flux. Test results show that the HTCs of these mixtures are up to 45% lower than those of the ideal HTCs calculated by a linear mixing rule with pure fluids' HTCs, due to the mass transfer resistance associated with non-azeotropic refrigerant mixtures. Pool boiling data show the deduction in HTCs with an increase in GTD of the mixture. The present mixture data agree well with five well known correlations, within 20% deviation.

Measurement and Prediction of Autoignition Temperature (AIT) and Ignition Delay Time of n-Pentanol and p-Xylene Mixture (n-Pentanol p-Xylene 과 혼합물의 최소자연발화온도와 발화지연시간의 측정 및 예측)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.31 no.5
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    • pp.1-6
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    • 2017
  • The fire and explosion properties of combustible materials are necessary for the safe handling, storage, transportation and disposal. Typical combustion characteristics for process safety include auto ignition temperature(AIT). The AIT is an important index for the safe handling of combustible liquids. The AIT is the lowest temperature at which the material will spontaneously ignite. In this study, the AITs and ignition delay times of n-pentanol and p-xylene mixture were measured by using ASTM E659 apparatus. The AITs of n-pentanol and p-xylene which constituted binary system were $285^{\circ}C$ and $557^{\circ}C$, respectively. The experimental AITs and ignition delay times of n-pentanol and p-xylene mixture were a good agreement with the calculated AITs and ignition delay times by the proposed equations with a few A.A.D. (average absolute deviation). Therefore, it is possible to estimate the AITs and ignition delay times in other compositions of n-pentanol and p-xylene mixture by using the predictive equations which presented in this study.

A simplified phase diagram in the ternary system $Y_2O_3-Ta(Nb)_2O_5-ZrO_2$ ($Y_2O_3-Ta(Nb)_2O_5-ZrO_2$ 삼성분계 상태도)

  • 이득용;김대준;장주웅;이명현
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.3
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    • pp.377-383
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    • 1997
  • Yttria-stabilized TZP alloyed with pentavalent oxides $(Ta_2O_5,\;Nb_2O_5)$ were fabricated by the conventional sintering method at $1500^{\circ}C$ in air to construct the simplified ternary phase diagram. The phase stability of tetragonal -$ZrO_2$ from the quasi-binary system $ZrO_2-YTa(Nb)O_4$, which do not transform to monoclinic-$ZrO_2$ even for a wide range of grain size and annealing temperature, was investigated to determine composition region of the non-transformable $t-ZrO_2$ solid solution$(NT_{ss})$. Phase stability of $NT_{ss}$ was probably due to the enhanced stability of $_YTa(Nb)O4$ having the tetragonal fergusonite structure. It was experimentally found that mixtures having $NT_{ss}$ alloyed with $T_{ss}$ by weight%% showed both excellent phase stability of $t-ZrO_2$ and fracture toughness even though the calculated composition of the mixture /was located outside $NT_{ss}$ composition region.

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The Condensation Pressure Drop of Alternative Refrigerants for R-22 in Small Diameter Tubes (세관내 R-22 대체냉매의 응축압력강항에 관한 연구)

  • O, Hu-Gyu;Son, Chang-Hyo;Choe, Yeong-Seok;Kim, Gi-Su
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.9
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    • pp.1245-1252
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    • 2001
  • The condensation pressure drop for pure refrigerants R-22, R-134a, and a binary refrigerant mixture R-410A flowing in a small diameter tube was investigated. The test section is a counterflow heat exchanger with refrigerant flowing in the inner tube and coolant flowing in the annulus. The test section consists of 1220 [mm] length with horizontal copper tube of 3.38 [mm] outer diameter and 1.77 [mm] inner diameter. The refrigerant mass fluxes ranged from 450 to 1050 [kg/(㎡$.$s)] and the average inlet and outlet qualities were 0.05 and 0.95, respectively. The main experimental results were summarized as follows : In the case of single-phase flow, the pressure drop of R-134a is much higher than that of R-22 and R-410A for the same Reynolds number. The friction factors for small diameter tubes are higher than those predicted by Blasius equation. In the case of two-phase flow, the pressure drop increases with increasing mass flux and decreasing quality. The pressure drop of R-134a is much higher than that of R-22 and R-410A for the same mass flux. Most of correlations proposed in the large diameter tube showed enormous deviations with experimental data. However, the correlation predicted by Honda et al showed relatively good agreement with experimental data for R-134.

Mechanical Properties of the High Flowing Self-Compacting Concrete for Members of Bridge Overcrowded Arrangement of Bar (과밀 배근된 교량 부재용 초유동 자기충전 콘크리트의 역학적 특성)

  • Choi, Yun-Wang;Kim, Yong-Jic;Kang, Hyun-Jin
    • Journal of the Korea Concrete Institute
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    • v.20 no.2
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    • pp.175-183
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    • 2008
  • Domestically, application of High Flowing Self-Compacting Concrete (HSCC) is limited to building structures and it is difficult to find examples of application in civil infrastructural constructions. However, in the case of North America and Europe, by introducing precast and prestressed system, HSCC is being used for high-density reinforced bridge members. Hence it is assessed that broadening the utilization of HSCC into areas such as bridges and civil construction is required. Therefore in this research, to apply HSCC to high-density reinforced bridge members, ground granulated blast-furnace slag and fly ash were mixed in binary and ternary systems. Also the dynamical characteristics of HSCC, following 1st class regulations of Japan Society of Civil Engineers (JSCE), were assessed to enable application on high-density reinforced structures. The test results revealed ternary system mixture showed better mechanical characteristics than binary system mixture and the application on high-density reinforced precast bridge members seems possible.

The study on the properties of binary mixture(crystalline silica/AIN) filled EMC(Epoxy Molding Compounds) (결정성 실리카/질화 알루미늄 혼합충진에 따른 EMC의 물성 연구)

  • 김원호;홍용우;배종우;황영훈;김부웅
    • Journal of the Microelectronics and Packaging Society
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    • v.6 no.4
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    • pp.41-48
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    • 1999
  • Silica is the most popular materials as a filler of EMC for microelectronic packaging. However, because of its low thermal conductivity, the use of silica is restricted to parts requiring high thermal dissipation. The superior fluidity of EMC can be achieved with a combination of filler size distribution. In this study, physical properties of EMC filled with the crystalline silica(13$\mu\textrm{m}$) which have high fluidity and low cost and the AlN(2 $\mu\textrm{m}$) which have high thermal conductivity and low coefficient of thermal expansion were evaluated by changing the AlN/silica ratios. As a result of the evaluation of physical properties of EMC, the optimum mixing ratio of AlN/crystalline silica was 0.3/0.7. In this condition, binary mixture(AlN/crystalline silica) filled EMC showed superior properties, i.e., in the thermal conductivity, CTE, dielectric constant, flexural strength, and thermal shock resistance without reduction of fluidity.

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Voice-Based Gender Identification Employing Support Vector Machines (음성신호 기반의 성별인식을 위한 Support Vector Machines의 적용)

  • Lee, Kye-Hwan;Kang, Sang-Ick;Kim, Deok-Hwan;Chang, Joon-Hyuk
    • The Journal of the Acoustical Society of Korea
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    • v.26 no.2
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    • pp.75-79
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    • 2007
  • We propose an effective voice-based gender identification method using a support vector machine(SVM). The SVM is a binary classification algorithm that classifies two groups by finding the voluntary nonlinear boundary in a feature space and is known to yield high classification performance. In the present work, we compare the identification performance of the SVM with that of a Gaussian mixture model(GMM) using the mel frequency cepstral coefficients(MFCC). A novel means of incorporating a features fusion scheme based on a combination of the MFCC and pitch is proposed with the aim of improving the performance of gender identification using the SVM. Experiment results indicate that the gender identification performance using the SVM is significantly better than that of the GMM. Moreover, the performance is substantially improved when the proposed features fusion technique is applied.

Effect of CQ-amine ratio on the degree of conversion in resin monomers with binary and ternary photoinitiation systems

  • Moon, Ho-Jin;Shin, Dong-Hoon
    • Restorative Dentistry and Endodontics
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    • v.37 no.2
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    • pp.96-103
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    • 2012
  • Objectives: This study evaluated the effect of camphorquinone (CQ)-amine ratio on the C=C double bond conversion of resins with binary and ternary photoinitiation systems. Materials and Methods: Two monomer mixtures (37.5 Bis-GMA/37.5 Bis- EMA/25 TEGDMA) with binary systems (CQ/DMAEMA in weight ratio, group A [0.5/1.0] and B [1.0/0.5]) and four mixtures with ternary system (CQ/OPPI/DMAEMA, group C [0.1/1.0/0.1], D [0.1/1.0/ 0.2], E [0.2/1.0/0.1] and F [0.2/1.0/0.2]) were tested: 1 : 2 or 2 : 1 CQ-amine ratio in binary system, while 1 : 1 ratio was added in ternary system. The monomer mixture was cured for 5, 20, 40, and 300 sec with a Demetron 400 curing unit (Demetron). After each exposure time, degree of conversion (DC) was estimated using Fourier transform infrared (FTIR) spectrophotometer (Nicolet 520, Nicolet Instrument Corp.). The results were analyzed by ANOVA followed by Scheffe test, with p = 0.05 as the level of significance. Results: DC (%) was expressed in the order of curing time (5, 20, 40, and 300 sec). Group A ($14.63{\pm}10.42$, $25.23{\pm}6.32$, $51.62{\pm}2.69$, $68.52{\pm}2.77$); Group B ($4.04{\pm}6.23$, $16.56{\pm}3.38$, $37.95{\pm}2.79$, $64.48{\pm}1.21$); Group C ($16.87{\pm}5.72$, $55.47{\pm}2.75$, $60.83{\pm}2.07$, $68.32{\pm}3.31$); Group D ($23.77{\pm}1.64$, $61.05{\pm}1.82$, $65.13{\pm}2.09$, $71.87{\pm}1.17$); Group E ($28.66{\pm}2.92$, $56.68{\pm}1.33$, $60.66{\pm}1.17$, $68.78{\pm}1.30$); Group F ($39.74{\pm}6.31$, $61.07{\pm}2.58$, $64.22{\pm}2.29$, $69.94{\pm}2.15$). Conclusion: All the monomers with ternary photoinitiation system showed higher DC than the ones with binary system, until 40 sec. Concerning about the effect of CQ-amine ratio on the DC, group A converted into polymer more than group B in binary system. However, there was no significant difference among groups with ternary system, except group C when cured for 5 sec only.