• Title/Summary/Keyword: Binary Mixture

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A Study on Operating Characteristics of the Two-Phase Closed Thermosyphon with a Binary Mixture (2성분 혼합물을 사용한 2상 밀폐 열싸이폰의 작동특성에 관한 연구)

  • 곽희열;김종보
    • Journal of Energy Engineering
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    • v.4 no.1
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    • pp.95-102
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    • 1995
  • 작동유체로서 비등점이 서로 다른 2종류, 즉 2성분 혼합물을 사용한 2상 밀폐 열싸이폰은 단일성분의 열싸이폰 보다 공학적으로 우수한 성능을 갖는다. 따라서 상 분리 현상이 나타나지 않은 안정적인 혼합물인 물/에탄올의 혼합물을 작동유체로 사용한 열싸이폰의 작동특성이 실험적으로 수행되었다. 실험에서는 시동성, 정상상태 작동, 경사시 작동특성 및 열전달 한계(Dry-out) 등에 관한 2성분 열싸이폰의 작동특성에 관해서 고찰되었다.

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Electrical Properties of PVdF/PVP Composite Filled with Carbon Nanotubes Prepared by Floating Catalyst Method

  • Kim, Woon-Soo;Song, Hee-Suk;Lee, Bang-One;Kwon, Kyung-Hee;Lim, Yun-Soo;Kim, Myung-Soo
    • Macromolecular Research
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    • v.10 no.5
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    • pp.253-258
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    • 2002
  • The multi-wall carbon nanotubes (MWNTs) with graphite crystal structure were synthesized by the catalytic decomposition of a ferrocene-xylene mixture in a quartz tube reactor to use as the conductive filler in the binary polymer matrix composed of poly(vinylidene fluoride) (PVdF) and poly(vinyl pyrrolidone) (PVP) for the EMI (electromagnetic interference) shielding applications. The yield of MWNTS was significantly dependent on the reaction temperature and the mole ratio of ferrocene to xylene, approaching to the maximum at 800 $^{\circ}C$ and 0.065 mole ratio. The electrical conductivity of the MWNTs-filled PVdF/PVP composite proportionally depended on the mass ratio of MWNTs to the binary polymer matrix, enhancing significantly from 0.56 to 26.7 S/cm with the raise of the mass ratio of MWNTs from 0.1 to 0.4. Based on the higher electrical conductivity and better EMI shielding effectiveness than the carbon nanofibers (CNFs)-filled coating materials, the MWNTs-filled binary polymer matrix showed a prospective possibility to apply to the EMI shielding materials. Moreover, the good adhesive strength confirmed that the binary polymer matrix could be used for improving the plastic properties of the EMI shielding materials.

The Study of Physical Properties for the Organic Compounds and their Binary Mixture according to Molecular Connectivity Method (Molecular Connectivity法을 이용한 有機化合物과 二成分 混合物에 對한 物理化學的 性質에 關한 硏究 (Ⅱ))

  • Ui-Rak Kim;Kyung-Sub Min;Myung-Jae Lee;Sang-Hae Kim;Bong-Jin Jeong
    • Journal of the Korean Chemical Society
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    • v.36 no.4
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    • pp.485-495
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    • 1992
  • The viscosities of organic compounds (alcohols, acetates, alkanes, acids, substituted $NH_2$) in liquid states, gas states and the binary mixtures of n-alkane / 1-chloroalkane were calculated by molecular modeling techniques. The molecular descriptors of molecular modeling technique are Molecular connectivity indices, Wiener indices and ad hoc descriptors, which can encode the information of compound properties about the effect of size, branching, cyclization, unsaturation, heteroatom content, polarizability, and so on. The successful results among method have been Molecular connectivity indices, binary mixtures of n-alkane / 1-chloroalkane, Wiener indices for gas state and ad hoc descriptor for liquid states. Also we obtained the regression equations for viscosities using molecular modeling indices for gas, liquid states and binary mixtures of n-alkane / 1-chloroalkane. The calculated viscosity values for organic compounds are in good agreement with experimental results.

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Visualization of Flow Characteristics on Thermosyphon with Immiscible Binary Working Fluid (비 혼합 2유체 열사이폰의 유동 특성에 관한 가시적 연구)

  • Do, Sun Yub;Kang, Hawn Kook;Park, Seung Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.5
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    • pp.3022-3029
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    • 2015
  • This study presents experiments to visualize the internal flow and heat transfer characteristics of thermosyphon with immiscible of water-FC40 adopted as binary working fluid. Three different regimes depending on the amount of heat flux applied to the thermosyphon were observed: natural convection, pulse boiling, and continuous boiling. Boiling incipience took place in water, which has lower vapor pressure than FC40. During natural convection water was vaporized in liquid pool while liquid film flows were formed. On the other hand, meanwhile bubbles were generated in the liquid pool during pulse and continuous boiling, the binary working fluid of water-FC40 was observed as the mixture throughout a whole range of the thermosyphon.

Predicting sorptivity and freeze-thaw resistance of self-compacting mortar by using deep learning and k-nearest neighbor

  • Turk, Kazim;Kina, Ceren;Tanyildizi, Harun
    • Computers and Concrete
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    • v.30 no.2
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    • pp.99-111
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    • 2022
  • In this study, deep learning and k-Nearest Neighbor (kNN) models were used to estimate the sorptivity and freeze-thaw resistance of self-compacting mortars (SCMs) having binary and ternary blends of mineral admixtures. Twenty-five environment-friendly SCMs were designed as binary and ternary blends of fly ash (FA) and silica fume (SF) except for control mixture with only Portland cement (PC). The capillary water absorption and freeze-thaw resistance tests were conducted for 91 days. It was found that the use of SF with FA as ternary blends reduced sorptivity coefficient values compared to the use of FA as binary blends while the presence of FA with SF improved freeze-thaw resistance of SCMs with ternary blends. The input variables used the models for the estimation of sorptivity were defined as PC content, SF content, FA content, sand content, HRWRA, water/cementitious materials (W/C) and freeze-thaw cycles. The input variables used the models for the estimation of sorptivity were selected as PC content, SF content, FA content, sand content, HRWRA, W/C and predefined intervals of the sample in water. The deep learning and k-NN models estimated the durability factor of SCM with 94.43% and 92.55% accuracy and the sorptivity of SCM was estimated with 97.87% and 86.14% accuracy, respectively. This study found that deep learning model estimated the sorptivity and durability factor of SCMs having binary and ternary blends of mineral admixtures higher accuracy than k-NN model.

Mechanical Alloying Effect in Immiscible Cu30Mo70 Powders (비고용 Cu30Mo70계 혼합분말의 기계적 합금화 효과)

  • 이충효;이성희;이상진;권영순
    • Journal of Powder Materials
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    • v.10 no.1
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    • pp.46-50
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    • 2003
  • Lee et al. reported that a mixture of Cu and Ta, the combination of which is characterized by a positive heat of mixing, $\{Delta}H_{mix}$ of +2 kJ/㏖, can be amorphized by mechanical alloying(MA). It is our aim to investigate to what extent the MA is capable of producing a non-equilibrium phase with increasing the heat of mixing. The system chosen is the binary $Cu_{30}Mo_{70}$ with $\{Delta}H_{mix}$=+19 kJ/㏖. The mechanical alloying was carried out using a Fritsch P-5 planetary mill under Ar gas atmosphere. The vial and balls are made of Cu containing 1.8-2.0 wt.%Be to avoid contaminations arising mainly from Fe when steel balls and vial are used. The MA powders were characterized by the X-ray diffraction, EXAFS and thermal analysis. We conclude that two phase mixture of nanocrystalline fcc-Cu and bcc-Mo with grain size of 10 nm is formed by the ball-milling for a 3:7 mixture of pure Cu and Mo, the evidence for which has been deduced from the thermodynamic and structural analysis based on the DSC, X-ray diffraction and EXAFS spectra.

Consumer Acceptance of Three Rice Varieties Formulated by a Simplex-Lattice Mixture Design

  • Choi, In-Duck;Son, Jong-Rok;Hong, Ha-Cheol;Kim, Kee-Jong
    • Preventive Nutrition and Food Science
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    • v.11 no.1
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    • pp.78-83
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    • 2006
  • A simplex-lattice mixture design was applied to blend three varieties of rice; Ilpum (IP), Goami2 (G2) and Baegjinju (BJJ) all of which have very different physicochemical properties from one another. G2 and BJJ are mutant rice developed from IP. Increasing G2 portions in a rice blend increases indigestible carbohydrate contents. Blending at least 33.3% of G2 to either IP or BJJ increased indigestible carbohydrates, which were approximately $3.55{\pm}1.31\;to\;4.57{\pm}0.37$(g/100 g), respectively. Consumers rated higher than 6.0 (=like slightly) for the IP alone and binary blends of IP and BJJ, whereas less than 5.0 (=dislike moderately) for the blends containing G2 rice, indicating that consumers would not accept rice blends containing higher G2 portions. However, although blends with G2 were given lower consumer ratings, a rice blend with G2 could have health benefits in terms of nutritional and functional properties due to the higher indigestible carbohydrate contents.

Density Measurement of Liquid Mixture and Estimation of Excess Molar Volume by A Cubic Equation of State (액체혼합물의 밀도 측정과 3차 상태방정식에 의한 과잉 몰부피의 예측)

  • Kim, Jung-Min;Bae, Hyo-Kwang
    • Korean Chemical Engineering Research
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    • v.43 no.5
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    • pp.637-640
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    • 2005
  • The density of polar-nonpolar liquid mixtures composed of methyl tert-butyl ether(MTBE) and 2,2,4-trimethylpentane, and methyl ethyl ketone (MEK) and 2,2,4-trimethylpentane, and the density of polar-polar liquid mixture of MTBE and MEK were measured by densitometer at 278.15 K, 288.15 K and 298.15 K, respectively. The excess molar volume of the binary systems calculated from the measured density was shown good agreement with the calculated one by the cubic Peng-Robinson- Stryjek-Vera (PRSV) equation of state together with Huron-Vidal mixing rule and it confirmed that the cubic PRSV equation of state could be used in the molar volume calculation of polar mixture.

Analysis on the non-equilibrium dendritic solidification of a binary alloy with back diffusion (역확산을 고려한 이원합금의 비평형 수지상응고 해석)

  • Jeong, Jae-Dong;Yu, Ho-Seon;Lee, Jun-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.10
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    • pp.3361-3370
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    • 1996
  • Micro-Macro approach is conducted for the mixture solidification to handle the closely linked phenomena of microscopic solute redistribution and macroscopic solidification behavior. For this purpose, present work combines the efficiency of mixture theory for macro part and the capability of microscopic analysis of two-phase model for micro part. The micro part of present study is verified by comparison with experiment of Al-4.9 mass% Cu alloy. The effect of back diffusion on the macroscopic variables such as temperature and liquid concentration, is appreciable. The effect, however, is considerable on the mixture concentration and eutectic fraction which are indices of macro and micro segregation, respectively. According to the diffusion time, the behavior near the cooling wall where relatively rapid solidification permits short solutal diffusion time, approaches Scheil equation limit and inner part approaches lever rule limit.

Interaction of Solid Particles with the Solidifying Front in the Liquid-Particle Mixture (액상-고체입자 혼합물의 응고 시 응고계면에서의 입자의 거동)

  • Lee, Ho-Suk;Lee, Kyu-Hee;Oh, Sung-Tag;Kim, Young Do;Suk, Myung-Jin
    • Journal of Powder Materials
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    • v.25 no.4
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    • pp.336-339
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    • 2018
  • A unique porous material with controlled pore characteristics can be fabricated by the freeze-drying process, which uses the slurry of organic material as the sublimable vehicle mixed with powders. The essential feature in this process is that during the solidification of the slurry, the dendrites of the organic material should repel the dispersed particles into the interdendritic region. In the present work, a model experiment is attempted using some transparent organic materials mixed with glass powders, which enable in-situ observation. The organic materials used are camphor-naphthalene mixture (hypo- and hypereutectic composition), salol, camphene, and pivalic acid. Among these materials, the constituent phases in camphor-naphthalene system, i.e. naphthalene plate, camphor dendrite, and camphor-naphthalene eutectic exclusively repel the glass powders. This result suggests that the control of organic material composition in the binary system is useful for producing a porous body with the required pore structure.