• Title/Summary/Keyword: Binary Alloys

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Estimation of surface tension of liquid alloys under different oxygen partial pressure

  • Min, Sun-Gi;Lee, Jun-Ho
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2008.11a
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    • pp.101-101
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    • 2008
  • The effect of oxygen partial pressure on the surface tension data of liquid alloys was investigated by means of comparing the calculated data and the measured one. Two binary alloy systems were chosen to observe the dependence of oxygen adsorption behavior on different oxygen partial pressures. It was found that the difference between the computed values and the experimental of the surface tension was within the range of maximum 10%.

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A Calorimetric Study on the Martensitic Transformation Characteristics with Chemical Composition and Thermal Cycling in Cu-Zr Binary Alloys (Cu-Zr이원계 합금에서 화학조성 및 열싸이클링에 따른 마르텐사이트변태 특성의 열분석학적 연구)

  • Jang, W.Y.;van Humbeeck, J.;Jo, M.S.;Lee, J.H.;Lee, Y.S.;Kang, J.W.;Gwak, S.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.11 no.2
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    • pp.111-120
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    • 1998
  • The effects of chemical composition and thermal cycling on the martensitic transformation characteristics in Cu-rich, equiatomic and Zr-rich CuZr binary alloys have been studied by calorimetry. Only martensite could be indentified in equiatomic $Cu_{49.9}Zr_{50.1}$ alloy, while $Cu_{10}Zr_7$ and $CuZr_2$ intermetallic compounds as well as martensite were formed by rapid cooling from the melts in Cu-rich $Cu_{52.2}Zr_{47.5}$ alloy and Zr-rich $Cu_{48.4}Zr_{51.6}$ alloy, respectively. The $M_s$ temperature of $Cu_{49.9}Zr_{50.1}$ was $156^{\circ}C$ but those of $Cu_{52.5}Zr_{47.5}$ and $Cu_{48.4}Zr_{51.6}$ alloys, being $109^{\circ}C$ and $138^{\circ}C$, were lower than that of equiatomic $Cu_{49.9}Zr_{50.1}$ alloy. In all the alloys, the $M_s$ temperature has fallen but the $A_s$ temperature has risen, resulting in widening of the transformation hysteresis with thermal cycling. The anomalous characteristics in the transformation temperature are due to the presence of the intermetallic compounds i.e. $Cu_{10}Zr_7$ and $CuZr_2$ formed by an eutectoid reaction during thermal cycling in the temperature range between $-100^{\circ}C$ < $T_c$ < $400^{\circ}C$.

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Microstructure Change and Mechanical Properties in Binary Ti-Al Containing Ti3Al

  • Oh, Chang-Sup;Woo, Sang-Woo;Han, Chang-Suk
    • Korean Journal of Materials Research
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    • v.26 no.12
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    • pp.709-713
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    • 2016
  • Grain morphology, phase stability and mechanical properties in binary Ti-Al alloys containing 43-52 mo1% Al have been investigated. Isothermal forging was used to control the grain sizes of these alloys in the range of 5 to $350{\mu}m$. Grain morphology and volume fraction of ${\alpha}_2$ phase were observed by optical metallography and scanning electron microscopy. Compressive properties were evaluated at room temperature, 1070 K, and 1270 K in an argon atmosphere. Work hardening is significant at room temperature, but it hardly took place at 1070 K and 1270 K because of dynamical recrystallization. The grain morphologies were determined as functions of aluminum content and processing conditions. The transus curve of ${\alpha}$ and ${\alpha}+{\gamma}$ shifted more to the aluminum-rich side than was the case in McCullough's phase diagram. Flow stress at room temperature depends strongly on the volume fraction of the ${\alpha}_2$ phase and the grain size, whereas flow stress at 1070 K is insensitive to the alloy composition or the grain size, and flow stress at 1270 K depends mainly on the grain size. The ${\alpha}_2$ phase in the alloys does not increase the proof stress at high temperatures. These observations indicate that improvement of both the proof stress at high temperature and the room temperature ductility should be achieved to obtain slightly Ti-rich TiAl base alloys.

Application of Fe-Mn High Damping Alloys for Reduction of Noise and Vibration in Power Plants (Fe-Mn 방진합금을 적용한 발전소 격납용기 살수펌프의 소음$\cdot$진동 저감효과에 관한 연구)

  • 백승한
    • Journal of KSNVE
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    • v.9 no.4
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    • pp.720-729
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    • 1999
  • Coventional methods for reducing vibration in engineering designs (i.e. by stifferning or detuning) may be undesirable in conditions where size or weight must be minimized, or where complex vibration spectra exist. Some alloys with a combination of high damping capacity and good mechanical properties can provide attractive techanical and economical solutions to problems involving seismic, shock and vibration isolation. Although several non ferrous damping alloys have been developed, none of those materials are applied in any industrial factor due largely to high production cost. To meet these requirement, we have developed a new Fe-Mn high damping alloy. In previous studies, we have reported that an Fe-17%Mn alloy exhibits the highest damping capacity(Specific Damping Capacity:SDC, 30%) among Fe-Mn binary system, and proposed that the boundaries of various types such as $\varepsilon$-martensite variant boundaries, stacking faults in $\varepsilon$-martensite, stacking faults in austenitic and ${\gamma}$$\gamma /\varepsilon$ interfaces give rise to a high damping capacity. The Fe-17%Mn alloy also has advantages of good mechanical properties(T.S. 70 kg/nm$^2$ and low cost over other damping alloys(1/4 times the cost of non-ferrous damping alloy). Thus, the Fe-17%Mn high damping alloy can be widely applied to household appliances, automobiles, industrial facilities and power plant components. In this paper, the overall properties of the Fe-17%Mn high damping alloy is introduced, and its applicability to containment spray pump in the power plant is discussed.

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A Study on the Microstructures of Rapidly Solidified Ti-($45{\sim}58at%$)Al Intermetallic Compound (급속응고된 TiAl 금속간화합물의 Al함량 변화에 따른 미세조직변화에 관한 연구)

  • Kim, Jae-Hoon;Jeoung, Tae-Ho;Nam, Tae-Woon
    • Journal of Korea Foundry Society
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    • v.18 no.6
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    • pp.550-554
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    • 1998
  • The microstructures of rapidly solidified binary Ti-Al alloys containing $45{\sim}58\;at%Al$ have been studied using C/S (carbon/sulfur), N/O (nitrogen/oxygen) analyser, X-ray fluorescence spectrometer (XRF), X-ray diffractometer (XRD), optical microscope (OM) and scanning electron microscope (SEM). The phases present in the alloys and their distribution were found to be a sensitive function of Al content. Essentially single-phase (${\gamma}$) microstructures were observed to alloys with 45 at%Al, 55 at%Al and 58 at%Al. In other content alloys, two phase (${\alpha}_2$, ${\gamma}$) microstructures were observed. The 48 at%Al, 52 at%Al alloys contain (${\gamma}+{\alpha}_2$) phase and ${\alpha}_2$ phase. These results indicate that rapid solidification affect the solidification path, then metastable phase forming during solidification.

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Effects of Hafnium Addition on the Pitting Corrosion Behavior of Ti Alloys in Electrolyte Containing Chloride Ion (염소이온 함유된 용액에서 Ti합금의 부식특성에 미치는 Hafnium함량의 영향)

  • Kim, Sung-Hwan;Choe, Han-Cheol
    • Corrosion Science and Technology
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    • v.11 no.5
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    • pp.191-195
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    • 2012
  • The aim of this study was to investigate effects of hafnium content on the corrosion behavior of Ti alloys in electrolyte containing chloride ion. For this study, Ti-Hf binary alloys contained 10 wt%, 20 wt% and 30 wt% Hf were manufactured in a vacuum arc-melting furnace and subjected to heat treatment for 12h at $1000^{\circ}C$ in an argon atmosphere. The pitting corrosion behavior of the specimens was examined through potentiodynamic and potentiostatic tests in 0.9 wt% NaCl electrolyte at $36.5{\pm}1^{\circ}C$. The corrosion morphology of Ti-xHf alloys was investigated using optical microscopy (OM) and X-ray diffractometer (XRD). From the optical microstructures and XRD results, needle-like martensite ($\alpha$') phases of the Ti-xHf alloys increased with an increase of Hf addition. Corrosion current density $(I_{corr})$ and current density $(I_{300mV})$ in passive region decreased, whereas, corrosion potential increased with Hf content. At the constant potential ($300mV_{SCE}$), current density decreased as time increased.

A Study on the Welding Process of Aluminum Alloy (알루미늄합금 용접공정기술 연구)

  • Kim Namin;Lim Dong-Yong;Lee Jeong-Soo;Choe Woo-Hyeon
    • Special Issue of the Society of Naval Architects of Korea
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    • 2005.06a
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    • pp.211-215
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    • 2005
  • The binary Al-Mg alloys are the basis for the 5000 series of non-heat-treatable aluminum alloys. In general, 5000 series of aluminum alleys have a high strength, good welding characteristics and a high resistance to corrosion, especially under the seawater. Thus the aluminum alloys are adopted in the hull material of hovercraft that is required light in weight as well as high strength. It is very important that the weldability problem of these alloys caused by high thermal conductivities welding deformation, porosity and so on. in this study, auto-welding equipment was applied for aluminum welding automation. Also, optimal welding data were studied by investigating welding characteristics for various shapes of weldment to use Al 5083 that is representative structural materials of the 5000 series of aluminum alloys.

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Development of High Damping Alloys for Reduction of Noise and Vibration (소음.진동 제어를 위한 방진합금 개발)

  • Baik, Seung-Han;Kim, Jung-Chul;Han, Dong-Woon;Baik, Jin-Hyun;Kim, Tai-Hoon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2004.11a
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    • pp.565-569
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    • 2004
  • Conventional methods for reducing vibration in engineering designs (i.e. by stiffening or detuning) may be undesirable or inadequate in conditions where size or weight must be minimized or where complex vibration spectra exist. Alloys which combine high damping capacity with good mechanical properties can provide attractive technical and economic solutions to problems involving seismic, shock and vibration isolation. To meet these trends, we have developed a new high damping Fe-17%Mn alloys. Also, the alloy has advantages of good mechanical properties and more economical than any other known damping alloys(1/4 times as cost of non-ferrous damping alloy). Thus, the high damping Fe-17%6Mn alloy can be widely applied to household appliances, automobiles, industrial facilities and power plant components with its excellent damping capacity(SDC, 30%) and mechanical property(T.S 700MPa). It is the purpose of this paper to introduce the characterization of the high damping Fe-17%Mn alloy and the results of retrofit several such applications.

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An Evaluation on the Weldability of Al-Li Alloys by Varestraint Testing Method (Varestraint Test법에 의한 Al-Li합금의 용접성 평가)

  • 김형태;이창배;신현식;서창제
    • Journal of Welding and Joining
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    • v.14 no.6
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    • pp.48-57
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    • 1996
  • The weldability of high purity aluminum-lithium binary alloys has been investigated using the Varestraint test. Autogenous GTAW (gas-tungsten-arc-welds) were run along specimens of different lithium concentration using three sets of welding parameters. Welding voltage was held constant at 10 volts. Welding current (70∼100 amps) and travel speed (23∼33 cm/min) were the parameter varied. Hot-tearing susceptibility varied with lithium content and exhibited a steep peak at 2.6 weight percent lithium. Depth of penetration increased with increasing heat input and lithium concentration. The susceptibility is influenced by the wettability of dendrites by the interdendritic eutectic liquid as well as the time available for back-Siting by eutectic liquid. The welding condition of welding current 70A and travel speed 23 cm/min was showed good resistance to cracking in aluminum-lithium alloys. Suggestions for improving weld cracking resistance are also provided.

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A Study on Mechanical Properties for Pb-free Solders of Electronic Packages (전자부품의 Pb-free 솔더에 대한 기계적 특성에 관한 연구)

  • 허우진;백승세;정영훈;권일현;양성모;유효선
    • Proceedings of the KWS Conference
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    • 2003.11a
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    • pp.83-85
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    • 2003
  • This paper is investigated the shear strength by using the micro shear-punch test method for Sn-37Pb alloy, binary and ternary alloys of environment-friendly Pb-free solder alloys which would be surely applicable to the electronic packages. As a result, in case of Max. shear strength, Sn-4Ag-0.5Cu has the highest value and Sn-37Pb has the lowest value on every condition of experiment temperature. Also, In case of Pb-free solder joint specimens, it was found that Pb-free solder alloys have higher value of shear strength than eutectic Sn-Pb solder alloy and Sn-4Ag-0.5Cu has the highest value.

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