• Title/Summary/Keyword: Bi2212

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Fabricatiion and Characterization of ${Bi_2}{Sr_2}{CaCu_2}{O_8}$ Superconductor Thick Films on Cu Substrates using Cu-free Precursors (Cu-free 전구체를 이용하여 구리 기판 위에 ${Bi_2}{Sr_2}{CaCu_2}{O_8}$ 초전도 후막의 제조 및 특성)

  • 한상철;김상준;한영희;성태현;한병성
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.4
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    • pp.349-358
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    • 2000
  • Fabrication and Characterization of Bi$_{2}$/Sr$_{2}$/CaCu$_{2}$/O$_{8}$(Bi2212) superconductor thick films were fabricated successfully on C tapes by liquid reaction between Cu-free precursors of Bi$_{x}$/SrCaO/$_{y}$(x=1.2-2) and Cu tapes. Cu-free Bi-Sr-Ca-O powder mixtures were screen-printed on Cu tapes and heat-treated at 850-87$0^{\circ}C$ for several minutes in air oxygen nitrogen and low oxygen pressure. In order to obtain the optimum heat-treatment condition we studied the effect of the precursor composition the printing thickness and the heat-treatment atmosphere on the superconducting properties of Bi2212 films and the reaction mechanism. Microstructures and phases of thick films were analyzed by films and the reaction mechanism. Microstructures and phases of thick films were analyzed by optical microscope and XRD. The electric properties of superonducting films were examined by the four probe method. At heat-treatment temperature the thick films were in a partially molten state by liquid reaction between CuO of the oxidized copper tape and the precursors which were printed on Cu tapes. During the heat-treatment procedure Bi2212 superconducting particle nucleate and grow in preferred orientations.ons.s.

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Effect of Doping Elements on Superconducting Characteristics in Bi-system Ceramics (Bi계 세라믹에서 초전도체 특성에 미치는 도우핑 원소의 영향)

  • 양승호;박용필;김용주
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.198-203
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    • 2000
  • This paper investigated the effects of doping elements on the Bi-Sr-Ca-Cu-O ceramics. The doping elements can be classified into four groups depending on their superconducting characteristics in the Bi-Sr-Ca-Cu-O structure. The first group of doping elements(Co, Fe, Ni and Zn) substitute into the copper site and can reduce the critical temperatures of the 2223 and 2212 phases. The second group of doping elements(Y and La) substitute into the Ca site and cause the disappearance of the 2223 phase and increase the critical temperatures in the 2212 phase. The third group of doping elements(P and K) have a tendency to decompose the superconducting phase and reduce the optimal sintering temperature. The fourth group of doping elements(B, Si, Sn and Ba) almost unaffected the superconductivity of the 2223 and 2212 phase.

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Deping characteristics of the Bi-Sr-Ca-Cu-O ceramics (Bi-Sr-Ca-Cu-O 세라믹의 도우핑 특성)

  • 박용필;김영천;황석영
    • Electrical & Electronic Materials
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    • v.9 no.1
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    • pp.1-8
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    • 1996
  • We investigated the effects of doping elements on the Bi-Sr-Ca-Cu-O ceramics. The doping elements can be classified into four groups depending on their supeconducting characteristics in the Bi-Sr-Ca-Cu-O structure. The first group of doping elements(Co, Fe, Ni and Zn) substitute into the copper site and can reduce the critical temperatures of the 2223 and 2212 phases. The second group of doping elements(Y and La) substitute into the Ca site and cause the disappearance of the 2223 phase and increase the critical temperatures in the 2212 phase. The third group of doping elements(P and K) have a tendency to decompose the superconducting phase and reduce the optimal sintering temperature. The fourth group of doping elements(B, Si, Sn and Ba) almost unaffected the superconductivity of the 2223 and 2212 phase.

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Bi2212 Tube Characteristics for SCFCL (한류기용 Bi2212 튜브의 특성)

  • Lee, N.I.;Jang, G.E.;Oh, I.S.;Park, G.B.
    • Progress in Superconductivity
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    • v.7 no.2
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    • pp.174-178
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    • 2006
  • For the practical application on SCFCL, Bi2212 tubes were fabricated by Centrifugal Forming Process (CFP) in terms of many different processing parameters. Typical sizes of tubes were 60, 150 mm in length and 2.5, 3.5, 4.8 mm in thickness. Initially powder was melted by induction heating. The optimum range of melting temperatures and preheating temperature were $1100^{\circ}C$ and $500^{\circ}C$ for 30min respectively. The nominal mold rotating speed was around 1000 RPM. A tube was annealed at $840^{\circ}C$ for 80 hours in oxygen atmosphere. The tube of 50mm x 70mm x 2.5mm, rotated with 1000 RPM showed $I_c=890\;A\;and\;T_c=80$. It was found that the tube processed with faster rate of mold rotation speed, thinner tube thickness and shorter tube length shows better electric characteristics as compared with the tube normally processed. In order to study the uniformity heat and fluid flow analysis tool was adopted along tube.

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A study on the Joining Properties of Bi-2212 High-Tc Superconducting Tube and Indium Solder (Bi-2212 고온초전도튜브와 인듐솔더의 접합특성연구)

  • Oh, S.Y.;Hyun, O.B.;Kim, Chan-Joong
    • Progress in Superconductivity
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    • v.7 no.2
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    • pp.179-183
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    • 2006
  • As a material for SFCL(Superconducting Fault Current Limiter), BSCCO tube with metal stabilizer is a promising candidate, assuring the stability and large power capacity, For the application, the proper soldering technique, which overcome the difficulties of the joining between BSCCO and metal stabilizer, is required. In this study, after soldering In-Bi solder and In-Sn solder with BSCCO superconductor, welding properties between BSCCO and solders were investigated. Because ceramic materials is difficult to weld, Ag electro-plating on BSCCO 2212 is used for intermetallic layer. To find out the best welding condition for superconductor, soldering is tested in the maximum temperature from $155^{\circ}C\;to\;165^{\circ}C$ in the reflow oven. By investigating the composition and thickness of IMC (lntermetallic Compound) created in the reaction of Ag with solder, we analyzed the welding properties of High-Tc superconductor from a micro point of view.

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