• Title/Summary/Keyword: Bi-phase

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Effects of Bi on Mg2Si Modification and Mechanical Properties of Mg-Al-Si Alloy (Mg-Al-Si 합금에서 Mg2Si의 개량화 및 기계적 특성에 미치는 Bi의 영향)

  • Jun, Joong-Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.24 no.2
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    • pp.82-86
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    • 2011
  • The influences of Bi addition on morphological modification of $Mg_2Si$ phase and mechanical properties were investigated in Mg-7%Al-0.5%Si casting alloy. It was found that the addition of 0.3%Bi changed the $Mg_2Si$ morphology from coarse Chinese script type to polygonal type, and significantly decreased the size to ~5 ${\mu}m$ or less with the increase of number density. The modification of $Mg_2Si$ phase by the addition of Bi resulted in the improvement of tensile properties of the Mg-Al-Si alloy at RT and $175^{\circ}C$.

Thermodynamics for Formation of Each Stable Single Phase in Bi-superconductor Thin Films

  • Park, Yong-Pil;Kim, Gwi-Yeol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.1
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    • pp.64-68
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    • 2001
  • High quality BSCCO thin films have been fabricated by means of an ion beam sputtering at various substrate temperatures, T$\_$sub/, and ozone gas pressures, PO$_3$. The correlation diagrams of the BSCCO phases appeared against T$\_$sub/ and PO$_3$ are established in the 2212 and 2223 compositional films. In spite of 2212 compositional sputtering, Bi2201 and Bi2223 phases as well as Bi2212 one come out as stable phases depending on T$\_$sub/ and PO$_3$. From these results, the thermodynamic evaluations of ΔH and ΔS, which are related with Gibbs' free energy change for single Bi2212 or Bi2223 phase are performed.

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R-T Characteristic in BSCCO Thin Films (BSCCO 박막의 저항-온도 특성)

  • Cheon, Min-Woo;Yang, Sung-Ho;Park, Yong-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.05b
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    • pp.98-101
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    • 2005
  • BSCCO thin films fabricated by using the evaporation method. As a result, although the composition of Bi2212 was set up, the phase of Bi2201, Bi2212 and Bi2223 was formed. The formation area of these stable phases is indicated as inclined line in the direction of the right lower end from the Arrhenius plot of the substrate temperature-oxidation gas pressure, and are distributed in very small area. The activation energy for the phase transformation from the Bi2201 to the Bi2212 is estimated in terms of the Avrami equation.

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Superconducting Phase Formation and Properties in the Bi-Sr-Ca-Cu-O System (Bi-Sr-Ca-Cu-O 계에서 초전도체 상형성 및 특성)

  • Nam, Gung-Chan;Lee, Sang-Yun
    • Korean Journal of Materials Research
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    • v.6 no.6
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    • pp.543-554
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    • 1996
  • Bi-Sr-Ca-Cu-O 계에서 상형성에 관해 연구하였다. 임계온도가 80K인 초전도체는 Bi-Sr-Ca-Cu의 몰비율이 2:2:1:2의 성분으로부터 solid state synthesis의 방법으로 합성하였다. 이때 이상에 대한 x-ray diffraction pattern은 모두 색인하였다. 2:2:1를 기본으로한 solid solution의 형성을 Bi2Sr2-xCa1+yCu2O8+$\delta$으로 단일상(single phase)을 형성하고 있으며, 이때 x와 y의 범위는 0

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Synthesis of Bismuth Vanadate as Visible-light Photocatalyst by Precipitation Reaction (침전 반응에 의한 가시광 광촉매 Bismuth Vanadate 합성)

  • Kim, Sang-Mun;Lee, Jae-Yong;Mun, Choo-Yeun;Lee, Hean-Soo
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.630-635
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    • 2011
  • Bismuth vanadate($BiVO_4$) with monoclinic phase as photocatalyst under visible light is synthesized by precipitation reaction in hot water. Properties such as crystal phase, particle morphology and visual light absorbance as well as the effects of thermal treatment for $BiVO_4$ powders are investigated. $BiVO_4$ powders with both single monoclinic phase and 0.2 ${\mu}m$ in particle size are synthesized when precipitate is stirred in water for 5 h at 95$^{\circ}C$. Well-developed monoclinic phase and light absorption property under 535 nm are observed as a result of thermal treatment for 1 h at 300$^{\circ}C$ after precipitation reaction in water for 5 h at 95$^{\circ}C$. Degradation of monoclinic crystal is found in firing above 350$^{\circ}C$, and particle growth is occurred in firing above 550$^{\circ}C$.

A Simple Resonant DC Link Snubber-Assisted Bi-directional Three-phase PWM Converter for Battery Energy Storage Systems

  • Hiraki, Eiji;Nakaoka, Mutsuo
    • KIEE International Transaction on Electrical Machinery and Energy Conversion Systems
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    • v.2B no.3
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    • pp.133-139
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    • 2002
  • In this paper, a prototype of an active auxiliary quasi-resonant DC link (QRDCL) snubber assisted voltage source bidirectional power converter (AC to DC and DC to AC) operating at zero voltage soft-switching (BVS) PWM nlode is presented for a Battery Energy Storage System (BESS). The operating principle of this QRDCL circuit and multifunctional control-based converter system, including PWM inverter mode in which energy flows from the battery bank to the three-phase utility-grid in addition to an active PWM converter mode in which energy flows from the utility-grid to the battery banks are described respectively by the control implementation on the basis of d-q coordinate plane transformation. The multifunctional operation characteristics of this three-phase ZVS PWM bi-directional converter with QRDCL is demonstrated fer a BESS under the power conditioning and processing schemes of energy supply mode and energy storage mode, and compared with a conventional three-phase hard switching PWM bi-directional converter for a BESS. The effectiveness of the three-phase ZVS PWM hi-directional converter with QRDCL is proven via the simulation analysis.

Preparation of High Tc Superconductor Powders by Emulsion Drying Method (Emulsion 건조방법에 의한 고온초전도체 분말제조)

  • Eom, Woo-Sik;Kim, Ho-Gi
    • Korean Journal of Materials Research
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    • v.1 no.2
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    • pp.71-76
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    • 1991
  • The superconducting powders in $YBa_2Cu_3O_{7-x}$ and Bi-Pb-Sr-Ca-Cu-O system were easily prepared from water in oil type emulsion by loading each cation into the aqueous phase. In $YBa_2Cu_3O_{7-x}$ system, the superconducting orthorhombic phase was formed by calcining at $750^{\circ}C$ for 10h in $O_2$. The size of the superconducting phase powders was submicron. The density of the sintered specimen using this powders was about 95% of the theoretical density and the resistance sharply decreases at about 90K, In Bi-Pb-Sr-Ca-Cu-O system the low Tc phase($(Bi, Pb)_2Sr_2Ca_1Cu_2O_y$) was formed by calcining at $800^{\circ}C$ for 10h in a low oxygen partial pressure of 1/20 atm The shape of clacined powder is thin plate of which size is about $2\mu\textrm{m}$ and thickness is smaller than $\mu\textrm{m}$. It was observed that the high Tc phase ($(Bi, Pb)_2Sr_2Ca_2Cu_3O_y$) was formed by sintering at $850^{\circ}C$ for 30h in oxygen pressure of 1/20 atm without intermediary grinding. The above sintered sample exhibited superconductivity with a Tc(zero)=105K.

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Effect of Na Substitution for the Ca Site in the Bi$_2$Sr$_2$Ca$_{1-x}$Na$_x$Cu$_2$O$_{8+y}$ Superconductors (Bi$_2$Sr$_2$Ca$_{1-x}$Na$_x$Cu$_2$O$_{8+y}$ 산화물 고온초전도체의 Ca 위치에 Na 치환 효과)

  • 이민수;송승용;이종용;송기영;최봉수
    • Journal of the Korean Ceramic Society
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    • v.35 no.10
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    • pp.1007-1013
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    • 1998
  • The samples of Bi2Sr2Ca1-xNaxCu2O8+y with various carrier concentration were synthesized by substituting Na for Ca ion. The superconducting properties hall coefficients and X-ray powder diffraction were measur-ed the sampled. Single phase samples were obtained for 0$\leq$x<0.3 of Bi2Sr2Ca1-xNaxCu2O8+y In the single phase the critical temperature. {{{{ { T}_{c } }} and carrier concentration increase with the increase of Na concentration pass through a maximum and then decreases. In the range of x$\geq$0.7 to the Na doped samples however we observed the metal-semiconductor transition. The c-axis seemed to decrease and a and b-axes increase with increasing Na concentration in the single phase. Decreasing of c-axis while increasing x is due to the smaller size of {{{{ {Na}^{+1 } }} ions to the {{{{ { Ca}^{+2 } }} ions. In the range of x>0.3 however the trend becomes ambiguous due to the inclusion of the 10K phase and impurity phase.

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Research on a 2.5kW 8-Phase Bi-directional Converter for Mild Hybrid Electric Vehicles (마일드 하이브리드 전기 차량용 2.5kW급 8상 양방향 컨버터에 관한 연구)

  • Lim, Jae-Woo;Kim, Hee-Jun;Choi, Jun-Sam
    • Transactions of the Korean Society of Automotive Engineers
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    • v.25 no.1
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    • pp.82-91
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    • 2017
  • This paper is a study on the bi-directional DC-DC converter, one of the key elements of 48V-12V dual systems in mild hybrid electric vehicles. Mild hybrid electric vehicles require a bi-directional DC-DC converter that can efficiently transmit power in two directions between a 48V battery and a 12V battery. To develop a bi-directional DC-DC converter with better price competitiveness, upgraded fuel economy, excellent performance and smaller size, this study designed, produced and presented a circuit that improved on the existing one. In the proposed 8-phase bi-directional DC-DC converter, the size of the passive element was reduced through the 8-phase interleaved topology, whereas downscaling had previously posed a difficulty. This study also designed and produced a 2.5kW class prototype. Based on the proposed 8-phase interleaved topology, a size of 227.5 (W) * 172 (L) * 64.35 (H) was achieved. In the boost mode operation and buck operation modes, the maximum efficiency was recorded at 94.04 % and 95.78 %, respectively.

Characteristics of Sticking Coefficient in BSCCO Thin Film

  • Cho, Choon-Nam;Ahn, Joon-Ho;Oh, Jae-Han;Choi, Woon-Shik;Park, Yong-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.10a
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    • pp.59-63
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    • 2000
  • BSCCO thin films are fabricated via a co-deposition process by an ion beam sputtering with an ultra-low growth rate, and sticking coefficients of the respective elements are evaluated. The sticking coefficient of Bi element exhibits a characteristic temperature dependence : almost a constant value of 0.49 below $730^{\circ}C$ and decreases linearly with temperature over $730^{\circ}C$ This temperature dependence can be elucidated from the evaporation and sublimation rates of bismuth oxide, $Bi_2O_3$, from the film surface. It is considered that the liquid phase of the bismuth oxide plays an important role in the Bi(2212) phase formation in the co-deposition process.

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