• 대한용접접합학회:학술대회논문집
• /
• 대한용접접합학회 2005년도 추계학술발표대회 개요집
• /
• pp.262-264
• /
• 2005

$Bi_{2}Sr_{2}CaCu_{2}O_{x}$(Bi-2212) and $Bi_{2}Sr_{2}Ca_{2}Cu_{3}O_{y}$(Bi-2223) high-$T_{c}$ superconductor(HTS) coating have been prepared by plasma spraying and heaat treatment. The Bi-2212 HTS coating later is synthesized through the peritectic reaction between Sr-Ca-Cu oxide coating layer and Bi-Cu oxide coating later, and $Bi_{2}Sr_{2}CaCu_{2}O_{y}$(Bi-2212) superconducting phase grow by partial melting process. The superconducting characteristic depends strongly on the conditions of the partial melting process. the Bi-2212 HTS layer consists of the whiskers grown in the diffusion direction. Above the 2212 layer, Bi-2223 phase and secondary phase was observed. The secondary phase is distributed uniformly over the whole surface. This is caused to the microcrack on the coatings surface. Despite everything, the film shows superconducting with an onset $T_{c}$ of about 115K. There are two changes steps. One changes (1step) at 115K is due to the diamagnetism of the Bi-2223 phase and the other changes (2step) at 78K is due to the diamagnetism of the Bi-2212 phase.

• 한국정보통신학회논문지
• /
• 제11권1호
• /
• pp.89-94
• /
• 2007

다양한 기판 온도와 산화 가스 압력 하에서 i-beam 스퍼터링 법으로 BiSrCaCuO 박막을 제작하였다. 기판온도 $T_{sub}$와 산화 가스 압력 $pO_3$를 변화시키며 제작된 Bi2212 및 Bi2223 박막의 생성상도를 작성하였다. Bi2212 조성으로 스퍼터링 하였으나 Bi2212 상 뿐 아니라 Bi2201 상과 Bi2223 상이 모두 생성되었고, Bi2212나 Bi2223 단상은 매우 좁은 온도 영역에서만 형성되었다. 생성 엔탈피의 변화 ${\Delta}{\bar}HO_2$와 생성 엔트로피의 변화 ${\Delta}{\bar}SO_2$에 대한 열역학적인 계산을 통해 Bi2212 단상이 형성된 경우 각각 -260 kJ/mol 및 $-225J/mol{\cdot}K$의 값을 얻었다.

• Transactions on Electrical and Electronic Materials
• /
• 제2권1호
• /
• pp.12-15
• /
• 2001

Bi-2212 and Bi-2223 thin films are prepared by IBS(ion beam sputtering) technique. Three phases of Bi-2201, Bi-2212 and Bi-2223 appear as stable ones in spite of the conditions for thin film fabrication of Bi-2212 and Bi-2223 compositions, depending on substrate temperature (T $_{sub}$) and ozone pressure(PO$_3$). It is found out that these phases are limited within very narrow temperature.e.

• 한국재료학회지
• /
• 제24권2호
• /
• pp.116-122
• /
• 2014

$Bi_2Sr_2CaCu_2O_x$(Bi-2212) and $Bi_2Sr_2Ca_2Cu_3O_y$(Bi-2223) high-Tc superconductors(HTS) have been manufactured by plasma spraying, partial melt process(PMP) and annealing treatment(AT). A Bi-2212/2223 HTS coating layer was synthesized through the peritectic reaction between a 0212 oxide coating layer and 2001 oxide coating layer by the PMP-AT process. The 2212 HTS layer consists of whiskers grown in the diffusion direction. The Bi-2223 phase and secondary phase in the Bi-2212 layer were observed. The secondary phase was distributed uniformly over the whole layer. As annealing time goes on, the Bi-2212 phase decreases with mis-orientation and irregular shape, but the Bi-2223 phase increases because a new Bi-2223 phase is formed inside the pre-existing Bi-2212 crystals, and because of the nucleation of a Bi-2223 phase at the edge of Bi-2212 crystals by diffusion of Ca and Cu-O bilayers. In this study the spray coated layer showed superconducting transitions with an onset Tc of about both 115 K, and 50 K. There were two steps. Step 1 at 115 K is due to the diamagnetism of the Bi-2223 phase and step 2 at 50 K is due to the diamagnetism of the Bi-2212 phase.

• 한국초전도학회:학술대회논문집
• /
• 한국초전도학회 1999년도 High Temperature Superconductivity Vol.IX
• /
• pp.260-260
• /
• 1999

We compared c-axis tunneling characteristics of small stacked intrinsic Josephson junctions prepared on the surface of pristine, I-, and HgI$_2$-intercalated Bi$_2Sr_2CaCu_2O_{8+x}$ (Bi2212) single crystals. The R(T) curves are almost metallic in I-Bi2212 specimens, but semiconducting in HgI$_2$-Bi2212 ones.· The transition temperatures were 82.0 K, 73.0 K, and 76.8 K for pristine Bi2212, I-Bi2212, and HgI2-Bi2212 specimens, respectively, consistent with p-T$_c$ phase diagram. Current-voltage (IV) characteristics of both kinds of specimens show multiple quasiparticle branches with well developed gap features, indicating Josephson coupling is established between neighboring CuO$_2$ planes. The critical current I$_c$ of I-Bi2212 is almost the same as of that of pristine crystals, but I$_c$ is much reduced in Hgl$_2$-Bi2212. In spite of expanded interlayer distances, the interlayer coupling is not significantly affected in I-Bi2212due to holes generated by iodine atoms. The coupling in HgI$_2$-Bi2212 is, however, weakened due to inertness of HgI$_2$ molecules and the expansion of interlayer distance. Relation between the superconducting transition temperature T$_c$ and the critical current I$_c$ seems to contradict Anderson's interlayer-pair-tunneling theory but agree with a modified version of it.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
• /
• pp.296-296
• /
• 2008

대용량의 초전도 전력기기에 사용되는 도체는 일반적으로 대전류를 통전할 수 있는 도체를 필요로 한다. 특히 SMES와 같이 펄스적으로 운전하는 코일에서 도체의 전류 용량을 증가시키면서 동시에 교류손실을 줄이는 방법으로 도체를 제조하기 위해서는 여러 가닥의 소선을 꼬아서 만드는 러더포드 케이블로 제조할 필요가 있으며 이를 위해서는 소선이 원형 상태를 유지하고 있어야 한다. Bi-2212 고온초전도선은 유일하게 원형 상태에서의 응용이 가능하므로 이 선의 개발 및 케이블 공정 개발은 매우 중요하다. 본 연구에서는 Bi-2212 고온초전도 소선을 사용하여 Rutherford 케이링을 할 수 있는 장치를 개발하였으며, 이 장치를 이용하여 복합 다심의 Bi-2212 초전도 소선을 8본, 20본 그리고 30본의 Bi-2212 러더포드 케이블을 110 m 길이까지 가공하였다. 제조한 러더포드 케이블 시료를 열처리에서의 부분용융 온도를 변화시키는 것으로 열처리 조건을 연구하였고, 77K, 64K 그리고 4.2K에서 임계전류 특성을 조사하였다. 또한 초전도 소선의 미세 조직을 관찰을 통하여 초전도 특성을 향상시키고자 하였다. 그래서 30본의 Bi-2212 러더포드 케이블에서 4.2K 온도로 환산하였을 때 5000 A를 초과하는 특성을 얻을 수 있었다.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
• /
• pp.77-79
• /
• 1999

Bi$_2$Sr$_2$CaCu$_2$O(Bi-2212) thick films were fabricated on Y211 substrate by screen printing method. The aim of the study was to fabricate superconducting thick films on Y211 substrate by MPMG process. For this study, patterned samples by screen printing method were heated with MPMG process. The thickness of Bi2212 on substrate was about 20 ${\mu}{\textrm}{m}$ and these samples showed many Bi- 2212 phases.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2003년도 춘계학술대회 논문집 초전도 자성체 연구회
• /
• pp.80-83
• /
• 2003

$SrSO_4$ were systematically added on Bi2212 from 0 to 10wt% to study the effect of Bi2212 superconductor tube characteristics. After mixing, the melted solution of Bi2212 and $SrSO_4$ was initially poured into the cylinder type of steel mold preheated at $550^{\circ}C$ for 30min and rotated at 1000rpm. Following that, tube was annealed at $840^{\circ}C$ for 72hrs. The tube dimension was 60 in diameter, 60mm in length and 2mm in thickness. XRD data suggests that there was no typical segregation phase related with $SrSO_4$. Well textured grain with typical 2212 phase was observed and average size was $20{\mu}m$. The measured critical current and critical current density of Bi2212 tube added by 5% $SrSO_4$ at 77K were 495A and $202A/cm^2$ respectively.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
• /
• pp.589-590
• /
• 2005

BSCCO:2212-2223 thin films were fabricated by using the ion beam sputter with a evaporation method at various substrate temperatures, $T_{sub}$, and ozone gas pressures, $pO_3$. The correlation diagrams of the BSCCO phases with Tsub and $pO_3$ are established in the 2212 and 2223 compositional films. In spite of 2212 compositional sputtering, Bi2201 and Bi2223 as well as Bi2212 phases come out as stable phases depending on Tsub and $pO_3$. From these results, the thermodynamic evaluation of ${\Delta}H$ and ${\Delta}S$, which are related with Gibbs' free energy change for single Bi2212 or Bi2223 phase, was performed.

• 한국전기전자재료학회논문지
• /
• 제14권7호
• /
• pp.606-610
• /
• 2001

Bi-2212 HTS tube was fabricated by centrifugal forming and partial melting processes. Bi-2212 bulk tube has been optimized to achieve smooth surface and uniform thickness. The slurry was prepared in the mixing ratio of 10:1 between Bi-2212 powder and binder and initially charged into the rotating mold under the speed of 300~450 rpm. Heat-treatment was performed at the temperature ranges of 860~89$0^{\circ}C$ in air for partial melting. the HTS tube fabricated by centrifugal forming process at 89$0^{\circ}C$ under the rotating speed of 450 rpm was highly densified and the plate-like grains with more than 20${\mu}{\textrm}{m}$ were well oriented along the rotating axis. The measured Tc and J$_{c}$ at 10K on specimen heat treated at 89$0^{\circ}C$ was around 85 K and 1,200 A/$\textrm{cm}^2$ respectively.y.