• Title/Summary/Keyword: Bi based glass

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Thermoelectric properties of $(Bi,;Sb)_2;(Te,;Se)_3$-based thin films and their applicability to temperature sensors ($(Bi,;Sb)_2;(Te,;Se)_3$계 박막의 열전 특성 및 온도 센서로의 응용)

  • 한승욱;김일호;이동희
    • Journal of the Korean Vacuum Society
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    • v.6 no.1
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    • pp.69-76
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    • 1997
  • P-type ($Bi_{0.5}Sb_{1.5}Te_3$) and n-type ($Bi_2Te_{2.4} Se_{0.6}$) thermoelectric thin film were deposited on glass and Teflon substrates by the flash evaporation technique. The changes in thermoelectric properties, such as Seebeck coefficient, electrical conductivity, carrier concentration, carrier mobility, thermal conductivity, and figure of merit, were investigated as a function of film thickness and annealing condition. Figures of merit of the thin films annealed at 473 K for 1 hour were improved to be $1.3{\times}10^{-3}K^{-1}$ for p-type and $0.3{\times}10^{-3}K^{-1}$ for n-type, and they were almost independent of film thickness. Temperature sensors were fabricated from the thin films having the above mentioned properties. And thermo-emf, sensitivity, and time constant of the sensors were measured to evaluate their characteristics for temperature sensors. Thin film sensors deposited on Teflon substrates showed better performance than those on glass substrates, and their sensitivity and time constant were 2.91 V/W and 28.2 sec respectively for the sensor of leg width 1 mm$\times$length 16 mm.

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A Study on the Current Status of the Glasses Design Industry in Korea (국내 안경 디자인산업 현황에 관한 연구)

  • Yun, Eul-Yo
    • Journal of the Korea Fashion and Costume Design Association
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    • v.15 no.3
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    • pp.199-211
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    • 2013
  • Glasses industry has great growth potential from the future-oriented perspective in Korea. In consideration of the fact that the ratio of aging population increases in this aging society, people have more and more interest in health. Also, their recognition on the cycle to change glasses is changing, and the utility of them as fashion items is increasing day by day, it is expected that the demand for glasses will be even more extended afterwards. Of course, presently it suffers from the gap between cheaper items and expensive ones provided by overseas prominent brands due to the bi-polarization of the market. However, they are pursuing the 2nd growth as export-leading items in the past through international glass exhibitions based on knowhow accumulated for a long time. Therefore, this study aims to examine the current status of glasses design industry in Korea reflecting the actual situations we have now and also understand the problems and limitations internalized in our glass design industry through the research process. As a result, the study has drawn the following conclusions. This paper intends to point out first, the phenomenon of bi-polarization of the glass market in Korea. Second, unequal distribution by region centering around Daegu. Third, the limitations of brand identity. Fourth, the limitations of information, planning, and marketing power. Fifth, passive conduction of international events and their insufficient effects. This study concludes that all these problems can be solved through 'planning and design, and marketing power'.

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Influence of Glass-Frit Size on the Microstructural Evolution of Conductive Silver Paste (전도성 실버 페이스트의 미세구조 발달에 미치는 glass-frit 크기의 영향)

  • Han, Hyun Geun;Seo, Dong Seok;Lee, Jong Kook
    • Korean Journal of Metals and Materials
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    • v.46 no.8
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    • pp.516-523
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    • 2008
  • The effect of glass-frit size on microstructural evolution and electrical resistance of conductive silver paste was investigated. Silver paste was prepared by mixing 70 wt% commercial silver powder with $1.6{\mu}m$, 3 wt% Bi based glass-frit and 27 wt% organic vehicle. Two different sizes of glass-frit were obtained by ball-milling of commercial glass-frit ($3{\mu}m$) for 3 and 5 days, which had an average particle size of 1.0 and $0.5{\mu}m$. The smaller glass-frit was melt at low sintered temperature and rapidly spread between the silver particles, which is induced the dense networking among silver particles and strong adhesiveness to $Al_2O_3$ substrate. The silver film with smaller glass-frit sintered at $500^{\circ}C$ showed the small pore size and low porosity resulting in low electrical resistivity of $4{\mu}{\Omega}cm$.

Fabrication of Pb Free Solder Glass for Electronic Packaging Application (전자 패키징용 Pb Free 저융점 유리의 제조)

  • 최승철;이창식;유재륜;정경원
    • Journal of the Korean Ceramic Society
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    • v.38 no.7
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    • pp.628-633
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    • 2001
  • 전자 패키징에 적용 가능한 저융점 유리 중에서 납성분이 포함되어 있지 않는 Bi계 유리의 연구를 행하였다. 기판과의 일체화를 위한 유리의 응용으로, 소자와의 반응 억제와 열응력 완화를 위해 유리의 저융점화 및 열팽창계수를 제어하였다. 본 연구에서 제조된 Bi계 유리는 DTA와 TMA의 열분석을 통해 5$50^{\circ}C$ 부근에서 연화점이 있고, 열팽창계수는 7.52~12.09$\times$$10^{-6}$/$^{\circ}C$의 범위였으며, 비유전율은 9~13이었다. 본 연구의 납성분을 포함되어 있지 않는 유리조성은 우수한 내산성을 나타내었다.

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Optical Properties of Color Conversion Lens for White LED Using B2O3-Bi2O3-ZnO Glass (B2O3-Bi2O3-ZnO계 유리를 이용한 백색 LED용 색변환 렌즈의 광 특성)

  • Chae, Yoo-Jin;Lee, Mi-Jai;Kim, Jin-Ho;Hwang, Jong-Hee;Lim, Tae-Young;Jeong, Hee-Suk;Lee, Young-Sik;Kim, Deuk-Jung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.8
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    • pp.614-619
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    • 2013
  • Recently, remote phosphor is reported for white LED enhancing of phosphor efficiency compared with conventional phosphor-based W-LED. In this study, Remote phosphor was produced by screen printing coating on glass substrate with phosphor contents rated paste and heat treatment. The paste consists of phosphor, lowest softening glass frit and organic binders. Remote phosphor can be well controlled by varying the phosphor content rated paste. After mounting remote phosphor on top of blue LED chip, CCT, CRI, and luminance efficiency were measured. The measurement results showed that CCT, CRI, and luminance efficiency were 6,645, 68, and 1,16l m/W in phosphor 80 wt.% remote phosphor sintered at $600^{\circ}C$.

Effect of Organic Processing Parameters in Non-aqueous Tape-casting on Dispersion Stability of Barium Titanate-Borosilicate Glass Based Suspensions (비수계 테잎성형공정의 유기공정변수의 변화에 따른 티탄산바륨-붕규산염유리계 현탁액의 분산안정성)

  • Yeo, Jeong-Gu;Choi, Sung-Churl
    • Korean Journal of Materials Research
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    • v.13 no.11
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    • pp.725-731
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    • 2003
  • The effect of organic processing parameters on the dispersion stability of the BaTiO$_3$-based dielectric particles and borosilicate glass particulate suspensions was investigated in a system where organic solvents, dispersant, binder and modifier were used as processing additives in a low temperature cofired ceramic fabrication processes. Two- and three-component organic solvents were used to disperse ceramic particles and it was found the better stability in the particulate suspension prepared in a bi-solvent, which was consists of toluene and ethanol in a non-azeotropic composition. The addition amount of organic additives had a great impact on dispersion in the present investigation. The flow curves of the suspensions prepared with binder and modifier were fitted according to the power-law equation, which indicates that the internal structure of the suspension could be disturbed under the applied shear stress. Finally, the LTCC green tapes were successfully tape-cast based upon the optimum formulation of LTCC suspension and its microstructure was compared with that of the hard-agglomerates.

A Study on the Mechanical Reliability of Large-area Bi-facial Glass-to-glass Photovoltaic Modules (대면적 양면 태양광 모듈의 기계적 신뢰성 연구)

  • Yohan, Noh;Jangwon, Yoo;Jaehyeong, Lee
    • Current Photovoltaic Research
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    • v.10 no.4
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    • pp.111-115
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    • 2022
  • For the high efficiency of the photovoltaic module, a high-output solar cell, which is the basis of photovoltaic power generation, is required. As the light receiving area of the solar cell increases, the light receiving area of the photovoltaic module also increases. Accordingly, recent trend is to use large-area solar cells such as M6 and M8 instead of M2-based solar cells for manufacturing the photovoltaic module and a study on the mechanical stiffness of the module with increased size is required. In this study, a mechanical load test corresponding to IEC-61215 was performed among the reliability tests of large-area photovoltaic modules. In order to confirm the degree to which the mechanical load test affects the photovoltaic module, the output and EL images were checked by sequentially increasing the pressure by 600 Pa at a pressure of 2400 Pa. Also, factors such as output and efficiency of large-area photovoltaic modules were verified through mechanical load testing of actual large-area photovoltaic modules and the rate of change was very small at 1%.

Effect of Sintering Aid and Glass-Frit on the Densification and Resistivity of Silver Paste (실버 페이스트의 치밀화 및 비저항에 미치는 소결조제와 프릿의 영향)

  • Lee, Jong-Kook;Park, Sung-Hyun;Yang, Gwon-Seung
    • Korean Journal of Materials Research
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    • v.18 no.5
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    • pp.283-288
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    • 2008
  • The effect of sintering aids and glass-frit on the densification and resistivity of silver paste was investigated in an effort to enhance the sintered density and electrical conductivity of the silver electrode. To prepare Pb-free silver paste for use at low sintering temperatures, two commercial silver powders ($0.8\;{\mu}m$ and $1.6\;{\mu}m$ in size) and 5wt.% lab-synthesized nanoparticles (30-50 nm in size) as a sintering aids were mixed with 3 wt.% or 6 wt.% of glass frit ($Bi_2O_3$-based) using a solvent and three roll mills. Thick films from the silver paste were prepared by means of screen printing on an alumina substrate followed by sintering at $450^{\circ}C$ to $550^{\circ}C$ for 15 min. Silver thick films from the paste with bimodal particles showed a high packing density, high densification during sintering and low resistivity compared to films created using monomodal particles. Silver nanoparticles as a sintering aid enhanced the densification of commercial silver powder at a low sintering temperature and induced low resistivity in the silver thick film. The glass frit also enhanced the densification of the films through liquid phase sintering; however, the optimum content of glass frit is necessary to ensure that a dense microstructure and low resistivity are obtained, as excessive glass-frit can provoke low conductivity due to the interconnection of the glass phase with the high resistivity between the silver particles.

Processing of Bi-based glass for transparent dielectrics ($Bi_2O_3$계 투명유전체의 제조)

  • 유재륜;정경원;최승철
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2001.11a
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    • pp.189-194
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    • 2001
  • PDP(Plasma Display Panel)의 투명 유전체에 적용 가능한 저융점 유리 중에서 납성분이 포함 되어 있지 않는 Bi계 유리의 연구를 행하였다. 기판과의 일체화를 위한 유리의 응용으로, 소자와의 반응 억제와 열응력 완화를 위해 유리의 저융점화 및 열팽창 계수를 제어하였다. 본 연구에서 제조된 Bi계 유리는 DTA와 TMA의 열분석을 통해 50$0^{\circ}C$부근에서 연화점이 있고, 7.31~10.02$\times$$10^{-6}$$^{\circ}C$, 비유전을 11.1~13.3, 광투과도가 80%이상으로 PDP 투명유전체에 적용 가능한 Bi계 유리를 얻을 수 있었다.

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Bithmooth Based Glass System for Transparent Dielectric in Plasma Display Panel ($Bi_2O_3-ZnO-SiO_2$ 유리계의 PDP 투명유전체에 적용 가능성)

  • 전재삼;차명룡;정병해;김형순
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.196-196
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    • 2003
  • 현재 PDP(Plasma Display Panel) 상판의 유전체층은 저온에서 소성이 가능한 저융점 유리가 요구되기 때문에 융점을 낮추기에 용이한 PbO계가 주 성분으로 사용되어 오고 있으나. 최근 환경오염 등의 문제점으로 인해 Pb-free을 추구하는 새로운 유리조성의 연구가 많이 수행되고 있다. 이에 본 연구는 이미 PDP의 격벽과 봉착용 조성으로 많이 연구되어진 비스무스계 유리를 고려하여 PDP의 투명유전체용 조성을 찾고자 한다. Bi$_2$O$_3$-ZnO-SiO$_2$3원계를 기본으로 하는 유리조성에 유리망목형성제등을 첨가하여 열적특성과 광학적 특성을 조사하였다. 열적특성은 DTA를 이용하여 유리 전이 점(Tg) 및 융점(Tl)등을 측정하였고 TMA를 이용하여 선팽창계수(CTE)를 측정하였으며 유리섬유를 제조한 후 Littleton softening point (Ts)를 측정하였다. 광학적 특성은 페이스트를 제조하여 스크린프린팅 후 54$0^{\circ}C$~$600^{\circ}C$에서 1-2 h동안 소성하여 투광성을 조사하였다. 그 결과로, 열적특성으로는 400~5$50^{\circ}C$의 Tg, 450~$600^{\circ}C$의 Ts 및 5~11$\times$$10^{-6}$K의 CTE 값을 나타 내었고 광학적 특성으로 투광성은 양호한 특성(60% 이상)을 나타내었다. Bi$_2$O$_3$ 계를 현재 PDP의 투명유 전체에 적용시키기에는 유리용융시에 높은 점도와 환원 등의 문제점을 갖고 있지만 열적특성과 광학특성면에서는 가능성을 제시하여 향후 연구를 할 가치가 있다고 본다.

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