• Title/Summary/Keyword: Bi/CNT composite

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Mechanical and Magnetic Properties of YBCO Superconductor with Bi/CNT Composite and Resin/CNT Impregnation (Bi/CNT 화합물과 Resin/CNT를 보강한 YBCO 초전도체의 기계적, 자기적 특성 변화)

  • Oh, W.S.;Jang, G.E.;Han, Y.H.;Sung, T.H.
    • Progress in Superconductivity
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    • v.9 no.1
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    • pp.107-110
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    • 2007
  • Bi/CNT composite and resin/CNT were chosen to improve the mechanical properties of $YBa_2Cu_3O_7$(YBCO) superconductor. In order to elucidate the effects of Bi/CNT composite and resin/CNT in YBCO superconductors, melt texture superconductor were impregnated by mixed compound of Bi and CNT into the artificial holes parallel to the c-axis, which were drilled on the YBCO superconductor. Various amount of Bi/CNT and resin/CNT were impregnated to YBCO superconductor with different holes diameters. Typical artificial holes diameters were 0.5, 0.7, and 1.0 mm respectively. Result of three-point bending test measurement, the bending strength with resin/CNT impregnation was improved up to 59.64 MPa as compared with 50.79 MPa of resin/CNT free bulk. Resin/CNT impregnation has been found to be one of the effective ways in improving the mechanical properties of bulk superconductor.

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Fabrication and Thermoelectric Properties of Carbon Nanotube/Bi2Te3 Composites (탄소나노튜브가 분산된 비스무스 텔루라이드 기지 복합재료의 제조 및 열전특성)

  • Kim, Kyung-Tae;Jang, Kyeong-Mi;Kim, Kyong-Ju;Ha, Gook-Hyun
    • Journal of Powder Materials
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    • v.17 no.2
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    • pp.107-112
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    • 2010
  • Carbon-nanotube-embedded bismuth telluride (CNT/$Bi_2Te_3$) matrix composites were fabricated by a powder metallurgy process. Composite powders, whereby 5 vol.% of functionalized CNTs were homogeneously mixed with $Bi_2Te_3$ alloying powders, were successfully synthesized by using high-energy ball milling process. The powders were consolidated into bulk CNT/$Bi_2Te_3$ composites by spark plasma sintering process at $350^{\circ}C$ for 10 min. The fabricated composites showed the uniform mixing and homogeneous dispersion of CNTs in the $Bi_2Te_3$ matrix. Seebeck coefficient of CNT/$Bi_2Te_3$ composites reveals that the composite has n-type semiconducting characteristics with values ranging $-55\;{\mu}V/K$ to $-95\;{\mu}V/K$ with increasing temperature. Furthermore, the significant reduction in thermal conductivity has been clearly observed in the composites. The results showed that CNT addition to thermoelectric materials could be useful method to obtain high thermoelectric performance.

Synthesis and Thermoelectric Properties of Carbon Nanotube-Dispersed Bi2Te3 Matrix Composite Powders by Chemical Routes

  • Kim, Kyung Tae;Son, Injoon;Ha, Gook Hyun
    • Journal of Powder Materials
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    • v.20 no.5
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    • pp.345-349
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    • 2013
  • Carbon nanotube-dispersed bismuth telluride matrix (CNT/$Bi_2Te_3$) nanopowders were synthesized by chemical routes followed by a ball-milling process. The microstructures of the synthesized CNT/$Bi_2Te_3$ nanopowders showed the characteristic microstructure of CNTs dispersed among disc-shaped $Bi_2Te_3$ nanopowders with as an average size of 500 nm in-plane and a few tens of nm in thickness. The prepared nanopowders were sintered into composites with a homogeneous dispersion of CNTs in a $Bi_2Te_3$ matrix. The dimensionless figure-of-merit of the composite showed an enhanced value compared to that of pure $Bi_2Te_3$ at the room temperature due to the reduced thermal conductivity and increased electrical conductivity with the addition of CNTs.

Development of Curing Process for EMC Encapsulation of Ultra-thin Semiconductor Package (초박형 반도체 패키지의 EMC encapsulation을 위한 경화 공정 개발)

  • Park, Seong Yeon;On, Seung Yoon;Kim, Seong Su
    • Composites Research
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    • v.34 no.1
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    • pp.47-50
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    • 2021
  • In this paper, the Curing process for Epoxy Molding Compound (EMC) Package was developed by comparing the performance of the EMC/Cu Bi-layer package manufactured by the conventional Hot Press process system and Carbon Nanotubes (CNT) Heater process system of the surface heating system. The viscosity of EMC was measured by using a rheometer for the curing cycle of the CNT Heater. In the EMC/Cu Bi-layer Package manufactured through the two process methods by mentioned above, the voids inside the EMC was analyzed using an optical microscope. In addition, the interfacial void and warpage of the EMC/Cu Bi-layer Package were analyzed through C-Scanning Acoustic Microscope and 3D-Digital Image Correlation. According to these experimental results, it was confirmed that there was neither void in the EMC interior nor difference in the warpage at room temperature, the zero-warpage temperature and the change in warpage.

Nonlinear vibration of FG-CNTRC curved pipes with temperature-dependent properties

  • Mingjie Liu;Shaoping Bi;Sicheng Shao;Hadi Babaei
    • Steel and Composite Structures
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    • v.46 no.4
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    • pp.553-563
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    • 2023
  • In the current research, the nonlinear free vibrations of curved pipes made of functionally graded (FG) carbon nanotube reinforced composite (CNTRC) materials are investigated. It is assumed that the FG-CNTRC curved pipe is supported on a three-parameter nonlinear elastic foundation and is subjected to a uniform temperature rise. Properties of the curved nanocomposite pipe are distributed across the radius of the pipe and are given by means of a refined rule of mixtures approach. It is also assumed that all thermomechanical properties of the nanocomposite pipe are temperature-dependent. The governing equations of the curved pipe are obtained using a higher order shear deformation theory, where the traction free boundary conditions are satisfied on the top and bottom surfaces of the pipe. The von Kármán type of geometrical non-linearity is included into the formulation to consider the large deflection in the curved nanocomposite pipe. For the case of nanocomposite curved pipes which are simply supported in flexure and axially immovable, the motion equations are solved using the two-step perturbation technique. The closed-form expressions are provided to obtain the small- and large-amplitude frequencies of FG-CNTRC curved pipes rested on a nonlinear elastic foundation in thermal environment. Numerical results are given to explore the effects of CNT distribution pattern, the CNT volume fraction, thermal environment, nonlinear foundation stiffness, and geometrical parameters on the fundamental linear and nonlinear frequencies of the curved nanocomposite pipe.

Effect of Binder and Electrolyte on Electrochemical Performance of Si/CNT/C Anode Composite in Lithium-ion Battery (리튬이온 이차전지에서 Si/CNT/C 음극 복합소재의 전기화학적 성능에 대한 바인더 및 전해액의 효과)

  • Choi, Na Hyun;Kim, Eun Bi;Yeom, Tae Ho;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.60 no.3
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    • pp.327-333
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    • 2022
  • In this study, silicon/carbon nanotube/carbon (Si/CNT/C) composites for anode were prepared to improve the volume expansion of silicon used as a high-capacity anode material. Si/CNT were prepared by electrostatic attraction of the positively charged Si and negatively charged CNT and then hydrothermal synthesis was performed to obtain the spherical Si/CNT/C composites. Poly(vinylidene fluoride) (PVDF), polyacrylic acid (PAA), and styrene butadiene rubber (SBR) were used as binders for electrode preparation, and coin cell was assembled using 1.0 M LiPF6 (EC:DMC:EMC = 1:1:1 vol%) electrolyte and fluoroethylene carbonate (FEC) additive. The physical properties of Si/CNT/C anode materials were analyzed using SEM, EDS, XRD and TGA, and the electrochemical performances of lithium-ion batteries were investigated by charge-discharge cycle, rate performance, dQ/dV and electrochemical impedance spectroscopy tests. Also, it was confirmed that both capacity and rate performance were significantly improved using the PAA/SBR binder and 10 wt% FEC-added electrolyte. It is found that Si/CNT/C have the reversible capacity of 914 mAh/g, the capacity retention ratio of 83% during 50 cycles and the rate performance of 70% in 2 C/0.1 C.