• 제목/요약/키워드: Benzyltrimethylammonium dichloroiodate

검색결과 1건 처리시간 0.013초

Novel synthetic method for the preparation of α-iododaphnetin using benzyltrimethylammonium dichloroiodate

  • Kim, Taek-Soo;Kim, Bo-Ram;Park, Jeong Hoon;Yang, Seung Dae
    • 대한방사성의약품학회지
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    • 제2권1호
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    • pp.56-60
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    • 2016
  • Benzyltrimethylammonium dichloroiodate in the presence of $ZnCl_2$ has been used for aromatic iodination of electron rich aromatic compounds. However, Baylis-Hillman type regioselective ${\alpha}$-iodination was carried out electronically rich coumarin compound under mild reaction condition with excellent chemical yield. Finally, $BBr_3$ demethylation gave ${\alpha}$-iododaphnetin.