• Journal of the Korean Chemical Society
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• v.68 no.4
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• pp.185-190
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• 2024

Recently, it was reported that the benzobisoxazole (BBO) molecule can be used for independent modulation of the HOMO and LUMO energy levels. In this study, we utilized this interesting property of BBO to quantitatively investigate the substituent effects according the substituents. We designed and proposed four BBO model systems (1BBO, 2BBO, 3BBO and 4BBO) by extending the π-conjugation lengths based on a BBO molecule. Two directions of substitution (x-axis and y-axis) and 15 various substituents were considered. From strong correlation between the LUMO energy levels of x-axis substitution and HOMO energy levels of y-axis substitution calculated from DFT method, it is found that the standardization of substitution effects can be established from BBO model systems. In addition, we demonstrated that the HOMO values of y-axis substituted 3BBO show the best performance to define the order of substituent effects. Our proposed way can be used to expect the substituent effect of any arbitrary substituents and develop the organic sensors and organic light emitting diodes.

• Textile Coloration and Finishing
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• v.33 no.4
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• pp.327-337
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• 2021

The uniformly dispersed Aramid and Poly (phenylene benzobisoxazole) (PBO) in a variety of rubber was investigated. The mechanical properties of rubber were characterized by hardness, tensile strength, elongation at break, heat resistance, oil resistance, cold resistance, ozone resistance measurements. The 3mm Aramid chopped fiber better tensile strength than the other Chopped fiber. The Aramid of 3mm chopped fiber showed excellent reinforcing in rubber composite because of homogeneous dispersion. Consequently, the best 3mm Aramid chopped fiber and rubber improved the tensile strength and elongation at break of the composite. Also, 3mm Aramid chopped fiber improved the oil-resistant, ozone resistant and cold resistant.

• Journal of Korean Society on Water Environment
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• v.24 no.6
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• pp.801-805
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• 2008

A fibrous material (p-phenylene-2,5-benzobisoxazole, PBO) was used as an adsorbent for solid phase extraction in order to simplify the extraction procedure. The extraction performance for di-(2-ethylhexyl) phthalate (DEHP) was examined with two types of PBO fibers (HM (High modulus) and AS (Regular type) types) by batch type sorption/desorption experiments. When 100 mg of the HM fibers were applied to 20 mL of the aqueous DEHP solution (less than $50{\mu}g/L$), more than 95% of DEHP was adsorbed on the fibers, however, the AS type fibers adsorbed alkyl phthalate up to 80%. In the case of $50{\mu}g/L$ of the initial concentration of DEHP, the adsorbed DEHP was extracted effectively with methanol and the maximum overall recovery ratio was 92.3%. The results indicated that the PBO fibers could be used as an adsorbent for alkyl phthalate analysis, and that the extraction procedure was not affected by suspended solids in a water sample.

• Journal of Korean Society on Water Environment
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• v.27 no.3
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• pp.329-333
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• 2011

p-phenylene-2,5-benzobisoxazole (PBO; Zylon$(R)$) fibers as an adsorbent were employed for solid phase extraction of aqueous alkylphenols. The removal ratios for 10 kinds of alkylphenols at initial concentration of $100{\mu}gL^{-1}$ were in the range of 16.8-96.3% and the removals increased with the increase of the phase ratio (fiber weight/solution volume). The plots of the logarithm of partition coefficient (log K) were correlated with the logarithm of the n-octanol/water partition coefficient (log P). The adsorbed alkylphenols were completely desorbed with the mixture of acetonitrile and dichloromethane.

• Composites Research
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• v.16 no.4
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• pp.74-79
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• 2003

Comparison of interfacial properties and microfailure mechanisms of oxygen-plasma treated poly(p-phenylene-2,6-benzobisoxazole(PBO. Zylon) and poly(p-phenylene terephthalamide)(PPTA, Kevlar) fibers/ epoxy composites were investigated using micromechanical technique and nondestructive acoustic emission(AE). Interfacial shear strength(IFSS) and work of adhesion, Wa of PBO or Kevlar fibers/epoxy composites increased by oxygen-plasma treatment. Plasma-treated Kevlar fiber shooed the maximum critical surface tension and polar term, whereas the untreated PBO fiber showed the minimum value. Microfibril fracture pattern of plasma-treated Kevlar fiber appeared obviously. Based on the propagation of microfibril failure toward core region. the number of AE events for plasma-treated PBO and Kevlar fibers increased significantly. The results oi nondestructive AE were consistent well with microfailure modes by optical observation in microdroplet and two-fiber composites tests.