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Comparison of energy efficiency by electrode materials and structure in bench scale bioelectrochemical anaerobic digestion (Bench scale 생물전기화학적 혐기성소화에서 전극재질 및 구조에 따른 에너지효율 비교)

  • Yang, Hyeon Myeong;Cheon, A In;Kim, Min Ji;Cha, Ji Hwan;Jun, Hang Bae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2022.05a
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    • pp.396-396
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    • 2022
  • 생물전기화학적 혐기성소화(Bioelectrochemical anaerobic digestion; BEAD)는 소량의 전압공급을 통해 고농도 하·폐수의 효과적인 처리 및 에너지 회수가 가능한 처리방법으로, 기존 하·폐수처리공정(활성슬러지 및 그 변법)에서 벗어나기 위한 방법 중 하나로 연구되고 있지만, 내부저항 및 전극구조에 따른 물질전달저해로 인해 소규모 연구 위주로 진행되었다. 하지만 stainless steel(SS) 등 내부저항을 완화할 수 있는 전극재료 및 전극구조 개선 연구가 진행됨에 따라 BEAD 적용규모가 증가하는 추세이며, 본 연구에서는 100 L의 용량에서 전극재질 및 구조에 따른 적용적합성을 에너지효율 비교를 통해 평가하였다. 반응조는 비교를 위한 AD, 반응조 내부에 전극을 설치한 BEAD, 반응조 외부에 전극이 포함된 반응조를 추가한 ABEAD로 구성하였으며, AD 및 BEAD는 기계적 교반, ABEAD는 기계적 교반 및 펌프를 통한 bulk 용액 순환으로 물질전달이 이뤄졌다. 또한 BEAD는 탄소계 전극, ABEAD는 SS계 전극을 사용하였으며 두 반응조 모두 0.4 V의 전압을 공급하였다. 실험조건은 유효용량 100 L, 유기물부하율 3 kg/m3/d, HRT 20 days 및 중온소화(35℃)으로 운전하였다. 실험결과 AD, BEAD 및 ABEAD의 유기물제거율은 각각 평균 68.1 %, 68.9 %, 74.9 %로 전극 및 반응조의 분리를 통해 물질전달을 개선한 ABEAD에서 증가하였다. 에너지 생성량의 경우 AD에 비해 BEAD는 평균 229 kJ/d, ABEAD는 309 kJ/d가 추가 생성되었으며 유기물제거율이 높은 ABEAD에서 더 높은 에너지생산이 이뤄졌다. 마지막으로 전압공급으로 인한 에너지소비량은 BEAD는 평균 3.4 kJ/d, ABEAD는 평균 0.9 kJ/d로 전극의 낮은 생물적합성으로 인해 전극에서의 생화학반응이 적은 ABEAD가 에너지소비량이 낮았다. 따라서 본 연구에서는 SS 전극의 사용가능성 및 전극구조 개선에 따른 에너지효율성 향상을 확인할 수 있었으며, 추후 연구에 활용할 수 있을 것으로 기대된다.

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Study of performance improvement in bench scale auxiliary bioelectrochemical anaerobic digestion for application suitability verification (보조 미생물전기화학적 혐기성소화의 적용적합성 검증을 위한 bench scale에서의 성능향상 연구)

  • Yang, Hyeon Myeong;Cheon, A In;Kim, Min Ji;Cha, Ji Hwan;Jun, Hang Bae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2022.05a
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    • pp.397-397
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    • 2022
  • 오늘날 급격한 인구증가 및 도시화로 인해 음식물류 폐기물 발생량이 크게 증가하였으며, 음식물류 폐기물에서 발생되는 음폐수의 적절한 처리방안에 대한 관심이 증가하였다. 혐기성 소화(Anaerobic digestion; AD)는 음폐수의 바람직한 처리방법으로 알려졌지만, 긴 처리기간 및 공정 불안정 등의 문제로 개선이 필요하며, 그 중 기존 AD에 보조 반응조를 추가한 보조 미생물전기화학적 혐기성소화(Auxiliary bioelectrochemical anaerobic digestion; ABEAD)가 적절한 개선방안으로 제시되었다. 하지만 아직 20 L 이상 용량에서의 연구는 이뤄지지 않았으며, 따라서 본 연구에서는 100 L의 용량에서 ABEAD의 성능향상을 평가하고 규모증가에 따른 성능변화를 비교하였다. 반응조는 AD와 ABEAD로 구성되었다. 유효용량 100 L, 유기물부하율 4 kg/m3/d, HRT 20 days 및 중온소화(35℃) 조건으로 운전하였으며, AD는 기계적 교반, ABEAD는 기계적 교반 및 펌프를 통한 bulk 용액 순환이 이뤄졌다. ABEAD의 전극재질은 SUS304를 사용하였고, 0.4V의 전압을 공급하였다. 성능비교는 pH, 휘발성지방산(Volatile fatty acids; VFAs), 유기물제거율 및 메탄 생성량을 비교해 수행하였다. 실험결과 AD는 pH 및 VFAs가 각각 평균 7.37 및 3,880 mg/L, ABEAD는 각각 평균 7.5 및 2,870 mg/L로 VFAs의 빠른 처리를 통해 공정안전성 향상되었고, 유기물제거율 및 메탄생성량의 경우 AD는 각각 평균 65.8 % 및 85.1 L/d, ABEAD는 각각 평균 76.1 % 및 108.1 L/d로 유기물의 빠른 처리 및 메탄전환이 이루어져 비교적 큰 규모에서도 ABEAD의 성능향상이 나타남을 확인하였다. 또한 이전 소규모 연구들과 비교를 통해 규모에 따른 성능향상폭을 비교했을 때에도 큰 차이가 나지 않는 것으로 판단되며, 따라서 ABEAD는 BEAD 기술의 상용화 및 적용에 적합한 것으로 사료된다.

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Occurrence and Damage of Bradysia agrestis Sasakawa (Diptera: Sciaridae) in Propagation House (육묘장내 작은뿌리파리의 발생과 피해)

  • 김형환;추호렬;이홍수;조성래;신현열;박정규;추영무
    • Korean journal of applied entomology
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    • v.39 no.2
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    • pp.89-97
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    • 2000
  • Insect pests of eggplant, pepper, Chinese cabbage, watermelon, cucumber, melon, and tomato seedlings were surveyed in eleven propagation houses from 1998 to 1999. Ten species of insect pests of nine genera in eight families, two species of mites of one genus in one family, and three species of slugsor snails in three genera belonging to two families were found from the observed seedlings but Bradysia agrestis was the most serious pest out of them. Thus, occurrence and damage of B. agrestis were investigated in two propagation houses all the year round. In the observation of seedling mortalities of seven crops in May, July, October and the following February, only watermelon seedlings were withered and dead by the larva of B. agrestis with different mortality depending on time representing 81.9%, 41.3%, 54.9%, and 79.1%, respectively. All the developmental stages of B. agrestis were found every month throughout the year. Larval density and adult density were different according to season with the highest numbers in May showing 34.9 and 407.4, respectively. Mortality of watermelon seedlings was higher in April and May than the other months showing 83.3% in April and 82.4% in May. The number of adults attracted to sticky trap was also different depending on card colour. The number of adults was much higher on yellow sticky card (326.2) than blue sticky card (20.2). In the investigation of the number of adults on yellow sticky card at 25 cm and 120 cm above the bench and 10 cm under the bench, more numbers of adults were caught at 25 cm above the bench (273.7) and 10 cm under the bench (320.1) than 120 cm above the bench (27.9). Mortalities of cucumber, pepper, and watermelon seedlings after transplanting in greenhouses were not significantly different depending on culture method.

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Study on Evaluation Method of Flow Characteristics in Steady Flow Bench(3) - Velocity Profile(1) (정상유동 장치에서 유동 특성 평가 방법에 대한 연구(3) - 유속분포(1))

  • Park, Chanjun;Sung, Jaeyong;Ohm, Inyong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.24 no.2
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    • pp.169-182
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    • 2016
  • This paper is the third investigation on the evaluation methods of flow characteristics in a steady flow bench. In the previous works, several assumptions used in the steady flow bench were examined and the flow characteristics were estimated both by the conventional impulse swirl meter and a particle image velocimetry at 1.75B position. From these works, it was concluded that the assumption of the solid rotation might cause serious problems and both of the eccentricity and the velocity profile distort the flow characteristics when using the ISM at 1.75B plane. Therefore, the understanding of the detail velocity profiles is very important to keep discussing the issues about the steady flow evaluation method. For this purpose, the planar velocity profiles were measure at 1.75B position by particle image velocimetry and the characteristics were examined according to the valve angles and lifts. The results show that the planar velocity profiles of 11, 16, $21^{\circ}$ valve angle heads according to the lift are similar to each other, however, that of $26^{\circ}$ angle is an exceptional case in the all aspects. In addition, the swirl behaviors are not apparent up to 6~8 mm lift under the $21^{\circ}$ angle and somewhat arranged motions are observed over the whole plane near the highest lift. At this point, the narrower the angle, the lower the lift at which the swirl motions become clear. On the other hands, when the angle is $26^{\circ}$, the center of swirl is always farthest from the cylinder center and only the indistinct swirl is observed even if at the highest lift. Also, all the swirl centers are quite apart from the cylinder center so that the effect of eccentricity may not be negligible at 1.75B regardless the valve angle. Related to the tangential velocity along with the radial direction, the bands of the velocity distribution are very wide and the mean velocities of cylinder center basis are lower than the velocity which is assumed in the ISM evaluation. Lastly, the mean tangential velocity profiles of swirl center basis are sometimes higher than that of ISM-assumed up to 0.6 non-dimensional distance less than 6mm lift, however, as the lift increases the profiles are different according to the angles and profile $11^{\circ}$ is the most closed to the ideal profile. Consequently, the real velocity profile is far from the assumption of ISM evaluation.

Analysis on the Characteristics of Rock Blasting-induced Vibration Based on the Analysis of Test Blasting Measurement Data (시험발파 계측자료 분석을 통한 암석 발파진동 특성 분석)

  • Son, Moorak;Ryu, Jaeha;Ahn, Sungsoo;Hwang, Youngcheol;Park, Duhee;Moon, Duhyeong
    • Journal of the Korean GEO-environmental Society
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    • v.16 no.9
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    • pp.23-32
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    • 2015
  • This study examined blast testing measurement data which had been obtained from 97 field sites in Korea to investigate the comprehensive characteristics of rock blasting-induced vibration focusing on the effect of excavation types (tunnel, bench) and rock types. The measurement data was from the testing sites mostly in Kangwon province and Kyungsang province and rock types were granite, gneiss, limestone, sand stone, and shale in the order of number of data. The study indicated that the blasting-induced vibration velocity was affected by the excavation types (tunnel, bench) and bench blasting induced higher velocity than tunnel blasting. In addition, the vibration velocity was also highly affected by the rock types and therefore, it can be concluded that rock types should be considered in the future to estimate a blasting-induced vibration velocity. Furthermore, the pre-existing criteria was compared with the results of this study and the comparison indicated that there was a discernable difference except for tunnel blasting results based on the square root scaling and therefore, further studies and interests, which include the effects of rock strength, joint characteristics, geological formation, excavation type, power type, measurement equipment and method, might be necessarily in relation to the estimation of blasting-induced vibration velocity in rock mass.

Study of NO Storage and Reduction on LNT by Micro Bench-Flow Reactor (마이크로 벤치-플로우 리액터를 이용한 LNT 촉매의 NO 흡장과 정화성능에 관한 연구)

  • Yoon, Joo-Wung;Hwang, Seung-Kwon;Hwang, In-Goo;Park, Sim-Soo;Lee, Jin-Ha;Yeo, Gwon-Koo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.8
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    • pp.789-798
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    • 2011
  • We carry out an experimental investigation to analyze the basic performance of NO(nitric oxide) storage in a lean phase and also analyze the NO reduction achieved by the spraying of reducing agents in the rich phase of the exhaust gas in an LNT(Lean NOx Trap). This is an after-treatment system used to reduce the NOx emissions from a diesel engine. If the stored NO is reduced, we measure the outlet concentration downstream of the LNT. The test LNT material used in the experiments is commercial LNT. After being canned into stainless-steel(SUS304), it was built in a micro bench-flow reactor. Compositions of feed gases, three heated and three no heated gases were sprayed upstream of the LNT to analyze the characteristics. We use various temperatures and space velocities as response variables.

Effects of Production of Ever-bearing Strawberries Using Cool Air from Mushroom Cultivation House (버섯재배시설의 냉공기 이용이 사계성딸기 생산성에 미치는 영향)

  • Jeoung, Yun-Kyeoung;Park, Ju-Hyen;Ha, Tae Moon;Lee, Young-Suk;Seo, Myeong-Hoon;Kim, In-Chul
    • Journal of Bio-Environment Control
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    • v.28 no.1
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    • pp.28-37
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    • 2019
  • We designed a system that can automatically collect, convey, and control cool air of $15^{\circ}C-20^{\circ}C$ containing carbon dioxide from a mushroom cultivation house to a strawberry plastic house. We recorded the temperature at various positions from July to August 2017. The average temperature of the green house during day and at night was maintained at $33^{\circ}C$ and $26^{\circ}C$, respectively. In the moveable three-tier cylindrical bed, the average temperature around root was maintained at $26^{\circ}C$ and $21^{\circ}C$ during day and at night, respectively. On the high-bench in the green house, the temperature was maintained at $32^{\circ}C$ and $30^{\circ}C$ during day and at night, respectively. The carbon dioxide concentration was maintained around 800-1,600 ppm in the mushroom cultivation system and 400-800 ppm in the strawberry plastic house. The growth characteristics of the strawberry treated with moveable three-tier cylindrical bed were significantly different from those of the untreated high-bench bed. In addition, during the summer season, moveable three-tier cylindrical bed showed more tendency to increase in normal fruit number (NFN) and to decrease in defective fruit number (DFN) compare to the high-bench bed. Therefore, the moveable three-tier cylindrical bed showed a tendency to be more than 2 times higher yields than that of the high-bench bed. It was confirmed that ever-bearing strawberry cultivars could be cultivated in green house due to the cool air supply from the mushroom cultivation system in the summer season.

Temperature Dependence of Cr Impurity in La0.6Sr0.4Ti0.3Fe0.7O3-δ Coated Ba0.5Sr0.5Co0.8Fe0.2O3-δ Ion Conducting Membrane for oxygen Separation (산소 분리를 위한 La0.6Sr0.4Ti0.3Fe0.7O3-δ가 코팅된 Ba0.5Sr0.5Co0.8Fe0.2O3-δ 이온전도성 분리막에서 Cr 불순물의 온도 의존성)

  • Park, Yu Gang;Park, Jung Hoon
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.11-16
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    • 2019
  • $La_{0.6}Sr_{0.4}Ti_{0.3}Fe_{0.7}O_{3-{\delta}}$(LSTF) coated $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$(BSCF) membranes which has properties of high oxygen permeability and stability to $CO_2$ were applied to a bench scale apparatus to conduct oxygen permeation experiments. Also, the membranes of the laboratory and the bench scale device were divided into three regions according to the temperature gradient in the membrane reactor for comparative analysis. While oxygen permeation experiment were conducted up to $900^{\circ}C$, temperature dependence of Cr deposition was investigated. As a result, it was confirmed that the oxygen permeability was $2.37ml/min{\cdot}cm^2$, which was significantly lower than $3.79ml/min{\cdot}cm^2$ measured in the laboratory apparatus. It was found through XRD and SEM/EDS analysis that the decrease in oxygen permeability was originated from the deposition of gaseous Cr on the membrane surface released from the alloy material of the housing. In particular, a large amount of Cr was found in the medium temperature region.