• 제목/요약/키워드: Bayer

검색결과 155건 처리시간 0.028초

Application of Bayer-Villiger Reaction to the Synthesis of Dibenzo-18-crown-6, Dibenzo-21-crown-7 and Dihydroxydibenzo-18-crown-6

  • Utekar, Druman R.;Saman, Shriniwas D.
    • 대한화학회지
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    • 제58권2호
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    • pp.193-197
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    • 2014
  • Dibenzo-18-crown-6, dibenzo-21-crown-7 and dihydroxy dibenzo-18-crown-6 were synthesized by Bayer-Villiger oxidation strategy. Dibenzo-18-crown-6 and dibenzo-21-crown-7 could be synthesized through a three-step protocol starting from salicylaldehyde. Salicylaldehyde was reacted with bis-(2-chloroethyl)ether using $K_2CO_3$ in acetonitrile to link the two phenolic groups with the oxyethylene bridge followed by conversion of the formyl group to the hydroxy group via a Baeyer-Villiger reaction and finally linking the two phenolic group with appropriate oxyethylene bridge. The two target crown ethers were obtained in overall yield, 24% and 30%, respectively. This method has a great potential for synthesis of symmetrical as well as unsymmetrical dibenzo crowns with varying oxyethylene bridges. Baeyer-Villiger oxidation could be used to prepare dihydroxy derivative of dibenzo-18-crown-6 through acetylation of dibenzo-18-crown-6 followed by Baeyer-Villiger oxidation. The Baeyer-Villiger oxidation could be substantially accelerated using trifluoroacetic acid.

After-infection Activity of Protective Fungicides against Apple White Rot

  • Lee, Dong-Hyuk;Kim, Dae-Hee;Woo, Hyun;Uhm, Jae-Youl
    • The Plant Pathology Journal
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    • 제23권3호
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    • pp.166-173
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    • 2007
  • In a trial to select suitable fungicides for developing a spray program that can control apple white rot effectively, after-infection activities in some protective fungicides were detected. Six fungicides, mancozeb, propineb, benomyl, folpet, azoxystrobin and iminoctadine-triacetate, which had been extensively used in apple orchards, were sprayed on 12-year-old apple trees (cv. Fuji) at 15-day intervals from late May to late July. Disease incidences and infection frequencies of the fruit bagged just before and soon after each spray were examined. When the infection frequency or disease incidence of the fruit bagged after each spraying of fungicide was significantly lower than those of the fruit bagged before spraying, the fungicides appeared to confer after-infection activity. The six fungicides showed diverse activities on white rot: folpet showed after-infection activity on disease development, iminoctadine-triacetate showed after-infection activity on infection, azoxystrobin showed after-infection activity on disease development and infection, and mancozeb, propineb and benomyl showed no distinct activity. The activity of a fungicide became much higher when it was sprayed alternately with other fungicide rather than successive spraying of the same fungicide. Analysis of the properties of these protective fungicides could lead to the development of a highly effective spray program against white rot.

Artemisinin의 Eimeria tenella에 대한 항콕시듐 효과 (Anticoccidial effects of artemisinin on the Eimeria tenella)

  • 오화균;윤희정;노재욱;장두환;강영배
    • 대한수의학회지
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    • 제35권1호
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    • pp.123-130
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    • 1995
  • Artemisinin, a sesquiterpene lactone, is isolated from the leafy portion of the Artemisia annua and has been known to be effective against Plasmodium species. Since the genera of Plasmodium and Eimeria(E) tenella are included the same order, Eucoccidiidae, it is presumed that artemisinin may also be effective against E tenella. In order to study the anticoccididal effects of artemisinin, the chickens inoculated with E tenella were treated with artemisinin at different concentrations as feed additive and the results were compared to those of non-medicated, infected control(NIC) and non-medicated, non-infected control(NNC) group. Artemisinin demonstrated anticoccidial effects by showing, compared to NIC group, improved results in all parameters, such as bloody diarrhea, lesion scores, the numbers of excreted oocystis in feces, body weight gain and feed conversion rate. Anticoccidial index(ACI) of artemisinin treated group (5ppm~50ppm) was higher than that of NIC group. Improvements were greatest in the group treated with artemisinin 50ppm with an ACI of 147.6. These results indicate that artemisinin has anticoccidial effects on the Eimeria tenella.

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Artemisia annua 추출액의 Eimeria tenella에 대한 항콕시듐 효과 (Anticoccidial effects of an extract of Artemisia annua on the Eimeria tenella)

  • 오화균;윤희정;노재욱;장두환;강영배
    • 대한수의학회지
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    • 제35권1호
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    • pp.115-121
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    • 1995
  • The herb, Artemisia(A) annua, a member of the composital family, has been used successfully for malaria(Plasmodium sp) patients in china. Since the genera of Plasmodium and Eimeria(E) tenella are related, it is presumed that A annua may also be effective against E tenella. In order to study the anticoccidial effects of A annua the chickens inoculated with E tenella were treated with the extract of A annua in drinking water and the results were compared to those of non-medicated, infected control(NIC) and non-medicated, non-infected control(NNC) group. A annua demonstrated anticoccidial effects by showing, compared to NIC group, improved results in all parameters, such as bloody diarrhea, lesion scores, the numbers of excereted oocysts in feces, body weight gain and feed conversion rate. Anticoccidial index(ACI) of the A annua treated group (123.4) was higher than that of NIC group (96.9). These results indicate that Artemisia annua has anticoccidial effects on the Eimeria tenella.

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국내(國內) 돼지의 Clostridium perfringens type C 감염증에 관한 연구 (Studies on the Clostridium perfringens type C infection of pig in Korea)

  • 예재길;박경윤;조성근
    • 대한수의학회지
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    • 제33권3호
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    • pp.419-427
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    • 1993
  • Thirteen strains of Clostridium perfringens were isolated from the pigs with hemorrhagic enteritis. The characteristics of the outbreaks, clinical signs and lesions were examined. The biochemical properties, type of toxin and susceptibility to antimicrobial agents of the isolates were investigated. The results could be summarized as follows ; 1. Almost of the pigs affected with hemorrhagic enteritis, 17 cases examined from 1989 to 1992, were piglets less than 7 day old. 2. The average mortality rate of piglet less than 7 day old affected with hemorragic and necrotic enteritis was 48.5%. 3. The clinical signs of pigs with hemorrhagic enteritis were depression, hemorrhagic diarrhea, anemia and dehydration. Necropsy of the infected pigs showed typical hemorrhage of upper intestine and necrosis of mucosal membrane. 4. The characteristic biochemical properties of the isolates were 2-band hemolysis, positive reaction of reverse CAMP test and formation of LV precipitate in egg yolk medium. 5. The toxin type of the 13 isolates, investigated by mouse inoculation test, was all type C strains of Clostridium perfringens. 6. In susceptibility test to antimicrobial agents, 13 isolates of Clostridium perfringens were highly sensitive to ampicillin, enrofloxacin(Baytril), cephalothin, penicillin and trimethoprim-sulfamethoxazole.

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이미지센서를 위한 조도에 따른 보간 기법의 성능 평가와 이를 이용한 가변적 보간 기법 (Performance Evaluations of the Interpolation Methods Under the various illumination intensities and its Application to the Adaptive Interpolation for Image Sensors)

  • 김병수;백두원
    • 인터넷정보학회논문지
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    • 제9권1호
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    • pp.171-177
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    • 2008
  • 본 연구에서는 베이어패턴을 가지는 보간 알고리듬들을 조도에 따른 성능을 실험을 통해 평가하였다. 보간 알고리듬으로는 양선형 컬러 보간 기법과 적응형 퍼지 컬러 보간 기법을 사용하였는데, 실험 결과 저조도하에서는 양선형 컬러 보간기법에 미디언 필터를 적용한 보간 기법이, 고조도하에서는 적응형 퍼지 컬러 보간 기법이, 그리고 그 사이의 조도 하에서는 양선형 컬러 보간 기법이 우수한 영상을 생성함을 알 수 있었다. 이 결과를 응용하여 입력되는 영상의 조도에 따라서 각각 다른 보간 알고리듬을 적용하여 영상을 보간하면 다양한 조도 하에서도 향상된 화질을 얻을 수 있을 것이다.

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De-soda Process Using Silica for Fabrication of Low Soda Alumina Powder

  • Park, Sang-Chun;Kim, Dae-Woong;Heo, In-Woong;Lee, Sang-Jin
    • 한국세라믹학회지
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    • 제52권3호
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    • pp.192-196
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    • 2015
  • Low soda alumina powder was fabricated using silica (${\alpha}$-quartz) as an agent for removing soda components in the alumina. Quartz powder 2 mm in size was added to aluminum hydroxide obtained through the Bayer process, and then the mixture was heated at various temperatures. Finally, the heat-treated powders were sieved for classification. In this study, the effects of the quartz amount and heating temperature on the mechanism of removing soda were examined. A minimum soda content of 0.005 wt% was observed at the conditions of 15 wt% quartz (based on $Al(OH)_3$ amount) heat-treated at $1600^{\circ}C$ for 8 h. The soda components, such as $Na_2O$, NaOH, and $Na_2CO_3$, in alumina were ionized and activated at high temperature, and this facilitated the reaction with quartz silica and alumina producing nepheline. The advantages of using quartz include low iron content and low cost in comparison with the conventional de-soda process using chamotte, another silicate mineral.

디모자이킹을 위한 Wiener Filter 기반의 디노이징 알고리듬 (Wiener Filter Based Denoising Algorithm for Demosaicking)

  • 이록규;정제창
    • 한국통신학회논문지
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    • 제36권5C호
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    • pp.286-294
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    • 2011
  • 다지털 카메라의 mosaicked image는 Bayer CFA 등의 센서를 통해 획득되며 full resolution의 컬러 영상을 얻기 위해서는 demosaicking이라는 과정이 요구된다. 그러나 시그널이 센서를 통과할 때 noise가 더해지게 되기 때문에 이를 제거하기 위한 denoising process는 demosaicking 과정 전단에 반드시 고려되어야 하는 것이다. 본 논문에서는 demosaicking과 denoising을 분석하고 효율적으로 noise를 제거하는 방식을 제안한다. 제안된 알고리듬은 noiseless CFA에서 얻어지는 필터를 수정함으로서 얻어지며, 낮은 연산량과 함께 만족할만한 성능을 보여준다. CPSNR, SCIELAB, FSIM로 대표되는 화질 측정 방식들은 제안하는 알고리듬이 다양한 레벨의 noise를 효율적으로 제거한다는 것을 보여준다.

닭에서 분리한 Clostridium perfringens의 독소형 (Toxigenic type of Clostridium perfringens isolated from chicken in Korea)

  • 박경윤;이상운;유한상;예재길
    • 대한수의학회지
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    • 제36권4호
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    • pp.829-837
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    • 1996
  • Clostridium perfringens has been identified as a causative organism in necrotic enteritis in chicken. The bacterium has been classified into five toxigenic types (A through E) based on the pattern of the production of major lethal toxins. Seroneutralization with mice or guinea pigs usually has been used to type the organism. Of the types, types A and C of the bacterium had been recognized as the major pathogenic types in chicken. In this experiment, we isolated nine field strains of C perfringens from chicken showing necrotic enteritis in clinical symptoms and pathologic findings and identified by biochemical tests. In order to type the organism, a multiplex polymerase chain reaction (PCR) was used with primers on major lethal toxin genes instead of seroneutralization. Amplification of only a toxin gene with the PCR suggested that the disease in chicken was due to type A of C perfringens in Korea. Furthermore, the PCR method can be replaced with seroneutralization to type C perfringens in future.

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Selectivity of Tefuryltrione between Rice and Eleocharis kuroguwai

  • Song, Jong-Seok;Park, Yong Seog;Park, Min-Won;Lee, Jeong Deug;Kim, Do-Soon
    • Weed & Turfgrass Science
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    • 제5권4호
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    • pp.191-195
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    • 2016
  • Tefuryltrione is a new hydroxyphenylpyruvate dioxygenase (HPPD) inhibitor, which has been recently registered for the use for paddy rice, Korea. Dose-response studies were conducted to compare rice safety and weed control efficacy of tefuryltrione against Eleocharis kuroguwai. When rice and E. kuroguwai were applied at a range of doses of tefuryltrione, $GR_{90}$ values (the dose required to inhibit weed growth by 90%) of E. kuroguwai were $82.38-93.39g\;a.i.\;ha^{-1}$ in two independent experiments. The $GR_{10}$ values (the dose required to inhibit rice growth by 10%) of tefuryltrione for rice were $297.77-471.54g\;a.i.\;ha^{-1}$. As a result, the selectivity indices ($GR_{10}$ for $rice/GR_{90}$ for E. kuroguwai) of tefuryltrione were 3.19-5.72. Therefore, these results demonstrate that tefuryltrione has a relatively high selectivity between rice and E. kuroguwai with a high herbicidal activity against E. kuroguwai and a good rice safety.