• Journal of Electrochemical Science and Technology
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• 제5권2호
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• pp.37-44
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• 2014

The $Li-O_2$ battery has been attracting much attention recently, due to its very high theoretical capacity compared with Li-ion chemistries. Nevertheless, several studies within the last few years revealed that Li-ion derived electrolytes based on alkyl carbonate solvents, which have been commonly used in the last 27 years, are irreversibly consumed at the $O_2$ electrode. Accordingly, more stable electrolytes are required capable to operate with both the Li metal anode and the $O_2$ cathode. Thus, due to their favorable properties such as non volatility, chemical inertia, and favorable behavior toward the Li metal electrode, ionic liquid-based electrolytes have gathered increasing attention from the scientific community for its application in $Li-O_2$ batteries. However, the scale-up of Li-$O_2$ technology to real application requires solving the mass transport limitation, especially for supplying oxygen to the cathode. Hence, the 'LABOHR' project proposes the introduction of a flooded cathode configuration and the circulation of the electrolyte, which is then used as an oxygen carrier from an external $O_2$ harvesting device to the cathode for freeing the system from diffusion limitation.

• 전력전자학회논문지
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• 제18권1호
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• pp.26-36
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• 2013

This paper presents a simple and cost-effective stand-alone rapid battery charging system of 30kW for electric vehicles. The proposed system mainly consists of active front-end rectifier of neutral point clamped 3-level type and non-isolated bi-directional dc-dc converter of multi-phase interleaved half-bridge topology. The charging system is designed to operate for both lithium-polymer and lithium-ion batteries. The complete charging sequence is made up of three sub-interval operating modes; pre-charge mode, constant-current mode, and constant-voltage mode. The pre-charge mode employs the stair-case shaped current profile to accomplish shorter charging time while maintaining the reliable operation of the battery. The proposed system is specified to reach the full-charge state within less than 16min for the battery capacity of 8kWh by supplying the charging current of 78A. Owing to the simple and compact power conversion scheme, the proposed solution has superior module-friendly mechanical structure which is absolutely required to realize flexible power expansion capability in a very high-current rapid charging system.

• 한국전기전자재료학회논문지
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• 제17권9호
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• pp.936-941
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• 2004

In recent years, the rapid growth of portable electronic devices requires the high-energy density characteristics of batteries. Zinc air batteries have specific capacity as high as 820mAh/g. However, Zinc air batteries used for hearing aid applications only so far, because the atmosphere could affect it, and it has weakness in the rate capability. However, recent developments of electrode manufacturing technologies made us to overcome that weakness. And the efforts of applying zinc air batteries to portable electronic devices, especially in cellular phone application have been increased. In this paper, the effects of conducting material and polymer binder in cathode on the electrochemical characteristics were investigated. Our research team succeeded in producing 2.4Ah class zinc air battery for cellular phone application. Its volumetric energy density was 920 wh/l, and gravimetric energy density was 308 wh/kg. The volumetric energy density of our zinc air battery is two times higher than one of lithium secondary battery, and three times higher than that of alkaline manganese battery.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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• pp.1196-1199
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• 2017

쿼드-틸트프롭(QTP) 무인기의 직렬-하이브리드 방식 동력시스템을 설계하고 특성을 분석하였다. 동력시스템은 4.5kW급 로터리엔진-발전기 장치를 기본으로 리튬-배터리를 동력원으로 사용하며, 동력제어기가 비행체가 필요로 하는 전체적인 동력을 제어하고 공급한다. 엔진의 출력은 발전기 구동 및 발전 효율과 배터리의 충전과 방전에 따른 손실을 고려하여 발전기 성능과 매칭된다. 배터리에 저장된 에너지와 통합 제어해서 전체적인 연료소모율을 최소화하도록 엔진-발전기의 정속(Constant Speed) 운용개념이 적용되며, 결과적으로 배터리의 용량과 특성, 그리고 충전과 방전 사이클이 효율 향상에 중요한 요소로 작용할 수 있다.

• Journal of Electrical Engineering and Technology
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• 제8권4호
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• pp.920-929
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• 2013

Within the project 'e performance' supported by the German Ministry of Education and Research (BMBF) an electric vehicle, powered by two lithium-ion battery packs of different capacity and voltage has been developed. The required Energy Management System (EMS) in this system controls the current flows of both packs independently by means of two individual dc-dc converters. It acts as an intermediary between energy storage (battery management systems-BMS) and the drivetrain controller on the vehicle control unit (VCU) as well as the on-board charger. This paper describes the most important tasks of the EMS and its interfaces to the BMS and the VCU. To validate the algorithms before integrating them into the vehicle prototype, a detailed Matlab / Simulink-model was created in the project. Test procedures and results from the simulation as well as experiences and comparisons from the real car are presented at the end.

• 한국전기전자재료학회논문지
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• 제31권1호
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• pp.61-67
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• 2018

High-power lithium batteries are suitable for equipment with high power output needs, such as for ESS's initial start-up. However, their management cost is increased by the installation of air-conditioning to minimize the risk of explosion due to internal temperature rise and also by a restriction on the number of charge/discharge cycles. High-capacity flow batteries, on the other hand, have many advantages. They can be used for over 20 years due to their low management costs, resulting from no risk of explosion and a high number of charge/discharge cycles. In this paper, we propose an ESS based on hybrid batteries that uses a lithium iron phosphate battery (LiFePO) at the initial startup and a vanadium redox flow battery (VRFB) from the end of the transient period, with a bi-directional PCS to operate two batteries with different DC voltage levels and using an efficient energy management control algorithm.

• 한국기계가공학회지
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• 제21권3호
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• pp.49-55
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• 2022

The design of a battery package and a BMS module for applications using seawater rechargeable batteries, which are known as next-generation energy storage devices, is proposed herein. Seawater rechargeable batteries, which are currently in the initial stage of research, comprise primarily components such as anode and cathode materials. Their application is challenging owing to their low charge capacity and limited charge/discharge voltage and current. Therefore, we design a method for packaging multiple cells and a BMS module for the safe charging and discharging of seawater rechargeable batteries. In addition, a prototype seawater rechargeable battery package and BMS module are manufactured, and their performances are verified by evaluating the prevention of overcharge, overdischarge, overcurrent, and short circuit during charging and discharging.

• 한국산업융합학회 논문집
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• 제24권6_1호
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• pp.669-681
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• 2021

As the supply of xEV in Korea is rapidly increasing, the amount of waste batteries is expected to increase rapidly, but the current recycling system for waste xEV batteries is very insufficient. In order to properly utilize the xEV reusable battery module, it is essential to classify it into a type that has similar discharge characteristics to the current state of health(SOH), which is the discharge capacity of the battery. This paper proposes a system that can minimize the exchange of energy with the KEPCO system by using the charging/discharging method by circulating power between batteries in order to minimize the power consumption when charging and discharging waste batteries. In the proposed system, a function to measure parameters during the charging/discharging test of the waste battery was implemented to build a customized big date for the test waste battery. In addition, the dynamic characteristics of the proposed circuit were analyzed using PSIM, which is useful for power electronics analysis, and the validity of the proposed circuit was verified through experiments.

• 전기화학회지
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• 제3권2호
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• pp.72-75
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• 2000

For the purpose of developing the non-stoichiometric Zr-based Laves phase alloy with higher capacity and better performance for electrochemical application, extensive work has been carried out in KAIST. After careful alloy design of $ZrMn_2-based$ hydrogen storage alloys through varing their stoichiometry while susbstituting or adding some alloying elements, the $Zr-Ti-(Lh-V-Ni)_{2.2},\;Zr-Ti-(Mn-V-Cr-Ni)_{1.8\pm0.1}$ with high capacity and better performance was developed. Consequently the $Zr-Ti-(Mn-V-Ni)_{2.2}$ alloy has a high discharge capacity of 394mAh/g and shows a high rate capability equaling to that of commercialized $AB_5$ type alloys. On the other hand, in order to develop the hydrogen storage alloy with higher discharge capacity, the hypo-stoichiometric $Zr(Mn-V-Ni)_{2-\alpha}$ alloys substituted by Ti are under developing. As the result of competitive roles of Ti and $stocihiometry({\alpha})$, the discharge capacity of $Zr-Ti-(Mn-V-Cr-Ni)_{l.8\pm0.1}$ alloys is about 400mAh/g(410 mAh/g, which shows the highest level of performance in the Zr-based alloy developed. Our sequential endeavor is improving the shortcoming of Zr-based Laves phase alloy for commercialization, i.e., poor activation property and low rate capability, etc. It is therefore believed that the commercialization of Zr-based Laves phase hydrogen storage alloy for Ni-MH rechargeable battery is in near future.

• 한국전기전자재료학회논문지
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• 제19권1호
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• pp.64-70
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• 2006

In this study, the $LiCoO_2/LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ mixed cathode electrodes were prepared and their electrochemical performances were measured in a high cut-off voltage. As the content of $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ increased in a mixed cathode, the reversible specific capacity and cycleability of the electrode enhanced, but the rate capability was deteriorated. On the contrary the rate capability of the cathode enhanced, but the reversible specific capacity and cycleability were deteriorated, increasing the content of $LiCoO_2$ in the mixed cathode. The cell of $LiCoO_2/LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ ($50:50 wt\%$) mixed cathode delivered a discharge capacity of ca. 168 mAh/g at a 0.2 C rate. The capacity of the cell decreased with the current rate and a useful capacity of ca. 152 mAh/g was obtained at a 2.0 C rate. However, the cell showed very stable cycleability: the discharge capacity of the cell after 20th charge/discharge cycling maintains ca. 163 mAh/g.